混合酸比例对ICP-MS/OES测定地球化学样品中多元素的影响

应用电感耦合等离子体质谱/发射光谱仪(ICP-MS/OES)测定地球化学样品中的多元素时,通常采用混合酸(盐酸-硝酸-氢氟酸-高氯酸)分解试样,但不同比例的混合酸对试样的分解效果影响极大,导致测试结果中经常出现铬、锰、铁、铝、钛及部分稀土元素测定结果偏低、精密度不理想的情况。本文通过改变混合酸中各类酸的混合比例,采用逆王水-氢氟酸-高氯酸分解试样,逆王水提取,使上述元素获得了较为理想的分解效果,特别是这些元素含量较高的样品分解效果的改善尤为显著。实验证明:当取样量为0.100 g时,采用8 mL逆王水、6 mL氢氟酸、3 mL高氯酸分解试样,8 mL逆王水提取,用国家一级标准物质进行验证,测试结果的相对标准偏差(n=6)为0.34%~4.02%,本方法精密度和准确度均满足地质实验室质量管理规范要求,可快速、准确、批量测定地球化学样品中的多元素。     

中国近海大气气溶胶的时间和地理分布特征

通过对中国近海10个航次气溶胶观测资料的统计分析得出:(1)从黄海、东海至日本以南海域气溶胶中地壳元素年平均浓度明显减小,在春季尘暴多发期间地壳元素浓度离到岸距离接指数规律递减.污染元素气溶胶浓度分布与陆源排放量和离岸距离有一定关系.(2)海上陆源气溶胶浓度的季节分布为:春季最大,秋冬次之,夏季最小.受日本排放源的影响,日本以南海域污染元素浓度最大值出现在冬季.(3)Se元素浓度与海洋源密切相关.海盐元素从黄海、东海至日本以南海域浓度逐渐增加,主要受周围海况影响,与风速呈现一定程度的正相关.影响近海气溶胶浓度的主要因素有陆源气溶胶排放量、降水分布和大尺度天气形势.     

小张庄近地面大气环境特性变化观测分析

根据１９９３年１０月,１９９５年５月和１９９７年４月在农业生态环境“全球５００佳”－安徽省颖上县小张庄（３４°４７′Ｎ,１１６°２３′Ｅ）所进行的近地面污染气体（ＳＯ２,Ｏ３,ＮＯｘ）和气溶胶的观测结果,给出了这些微量气体的浓度平均概况及随时间和季节变化的一些特征,这三次观测表明,小张庄大气环境质量是持续好的,地面Ｏ３浓度主要取决于地面总辐射强度控制下的光化学反应过程;小张庄大气气溶胶粒子９９％是     

The Great Dun Fell Experiment 1995: an overview

During March and April of 1995 a major international field project was conducted at the UMIST field station site on Great Dun Fell in Cumbria, Northern England. The hill cap cloud which frequently envelopes this site was used as a natural flow through reactor to examine the sensitivity of the cloud microphysics to the aerosol entering the cloud and also to investigate the effects of the cloud in changing the aerosol size distribution, chemical composition and associated optical properties. To investigate these processes, detailed measurements of the cloud water chemistry (including the chemistry of sulphur compounds, organic and inorganic oxidised nitrogen and ammonia), cloud microphysics and properties of the aerosol and trace gas concentrations upwind and downwind of the cap cloud were undertaken. It was found that the cloud droplet number was generally strongly correlated to aerosol number concentration, with up to 2000 activated droplets cm⁻³ being observed in the most polluted conditions. In such conditions it was inferred that hygroscopic organic compounds were important in the activation process. Often, the size distribution of the aerosol was substantially modified by the cloud processing, largely due to the aqueous phase oxidation of S(IV) to sulphate by hydrogen peroxide, but also through the uptake and fixing of gas phase nitric acid as nitrate, increasing the calculated optical scattering of the aerosol substantially (by up to 24%). New particle formation was also observed in the ultrafine aerosol mode (at about 5 nm) downwind of the cap cloud, particularly in conditions of low total aerosol surface area and in the presence of ammonia and HCl gases. This was seen to occur at night as well as during the day via a mechanism which is not yet understood. The implications of these results for parameterising aerosol growth in Global Climate Models are explored.     

大步长波场深度延拓的理论

波场延拓是地震偏移成像的基础. 快速进行目标区波场延拓对石油勘探中急需发展的深部地震勘探和无组合海量地震数据的成像有重要意义. 在目标区成像中,目前已有的波场延拓方法,包括基于走时计算的Dix方法和射线追踪方法,以及基于小步长波场递推的方法,在适应复杂介质、计算精度和计算效率的某一方面还不能完全满足实际需要. 本文提出一种基于“算子相位”李代数积分的快速计算延拓算子的方法,称为大步长波场延拓方法. 在该方法中,指向目标区的波场延拓算子象征的复相位被表示成波数的线性组合. 线性组合的系数是层速度函数及其导数的深度积分,计算和存储较为方便. 波场延拓算子通过相移算子加校正的方法,利用快速Fourier变换在空间域和波数域予以实现. 利用动力学等价关系导出了便于计算的表达式. 本文比较了算子主象征函数用一步法展开和用两步法展开的精度,从而说明大步长方法的精度要高于递推方法. 在横向和纵向线性变化介质中,将大步长方法的脉冲响应与递推法做了比较,说明大步长延拓算子的走时精度主要取决于相移因子中的横向变速校正项;且在各种近似下,大步长算子发生的频散都非常小.     

