塔东地区古城4井上寒武统—中、上奥陶统流体地球化学示踪

通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。     

Breakdown of hydrous ringwoodite to pyroxene and spinelloid at high P and T and oxidizing conditions

To get deeper insight into the phase relations in the end-member system Fe₂SiO₄ and in the system (Fe, Mg)₂SiO₄ experiments were performed in a multi-anvil apparatus at 7 and 13 GPa and 1,000–1,200°C as a function of oxygen fugacity. The oxygen fugacity was varied using the solid oxygen buffer systems Fe/FeO, quartz–fayalite–magnetite, MtW and Ni/NiO. The run products were characterized by electron microprobe, Raman- and FTIR-spectroscopy, X-ray powder diffraction and transmission electron microscopy. At fO₂ corresponding to Ni/NiO Fe-ringwoodite transforms to ferrosilite and spinelloid according to the reaction: 9 Fe₂SiO₄ + O₂ = 6 FeSiO₃ + 5 Fe_2.40Si_0.60O₄. Refinement of site occupancies in combination with stoichiometric Fe³⁺ calculations show that 32% of the total Fe is incorporated as Fe³⁺ according to From the Rietveld refinement we identified spl as spinelloid III (isostructural with wadsleyite) and/or spinelloid V. As we used water in excess in the experiments the run products were also analyzed for structural water incorporation. Adding Mg to the system increases the stability field of ringwoodite to higher oxygen fugacity and the spinel structure seems to accept higher Fe³⁺ but also water concentrations that may be linked. At oxygen fugacity corresponding to MtW conditions similar phase relations in respect to the breakdown reaction in the Fe-end-member system were observed but with a strong fractionation of Fe into spl and Mg into coexisting cpx. Thus, through this strong fractionation it is possible to stabilize very Fe-rich wadsleyite with considerable Fe³⁺ concentrations even at an intermediate Fe–Mg bulk composition: assuming constant K _D independent on composition and a bulk composition of x _Fe = 0.44 this fractionation would stabilize spl with x _Fe = 0.72. Thus, spl could be a potential Fe³⁺ bearing phase at P–T conditions of the transition zone but because of the oxidizing conditions and the Fe-rich bulk composition needed one would expect it more in subduction zone environments than in the transition zone in senso stricto.

C_4植物的出现与全球环境变化

C4 光合作用途径 (C4 植物 )的出现和随后的扩展 ,是发生在新生代晚期的重大事件。这一事件是晚新生代全球环境演化的产物。C4 植物在某些生态系统中占据主导地位 ,又通过食物链 ,影响了动物 ,特别是食草动物的演化。以C4 植物为主的干草原环境甚至与人类的起源有着某种成因上的联系。C4 植物的出现对中新世以来全球环境变化和现代环境格局形成过程具有特殊的意义。文中就C4 植物出现和扩展的时间、C4 植物的分布和生态特征、C4 植物出现的环境背景、构造运动 ,特别是印度和欧亚板块碰撞以及由青藏高原强烈隆升引发的侵蚀作用和大气组分变化及其与C4 植物出现的联系等问题作了较为系统的综述。文章还介绍了中国北方现代草本植物的δ13 C值的最新研究结果 ,并就草本植物δ13 C值与环境参数之间可能的关系进行了初步讨论。     

黔北下寒武统黑色岩系古地温及其指示意义

采用显微光度计测定黔北下寒武统牛蹄塘组黑色岩系固体沥青反射率平均为5.89%,按相关经验公式折算出来的镜质体反射率平均为4.123%,在迈维尔图解、Karwell图解、Hood图解上投点,结合干酪根和孢粉颜色指数法,推断黑色岩系的古地温为60～250℃。结合黄铁矿热电系数法和包裹体均一法测温值,认为黑色岩系属中、低温沉积成岩成矿作用,以低温沉积成岩成矿作用为主。"热"的来源为海底火山喷溢,含矿热卤水提供了丰富的有用元素。黑色岩系有机碳含量高,属好烃源岩,有机质成熟度高,热演化程度高,属过成熟。黑色岩系古地温的研究,对阐明黑色岩系的沉积、成岩和成矿条件具有重要意义。     

地下水浅埋区土壤水的矿化度变化规律及其影响因素浅析

土壤水的研究对农田水利、水文地质、生态与环境等都具有很重要的意义 ,本文概略介绍了在黄河三角洲地区开展包气带水分运移试验研究过程中 ,野外获取土壤水的方法及设备。在对水样分析结果进行总结的基础上 ,对试验点土壤水的矿化度变化规律及其影响因素进行了初步的分析。主要结论为 ,在地下水浅埋区 ,地下水与土壤水矿化度变化关系密切 ;蒸发作用与蒸腾作用对土壤水矿化度的影响效果是不同的 ,蒸发作用使上层土壤水的矿化度加大 ,而植被在其生长期降低土壤水的矿化度 ;地下水、植被和土壤性质是影响土壤水矿化度的重要因素     

