Recommended Values of 239Pu, 240Pu and 239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.     

Effect of volatiles erupted from Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China

Based on the determination of composition of volcanic volatiles and petrologic estimation of the total mass of volatiles erupted, we showed important advances in the study of the impact of Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China. The volcanic activities include western Liaoning and Zhangjiakou Mesozoic intermediate-acidic explosive eruptions, southern Tibet and Shanwang Cenozoic volcanism, and Mt. Changbai volcanic eruption around one thousand years ago. The paper predominantly discusses the earth’s surface temperature changes, ozone depletion, acidic rain formation and mass mortalities of vertebrate induced by the Mesozoic and Cenozoic volcanism in China. __________ Translated from Bulletin of Mineralogy, Petrology and Geochemistry, 2007, 26(4): 319–322 [译自: 矿物岩石地球化学通报]     

A quantitative analysis of the prototype [WCL] star CPD-56° 8032

We present a detailed, quantitative study of the standard [WC10] Wolf-Rayet central star CPD-56^o 8032 based on new high resolution AAT UCLES observations and the Hillier (1990) WR standard model. Our analysis of CPD-56^o 8032 gives the wind properties (T _*=34500K, lg (L/L )=3.8, lg (M/M a^–1)=–5.4,v =225 km s^–1) and chemistry (C/He=0.5, O/He=0.1, by number), the latter suggesting an intimate relationship with the Ovi PN central stars and the PG 1159-035 objects. A comparison between the wind properties of CPD-56^o 8032 and Sk-66^o 40 (WN 10) indicates that low excitation, low wind velocity WR winds are common to both low mass PN central stars (WC sequence) and high mass post-LBV's (WN sequence).     

南极海冰、冰穴和冰川冰及其对水团形成和变性的作用

本文利用前人的成果及笔者1992/1993年的南极海冰观测和收集的资料以及水文观测资料数据阐述了南极海冰的特性,特别是南极海冰过程、冰穴以及冰川冰对南极水团(南极表层水、南极底层水、南极陆架水、南极中层水以及南极冰架水)的形成和变性所起的特殊作用。 南极海冰覆盖面积的年际变化,夏季最大年份是最小年份的2倍多,冬季年间变化较小,最大仅为20％;但其季节变化非常大,冬季平均覆盖面积通常是夏季的5倍。南极海冰对大气-海洋间相互作用有重大影响,特别是深海洋区中冬季的结冰和发育造成的垂向对流、夏季的融化是形成南极表层水(含南极冬季水和南极夏季表层水),进而形成南极中层水的主要原因;南极陆架区的的海冰兴衰过程是形成南极陆架水的直接原因,它与变性南极绕极深层水混合并受到冰川冰的进一步冷却作用,成为形成南极底层水的主要水团;南极冰架底部的冷却、融化和冰架以下水体的结冰作用形成的高盐对流过程产生的南极冰架水,亦是形成南极底层水的贡献者。 冰穴是70年代以来卫星观测的重大发现。对其形成和对大气、海洋的影响作用尚不完全清楚,初步的研究成果表明,冰穴中产生的热盐对流对南极水团的形成、变性、大洋深层的翻转以及海洋-大气间的热量传输和气体交换起有非常重要的作用。     

The mass accommodation coefficient of ammonia on water

The mass accommodation coefficient of ammonia gas on water has been determined by measuring the absorption rate of 50–200 ppm NH₃ in one atm of air or helium into a liquid jet of 97 µm diameter as function of the exposed jet length, and comparing the results with numerical simulations which treat as the only free parameter. The model considers in detail transport of NH₃ by molecular diffusion, penetration of the gas/water interface, hydrolysis in the acidified water, and transport of the solutes from the surface into the jet. A correction is applied for the time evolution of the jet surface speed, using literature data on the fluid mechanics of liquid jets. The result of nine sets of independent measurements is

The circumstellar shells of carbon miras

The relation between mass loss rate and pulsation period in carbon Miras is discussed. The dust mass loss rate is very low (about 2 × 10^–10 M/yr) up to aboutP = 380 days, where there is a sudden increase. ForP > 400 days there is a linear relation between logM andP. The change in the mass loss rate near 380 days may be related to radiation pressure on dust becoming effective in driving the outflow.     

Airborne gamma-ray spectrometry to quantify chemical erosion processes

Airborne gamma-ray spectrometry data (uranium, potassium and thorium contents) reveal geochemical heterogeneities within the monolithological Hyrôme watershed (ca. 150 km²) in the Armorican massif (western France). Our observations and computations provide important constraints on the spatial distribution and the associated magnitudes of chemical erosion processes at the scale of a small watershed. Two distinct, partially preserved, weathering profiles exhibit a strong correlation between regolith evolution and airborne-derived K/Th ratios, suggesting that the variability is linked to supergene processes. Using both airborne data and laboratory measurements on rock samples, the total net export of potassium has been estimated at 422 ± 50 kg/m² and the chemical weathering rate of potassium at 17 ± 2 kg/km²/a.     

Engineering geological studies and tunnel support design at Sulakyurt dam site, Turkey

This paper presents the results of engineering geological investigations and tunnel support design studies, carried out at the Sulakyurt dam site, northeast of Ankara, Turkey. The Sulakyurt dam will be used for flow control and water storage for irrigation projects. Studies were carried out both in the field and the laboratory. Field studies include engineering geological mapping, intensive discontinuity surveying, core drilling and sampling for laboratory testing. The diversion tunnel will be driven in rock mass, consisting of granite and diorite. Empirical, analytical and numerical methods were combined for safe tunnel design. Rock mass rating (RMR), Rock mass quality (Q) and Geological strength index (GSI) systems were used for empirical rock mass quality determination, site characterization and support design. The convergence–confinement method was used as analytical method and software called Phase², a 2D finite element program, was utilized as numerical method. According to the results acquired from the empirical, analytical and numerical methods, tunnel stability problems were expected in both granite and diorite rock masses. The support system, suggested by empirical methods, was applied and the performance of suggested support system was evaluated by means of numerical modelling. It was concluded that the suggested support systems were adequate, since after applying the suggested support system to granite and diorite, tunnel deformation and the yielded elements around the tunnel decreased significantly. Thus, it is suggested that for more reliable support design empirical, numerical and analytical methods should be combined.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.