Distribution of As, Cr and V species in the Po-Adriatic mixing area, (Italy)

The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters.     

北太平洋亚热带环流区表层水中226Ra和228Ra的分布与变化

对1999年9～10月采自北太平洋亚热带环流区的19份表层海水样品的Ra同位素分析表明。研究海域表层水中的^226Ra、^228Ra放射性比度分别介于0．67～0．92、0．08～0．30Bq／m^3之间，平均值分别为0．74、0．11Bq/m^3．^226Ra/^228Ra)A．R．活度比的变化范围为0．11～0．44，平均值为0．19．上述数值明显低于近岸海域水体的相应值，表现为典型的开阔大洋水的特征．从空间分布的特征看，研究海域Ra同位素含量与^226Ra/^228Ra)A.R.值均呈均匀分布态势．将本研究结果与历史数据进行对比后发现，本研究获得的^226Ra、^228Ra放射性比度比20世纪60～80年代得到的数据来得低，可能与水体层化作用加强导致的Ra补充量的减少以及生物生产力升高导致的Ra迁出量的增加有关．北太平洋亚热带环流区表层水中Ra同位素的时间变化与文献报道的该海域叶绿素a、硅酸盐、磷酸盐含量与初级生产力的历史变化趋势相吻合．     

模糊化(拓扑)导算子的公理化

将模糊化(拓扑)导算子进行了公理化，并且给出了若干模糊化(拓扑)导算子的刻画；同时建立了模糊化(拓扑)导算子和模糊化(拓扑)闭包算子之间的关系。     

海岛旅游效率空间格局演变及影响因素研究 ——以中国12个海岛县(区)为例

旅游产业是海岛地区的重要产业之一，借助 DEA 模型测度 12 个海岛县 （区） 的旅游效率，采用组合方法对海岛旅游效率的空间特征演变进行刻画，并通过 EVIEWS 软件分析海岛旅游效率的影响因素。 （1） 海岛旅游综合效率总体不高，技术效率是海岛旅游效率发展的主要驱动力，规模效率水平较低，海岛旅游发展能力未得到全面发挥。 （2） 海岛县 （区） 之间旅游效率总体差异不大，相对差异明显。海岛旅游效率空间状态演变由不稳定趋向于稳定，可能存在“贫困陷阱”和“俱乐部趋同”现象。 （3） 经济发展水平、生态环境、科技信息对海岛旅游效率的发展起到积极的推动作用，产业结构、交通条件、城镇化是海岛旅游效率发展的约束性因素。     

Fe(OH)_3胶体与铜离子作用的研究

使用切向流超滤系统得到粒度较均匀的Fe(OH)3胶体,进而对Fe(OH)3胶体粒子与Cu2 的作用进行了研究,并将实验结果与南沙群岛海区表层水中铜与胶体物质结合状况的调查数据进行了比较分析,得到如下结果:(1)在海水介质中,铜在Fe(OH)3胶体上结合的百分率(pH>5)随pH的升高而下降,随着Fe(OH)3胶体浓度的减小而下降?(2)在天然海水介质中,使铜在Fe(OH)3胶体上结合的百分率在50%-70%的有机物浓度为1.0mg·L-1,有机物浓度的增大使铜与无机胶体结合的百分率有下降的趋势?     

The DNA de-methylating agent 5-azacytidine does not restore CYP1A induction in PCB resistant Newark Bay killifish (Fundulus heteroclitus)

Newark Bay (NB) killifish (Fundulus heteroclitus) have been chronically exposed to environmental contaminants that activate the aryl hydrocarbon receptor (AHR) and are tolerant to toxic effects and CYP1A induction provoked by AHR ligands. Resistance to CYP1A induction could be due to an epigenetic mechanism such as DNA methylation. We measured in-ovo CYP1A catalytic activity (ethoxyresorufin-O-deethylase, EROD) in NB and reference site killifish embryos aqueously exposed to various concentrations of the de-methylating agent 5-azacytidine, 5-AC (5, 50 and 500 μ(micro)M) with or without 0.2 μ(micro)g/l of the CYP1A inducer 3,3^′,4,4^′,5 pentachlorobiphenyl (IUPAC PCB126). Neither PCB126 alone, nor PCB126 plus 5-AC, induced EROD above levels in vehicle treated Newark Bay fish. In reference site fish, the same PCB126 dose provoked a 7.4-fold EROD induction relative to controls. We conclude that Newark Bay killifish are resistant to CYP1A induction by co-planar PCBs during early embryological development and our data suggests that DNA methylation does not play a critical role in resistance to CYP1A induction in this model.     

海浪日最大波高序列的一种标度性质

应用重标度分析方法研究小麦岛海洋观测站１９６１－１９８０年二十年海浪日最大波高序列时发现，该序列并不是相互独立的，而是具有记忆性和持久性，详细的论证表明分式布朗运动模型是描述海浪日最大波高序列的一个较好的模型，同时，应用分式布朗运动模型我们找到了存在于海浪日最大波高序列中的一种标度性质－累积离差（ｔ）的统计自仿射性。     

分离入射波与反射波的解析方法

提出了一种新的分离入射波和反射波的解析方法（AM）。利用两点处的 波高信息，运用Hilbert变换得到波浪信号在复域内的解析表达式，不需要计算合成波高和相位差即可实现信号的分离。根据分离结果，可以精确地估计入射波与反射波的幅值以及反射系数等参数，能够获得入射波与反射波之间的相位信息，并且可方便地用于不规则波的分离。文中通过数值模拟与物理模型实验对AM法进行了检验，所得的结果与实际值非常吻合。