4D architecture and tectonic evolution of the Laverton region,eastern Yilgarn Craton,Western Australia

The Laverton region, located in the eastern Yilgarn Craton (EYC) Western Australia, is second only to the Kalgoorlie region for gold endowment. The integration of high-density, potential-field data, regional- and camp-scale seismic reflection data, regional- and mine-scale structural analysis, and geochronologically-constrained stratigraphy, provided new insights into the 4D architecture and tectonic evolution of Laverton region.     

Structural changes and valence states in the MgCr<Subscript>2</Subscript>O<Subscript>4</Subscript>–FeCr<Subscript>2</Subscript>O<Subscript>4</Subscript> solid solution series

The influence on the structure of Fe²⁺ Mg substitution was studied in synthetic single crystals belonging to the MgCr₂O₄–FeCr₂O₄ series produced by flux growth at 900–1200 °C in controlled atmosphere. Samples were analyzed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption-, infrared- and Mössbauer spectroscopy. The Mössbauer data show that iron occurs almost exclusively as ^IVFe²⁺. Only minor Fe³⁺ (<0.005 apfu) was observed in samples with very low total Fe. Optical absorption spectra show that chromium with few exceptions is present as a trivalent cation at the octahedral site. Additional absorption bands attributable to Cr²⁺ and Cr³⁺ at the tetrahedral site are evident in spectra of end-member magnesiochromite and solid-solution crystals with low ferrous contents. Structural parameters a₀, u and T–O increase with chromite content, while the M–O bond distance remains nearly constant, with an average value equal to 1.995(1) Å corresponding to the Cr³⁺ octahedral bond distance. The ideal trend between cell parameter, T–O bond length and Fe²⁺ content (apfu) is described by the following linear relations: a₀=8.3325(5) + 0.0443(8)Fe²⁺ (Å) and T–O=1.9645(6) + 0.033(1)Fe²⁺ (Å) Consequently, Fe²⁺ and Mg tetrahedral bond lengths are equal to 1.998(1) Å and 1.965(1) Å, respectively.     

The Momentum 4-Vector Imparted by Gravitational Waves in Bianchi-Type Metrics

Considering the Møller, Weinberg and Qadir-Sharif's definitions in general relativity, we find the momentum 4-vector of the closed universe based on the Bianchi-type metrics. The momentum 4-vector (due to matter plus fields) is found to be zero. This result supports the viewpoints of Albrow and Tryon and extends the previous works by Cooperstock–Israelit, Rosen, Johri et al., Banerjee–Sen and Vargas who investigated the problem of the energy in Friedmann–Robertson–Walker universe and Salt?-Havare who studied the problem of the energy-momentum of the viscous Kasner-type space-times.     

利用空间测地技术结果估计地球平均下地幔粘性(英)

基于IEC－4G冰期后地壳反弹模型,和地球上Laurentia,Fennoscandia,Antarctica,andGreenland四大冰盖最近21000年以来的冰融参数,计算了对地球最大主转动惯量的影响△I33,并进而由现代空间测地技术观测资料分析得到的地球自转非潮汐加速项为约束,估计了地球平均下地幔（670km以下）粘性vLM为（0．9～2．5）·1022Pas,这个结果表明了vLM应具有1022Pas量级．     

A unified C-band and Ku-band geophysical model function determined by neural network approach

The geophysical model function （GMF） describes the relationship between backscattering and sea surface wind, so that wind vec- tors can be retrieved from backscattering measurement. The GMF plays an important role in ocean wind vector retrievals, its performance will directly influence the accuracy of the retrieved wind vector. Neural network （NN） approach is used to develop a unified GMF for C-band and Ku-band （NN-GMF）. Empirical GMF CMOIM and QSCAT-1 are used to generate the simulated training data-set, and Gaussian noise at a signal noise ratio of 30 dB is added to the data-set to simulate the noise in the backscat- tering measurement. The NN-GMF employs radio frequency as an additional parameter, so it can be applied for both C-band and Ku-band. Analyses show that the %predicted by the NN-GMF is comparable with the σpredicted by CMOIM and QSCAT-1. Also the wind vectors retrieved from the NN-GMF and empirical GMF CMOIM and QSCAT-1 are comparable, indicating that the NN-GMF is as effective as the empirical GMF, and has the advantages of the universal form.