The Present Status and Prospect of Earthquake Focal Depth Locating

Locating an earthquakes focal depth is always a key project in seismology. Precise focal depth is of critical importance for evaluating seismic hazards, deciphering dynamic mechanisms of earthquake generating,estimating aftershock evolutions and risk,as well as monitoring nuclear tests. However,how we determine an accurate focal depth is always a challenge in seismological studies. Aiming to solve these problems, we analyzed and summarized the present status and the future development of earthquake focal depth locating. In this paper we first reviewed the present status of focal depth locating in the world,and summarized the frequently-used relocating methods and ideas at present,and introduced two types of focal depth relocating ideas: arrival time relocating and waveform modeling methods. For these ideas,we systematically described the S-P and the Pn-Pg methods that belong to arrival time method,and polarization focal depth locating and amplitude focal depth locating that belongs to waveform modeling,and further analyzed the advantages and limitations of these methods. Since the depth phase methods are highly sensitive to focal depth,and are relatively free from the uncertainties of crustal models,we mainly reviewed the depth phases of s Pm P,s PL,s Pn,and s Sn,and quantitatively evaluated their availabilities and characteristics. Second,we also discussed the effects of crustal velocity models on the reliability of focal depth locating,and reviewed the advancements of seismic tomography techniques over recent years. Finally,based on the present status of the progress on the focal depth locating,and studies of seismic velocity structures,we proposed an idea of combining multiple datasets and relocating methods,jointly utilizing seismologic and geodetic techniques to relocate focal depth,which should be the major research field in investigating focal depth and source parameters in the near future.     

Spatial variability of E. coli in an urban salt-wedge estuary

This study investigated the spatial variability of a common faecal indicator organism, Escherichia coli, in an urban salt-wedge estuary in Melbourne, Australia. Data were collected through comprehensive depth profiling in the water column at four sites and included measurements of temperature, salinity, pH, dissolved oxygen, turbidity, and E. coli concentrations. Vertical variability of E. coli was closely related to the salt-wedge dynamics; in the presence of a salt-wedge, there was a significant decrease in E. coli concentrations with depth. Transverse variability was low and was most likely dwarfed by the analytical uncertainties of E. coli measurements. Longitudinal variability was also low, potentially reflecting minimal die-off, settling, and additional inputs entering along the estuary. These results were supported by a simple mixing model that predicted E. coli concentrations based on salinity measurements. Additionally, an assessment of a sentinel monitoring station suggested routine monitoring locations may produce conservative estimates of E. coli concentrations in stratified estuaries.     

渤海常见土类剪切波速与埋深关系分析

土层的剪切波速是岩土地震工程中重要的物理量,本文利用多年来在渤海海域地震安全性评价中积累的资料,研究了渤海常见土类剪切波速和埋深的关系。利用非线性最小二乘法,采用指数函数、一次函数、二次函数、幂函数、"幂函数+常数函数"、"幂函数+一次函数" 6种回归模型对各类土的剪切波速和埋深的关系进行了回归分析,以拟合优度以及最小二乘拟合的误差平方和为评价指标对比了各种模型拟合效果的优劣。结果表明,"幂函数+一次函数"回归模型的拟合效果最好。此外,本文给出了该海域常见的7类土在此回归模型下的拟合公式的系数,以供工程中参考。     

华北典型污染地区多轴差分吸收光谱技术的气溶胶反演研究

基于华北典型污染地区的地基多轴差分吸收光谱仪（MAX-DOAS）近4年的观测数据,利用最优估计算法和LIDORT辐射传输模式反演了该区域气溶胶的消光系数垂直廓线和光学厚度（AOD）.MAX-DOAS观测反演的AOD与全球气溶胶观测网络同波段在华北地区的AOD间具有很好的一致性,相关系数都在0.9以上,证明MAX-DOAS具备对华北污染区域气溶胶光学厚度和消光系数垂直廓线的反演能力.AOD的反演误差表现为冬季最大,春夏最小,早晚大于正午,这是因为冬季以及早晚太阳天顶角较大导致信噪比偏小,所以AOD反演误差偏大.反演廓线表明该区域气溶胶主要集中在1 km以下的边界层,浓度随高度呈指数递减,部分情况下峰值出现在300 m处;气溶胶光学厚度夏季最大,冬季最小,正午较大,早晚较小.在东风条件下浓度最高,表明东边（即重工业城市唐山方向）的输送对香河和周边区域的气溶胶积聚有重要贡献.     

基于时空局域化dreamlet单程波算子的观测系统沉降法偏移

Dreamlet偏移成像目的是探索一类能够对地震波场和单程波传播算子同时分解和压缩的理论和方法,也即实现在压缩域的传播与成像、地震数据在时间和空间的非平稳性质,决定了要实现地震数据的有效稀疏表示,分解方法必须在时间和空间上同时具有局域化性质.Dreamlet由时间和空间局部分解原子的张量积构成,可以看作一种脉冲-小波束形式的波场分解原子.时空局域化的dreamlet单程波传播算子在对波场沿深度方向延拓时,地震数据在时间轴上总是向同一方向流动.随着深度的增加,部分用于成像浅层结构的数据归位至其空间位置后被dreamlet算子丢弃,波场的有效记录时间变短,每一步用于波场延拓的计算量也相应下降.为了充分发挥这一优势,本文介绍dreamlet传播算子与观测系统沉降法偏移相结合的理论与方法.观测系统沉降法偏移每一步都将记录到的所有数据向下延拓,沉降后的波场等效于把源和检波器都放置在目标深度所能接收的反射数据.Dreamlet观测系统沉降过程只保留用于成像观测系统下部地质结构的有效数据,自动丢弃已经用于成像观测系统上部而对下部成像没有贡献的信号.本文通过二维SEG/EAGE叠后和Marmousi叠前数据算例展示了dreamlet传播算子应用于观测系统沉降法偏移的这一特点.数值算例结果显示,在不影响成像质量的前提下,该偏移方法能够有效减少传播数据量,为发展一种快速高效的偏移方法提供了新的思路.