火焰原子吸收法间接测定磷矿中氯

火焰原子吸收法间接测定磷矿中氯达刘生１云南个旧市化肥厂中心化验室个旧６６１４１１目前磷矿中Ｃｌ－含量的测定多采用浊度法、氯离子选择电极法及离子色谱法。本文采用火焰原子吸收法来间接测定磷矿中Ｃｌ－,即在试样溶液中加入定量的Ａｇ＋,试样中Ｃｌ－与Ａｇ＋生...     

Isotopic composition of xenon in petroleum from the shell bullwinkle field

We have measured the abundance and isotopic composition of xenon in petroleum samples from the Shell Bullwinkle Field off the coast of Louisiana. We used an oxidation and purification procedure designed to insure complete extraction and clean up of xenon from the petroleum. The xenon isotopic composition was found to be similar to the atmospheric value for one petroleum sample. While the results of the second sample suggest possible enrichment of the heavier isotopes, the errors associated with these excesses preclude a definitive statement to that effect. No monoisotopic enrichment in¹²⁹Xe was detected in either sample, the presence of which might have allowed us to deduce the petroleum age. Our results represent only the second xenon measurement from petroleum, and the concentrations are within the range of values published in the earlier report.     

Some foundation stability problems of the railway bridge over the Mala Rijeka

SummarySome Foundation Stability Problems of the Railway Bridge over the Mala Rijeka The authors presented an outlay of problems occurring in estimating the stability of rocky slopes loaded by large vertical forces. General attitudes, kept by the authors during the stability analysis for an actual case — foundation of piers No. 3 and 4 of the railway bridge across the Mala Rijeka, are also presented. The results of calculation as well as the advantages of the approach applied are outlined in the paper. Finally, general conclusions are drawn regarding the method to be kept in solving the stability of slopes loaded by large artificial loading.With 7 Figures     

矽卡岩浆型铜矿床特征——以安徽铜陵东狮子山铜矿床为例

东狮子山铜矿床具有下列独特的特征:(1)矽卡岩是高温、高密度、粘稠的岩浆熔融体;(2)矽卡岩体与辉石二长岩体具有同源性;(3)矿体与矽岩体具有同源性;(4)成矿物质来自岩浆源,硫同位素测定的绝对值小于5‰;(5)矽卡岩矿物开始结晶温度为920C,可见熔融包裹体,成矿温度为620C;(6)成矿压力相当于1～2km深度条件;(7)矿石、矽卡岩具有典型的岩浆矿床的结构构造。     

澜沧江某电站右坝肩复杂岩体质量分类

笔者通过对澜沧江某电站右岸坝肩复杂岩体的成因进行分析,采用岩体质量指数Z并结合水利水电工程围岩分级和RMR分级等岩体分类方法对电站右岸坝肩的复杂岩体进行了综合分类。     

短波红外光谱、X射线荧光光谱、黄铁矿热电性分析在胶东新城金矿田深部找矿中的应用

胶东半岛是我国最重要的金矿集区之一,其矿床是典型受北东向断裂构造(焦家断裂带、三山岛断裂带和招平断裂带),以及次生断裂构造(如望儿山断裂和灵北断裂等)控制的矿床类型.前人在该区域做了大量研究,但主要集中在地表和浅层成矿段,对于深部成矿规律与预测的研究相对较少.新城金矿田是胶东半岛的特大型金矿之一,由新城矿床、曲家矿床和...     

岩体波速与坝基岩体变形模量关系

岩体变形模量是岩体工程设计最重要的参数之一,尽管其可以通过各种现场试验来获得,但因其耗时、费力、投资大,使得许多中小型工程及大型工程的初步设计阶段无法通过试验来得到这一参数。因此,许多研究者建立了诸多岩体变形模量与岩体物理力学参数或岩体质量分级之间的相关关系,如岩体变形模量与RQD、RMR分级、Q分级、岩体纵波速度等之间的关系,从而利用这些关系估算岩体变形模量。总结了已有估算岩体变形模量的各种方法,讨论了其应用条件及预测结果,重点分析了利用岩体纵波速度估算岩体变形模量的方法及存在的问题,并以玛尔挡坝址为实例,建立了相关预测公式。通过与已有估算方法的对比研究,阐明了各种方法预测结果的异同,表明其建立的估算公式与Barton等公式具有较好的一致性,可以用来估算岩体的变形模量     

福建福清核电厂厂址地基岩土工程评价

根据福清市核电厂候选厂址区花岗岩体微风化和中风化层结构的特征,节理裂隙统计,结合声波测试和室内岩石单轴抗压强度、变形试验、三轴压缩试验等测试数据,评价核电厂地基岩体的适宜性。     

刘家坪杂岩体的岩石特征及时代

刘家坪杂岩体出露于扬子准地台西北边缘。该区扬子期岩浆活动,早期为刘家坪组海底喷发的中～酸性火山岩系,晚期先后侵入有角闪辉长岩—石英闪长岩—斜长花岗岩—辉绿岩脉。岩浆岩具有幔源岩浆及造山带地区火山岩的特征。据震旦系覆于刘家坪杂岩体之上,其底部砂砾岩的砾石中有杂岩体成分,以及杂岩体侵入于同位素年龄值为6.43亿年的刘家坪组之中,认为刘家坪杂岩体时代为前震旦纪。     

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.