融入WTO——为农业服务的化工矿产资源发展战略构想

我国直接为农业服务的磷、硫、钾矿资源总体形势不容乐观。针对各自资源特点,应采取不同的发展战略:磷——立足国内,有进有出,南出北进;硫——立足国内,适当进口,调整结构,必要储备;钾——稳定进口,国外开发,国内开发,国内找矿,四位一体,分三步走。为此建议:将磷、硫、钾纳入战略性矿产资源的范畴进行管理和规划;强化地勘队伍,加大找矿力度;增加投入,寻求新的突破;加大“走出去”的步伐;规范进出口秩序;国家在更高的层面进行宏观调控;拓宽为农业服务的新领域。     

阿尔泰地区铜镍矿床综合信息找矿模型及成矿预测

阿尔泰地区存在 5条与深大断裂有关的基性、超基性岩带 ,是铜镍硫化物矿床产出的有利地段 ,其中喀拉通克铜镍矿是我国大型铜镍矿之一。通过对成矿必要条件的深入研究 ,得出深大断裂及其次级断裂控制了岩体的产出 ,北北西向断裂叠加北西向断裂控制了矿体的产出 ;成矿充分条件是基性、超基性岩体 ,总结了岩体含矿性的评价指标。结合重磁及地化资料 ,在喀拉通克铜镍矿的成矿模式基础上 ,建立了区域综合信息找矿模型 ,进行成矿预测 ,圈定靶区 9处。     

四川巴塘夏塞花岗岩和银多金属矿床年龄及ち颉⑶ν位素组成

为了解四川西部夏塞银多金属矿区黑云母二长花岗岩形成和矿化发生的时代及成矿物质来源,测定了该矿区绒依措和若洛隆花岗岩的Rb_Sr年龄和钾长石、黑云母及主要银矿化阶段石英的40Ar/39Ar年龄及矿石的硫、铅同位素组成。花岗岩的结晶年龄约为93Ma,银矿化年龄约为75Ma。矿石硫可能源于花岗岩,但不能排除源于弱沉积围岩的可能性;矿石、花岗岩和弱变质沉积围岩的铅同位素组成相似,铅主要源于上地壳,少量源于下地壳。     

The Kuwae (Vanuatu) eruption of<Emphasis Type="SmallCaps"> AD</Emphasis> 1452: potential magnitude and volatile release

Sometime during AD 1452, according to new evidence, a large-magnitude, initially phreatomagmatic eruption, destroyed the island of Kuwae (16.83°S, 168.54°E), located in the present-day Republic of Vanuatu. It created a 12×6-km submarine caldera composed of two adjacent basins. Based on estimates of caldera volume, between 30 and 60 km³ DRE of dacite magma was ejected as pyroclastic flow and fall deposits during this event. Annual layers of ice dating from the period AD 1450–1460 contain acidity peaks representing fallout of sulfuric acid onto both the Greenland and Antarctic ice caps. These acidity peaks have been attributed by others to the sedimentation of H₂SO₄ aerosols that originated from sulfur degassing during the Kuwae eruption. Improved dating techniques and new data from nineteen ice cores reveal a single acidity peak attributed to Kuwae lasting from 1453 to 1457. In this study, we present new electron microprobe analyses of the S, Cl, and F contents of matrix glasses and glass inclusions in phenocrysts from tephra ejected during the Kuwae eruption. We establish that the Kuwae event did indeed yield a large release of sulfur gases. From our glass inclusion data and analysis, we calculate that the total atmospheric aerosol loading from the 1452 Kuwae eruption was ≫100 Tg H₂SO₄. Much of the volatile mass released during the eruption was probably contained in a separate, volatile-rich, fluid phase within the pre-eruptive Kuwae magma body. Comparing the volatile release of the Kuwae eruption with other large-magnitude eruptions, places Kuwae as the greatest sulfuric acid aerosol producer in the last seven centuries, larger even than sulfur emissions from the eruption of Tambora (Indonesia) in 1815, and possibly Laki (Iceland) in 1783. The severe and unusual climatic effects reported in the mid- to late-1450s were likely caused by the Kuwae eruption.     

Do stratocumulus clouds detrain? FIRE I data revisited

Analyses of aircraft observations of the stratocumulus-topped boundary layer during the First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE I) show the frequent presence of clear, but relatively moist, air patches near the stratocumulus cloud-top interface. A conditional sampling of measurements in these clear air patches shows that their thermodynamic properties do more resemble boundary-layer air characteristics than those of free troposphere air. From an aircraft leg through cloud tops it is demonstrated that turbulent mixing across the cloud-top interface can lead to the local dissipation of the cloud top. Analogous to the terminology used for shallow cumulus parameterizations this process can be considered as detrainment, with which we mean that after a mixing event across the cloud-top boundaries, mixed unsaturated parcels become part of the clear environment of the cloud.     

The Atmospheric Oxidation of the HS Radical: Reaction with NO2

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.     

热解硫酸钡制备硫同位素分析试样二氧化硫

改进了硫同位素分析中由ＢａＳＯ４制备ＳＯ２的方法：ＢａＳＯ４和Ｖ２Ｏ５及ＳｉＯ２混合后覆盖铜丝,在真空状态９８０℃加热２０ｍｉｎ,用液氮捕集ＳＯ２。与火焰直接加热分解法相比,用高温炉方便,改善了制样环境,避免污染。经国际标样和国家标准物质分析验证,结果与标准值相符,标准偏差（１σ）在±００９‰～±０２０‰,符合分析要求。     

Mitigating Agricultural Emissions of Methane

Agricultural crop and animal production systems are important sources and sinks for atmospheric methane (CH4). The major CH4 sources from this sector are ruminant animals, flooded rice fields, animal waste and biomass burning which total about one third of all global emissions. This paper discusses the factors that influence CH4 production and emission from these sources and the aerobic soil sink for atmospheric CH4 and assesses the magnitude of each source. Potential methods of mitigating CH4 emissions from the major sources could lead to improved crop and animal productivity. The global impact of using the mitigation options suggested could potentially decrease agricultural CH4 emissions by about 30%.     

A Three-Dimensional Global Model Study of Carbonyl Sulfide in the Troposphere and the Lower Stratosphere

Global distributions of carbonyl sulfide and carbon disulfide have been calculated with a three-dimensional global model of the atmospheric general circulation (ECHAM). The model calculates a global sink strength for carbonyl sulfide of 0.3 Tg S yr^-1, with vegetation uptake being the largest sink. With this sink strength, the sources have to be close to the lower limit of the present estimate in the literature. The calculated mixing ratios are higher in the Southern Hemisphere than in the Northern Hemisphere. This interhemispheric gradient is the opposite of what is observed demonstrating that the present knowledge of the distribution of sinks and sources is not fully adequate. The model calculations support the idea that the open oceans could act as a net sink of carbonyl sulfide. The calculated stratospheric photolysis of carbonyl sulfide constitutes about 4% of the total sink of carbonyl sulfide. A stratospheric production of sulfate from carbonyl sulfide of 0.013 Tg S yr^-1 is obtained, which is 3 to 12 times less than what is needed to maintain the stratospheric sulfate aerosol layer. Although these results are associated with uncertainties, due to the low upper boundary and coarse vertical resolution of the model, they support recent findings of a low stratospheric production of sulfate from carbonyl sulfide. Instead, sulfur dioxide transported from the troposphere is calculated to be the most important precursor for the stratospheric sulfate aerosol layer.