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101.
Ecological investigations at four streams in Saxony‐Anhalt have shown that there are considerable differences between the self‐purification power of upland and lowland streams. This result is reflected in chemistry and in microbiology. The structure of the bottom substrate mainly influences the degree of self‐purification in connection with rate of flow and flow velocity. The results and differences are demonstrated using the example of Katzsohlbach in the landscape unit “Mittel‐ and Unterharz” and the stream Olbe in the landscape unit “Magdeburger Börde”. 相似文献
102.
The OECD soil, which is standardised for use in the sediment toxicity with the midge Chironomus riparius revealed inhibition of the nematode Caenorhabditis elegans in body growth length and egg production of 41.0% and 84%, respectively. 18 formulated sediments were tested to optimise the sediment composition for growth and reproduction of C. elegans. Their components were chosen to simulate native sediments, whereby different quantities and different clay minerals were tested. The mixture that we found to be optimal in our experiments consisted of 5% sphagnum peat, 70% calcitic sand, 0.5% dolomite limestone, 4.5% iron(III) oxide, and a clay combination of 1.5% chlorite and 18.5% aluminium(III) oxide. When applying this mixture to C. riparius, the new formulated sediment improved also growth in comparison to the OECD sediment. 相似文献
103.
The spinel solid solution was found to exist in the whole range between Fe3O4 and γ-Fe2SiO4 at over 10 GPa. The resistivity of Fe3−
x
Si
x
O4 (0.0<x<0.288) was measured in the temperature range of 80∼300 K by the AC impedance method. Electron hopping between Fe3+ and Fe2+ in the octahedral site of iron-rich phases gives a large electric conductivity at room temperature. The activation energy
of the electron hopping becomes larger with increasing γ-Fe2SiO4 component. A nonlinear change in electric conductivity is not simply caused by the statistical probability of Fe3+–Fe2+ electron hopping with increasing the total Si content. This is probably because a large number of Si4+ ions occupies the octahedral site and the adjacent Fe2+ keeping the local electric neutrality around Si4+ makes a cluster, which generates a local deformation by Si substitution.
The temperature dependence of the conductivity of solid solutions indicates the Verwey transition temperature, which decreases
from 124(±2) K at x=0 (Fe3O4) to 102(±5) K at x=0.288, and the electric conductivity gap at the transition temperature decreases with Si4+ substitution.
Received: 15 March 2000 / Accepted: 4 September 2000 相似文献
104.
Tobelite (NH4) Al2 [AlSi3O10] (OH)2, the ammonium analogue of muscovite, and its deuterated form ND4-tobelite (ND4) Al2 [AlSi3O10] (OD)2 have been synthesised at 600?°C and 200 and 500 Mpa using a well homogenised, stoichiometric SiO2-Al2O3 oxide mix with Al2O3 in excess of 5 mol% and a 25% NH3 solution whose relative abundance was such that the amount of NH4 + stoichiometrically available was in excess of 50%. Characterisation of both tobelite and ND4-tobelite using IR-spectroscopy, Rietveld refinement of X-ray powder diffraction data, and electron microprobe analysis indicate that, similar to K+ in muscovite, the NH4 + or ND4 + molecule occupies the interlayer site. IR absorption bands caused by NH4 + and ND4 + can be explained, to a very good approximation, on the basis of Td symmetry. Nevertheless, substantial line broadening and the occurrence of shoulders indicate a deviation from ideal Td symmetry. However, even at 77?K, no discrete splitting of the degenerate states could be confirmed. The OH stretching frequencies observed for synthetic tobelite are quite similar to those for muscovite, indicating that the replacement of K+ by NH4 + has no effect. The low FWHH of the OH bands indicate that the hydroxyl groups are well ordered within the structure. Rietveld refinement of tobelite and ND4-tobelite indicates that all samples synthesised consist of the 3 different mica polytypes which are typical of muscovite – namely 1M (C2/m), 2M 1 (C2/c) and 2M 2 (C2/c). Tobelite and ND4-tobelite synthesised at 500 Mpa principally contain the 1M polytype, whereas the principle polytype for ND4-tobelite synthesised at 200 Mpa, is 2M 2. Rietveld refinement of X-ray diffraction spectra for tobelite synthesised at 200 Mpa was problematic due to the very broad FWHH of the X-ray peaks indicating poor crystallinity. In comparision to synthetic muscovite, the cell dimensions observed for tobelite and its deuterated analogue are quite similar except for the lattice constant c. Due to the larger radius of NH4 + or ND4 + compared to K+ cation, the c-direction is expanded form 10.275 Å in muscovite to approximately 10.540 Å in tobelite and ND4-tobelite. 相似文献
105.
Contribution to the characterization and identification of low molecular weight organic substances in biologically treated effluent. In a review it is shown that by determination of sum parameters only 25% of low molecular weight substances <1000 Dalton in biologically treated effluent can be divided into different classes of compounds. A method is described to separate the low molecular weight compounds (freeze concentration, electrodialysis, vacuum evaporation, freeze drying) in order to identify single compounds. In a first GC-MS analysis 87 compounds, among them a high proportion of substances with hetero atoms, could be identified. Their concentrations lie between 0,1 and 3 μg/1. Only 3% of the low molecular weight fraction related to the DOC value is covered by the identified substances. Therefore it can be assumed, that a broad variety of low molecular weight compounds in very low concentrations is present in the effluent of biological treatment plants. 相似文献
106.
A method is described for the specific hydrolysis of amino acids from humic substances by using the proteolytic enzyme “Pronase E”. The amino acids are analyzed by a fluorescence detector after precolumn derivatization and HPLC-separation. The pattern and the concentration of amino acids after the enzymatic hydrolysis are set up for humic substances of different origin. Due to the results the enzymatic hydrolysis is suitable for the characterization of humic substances with a nitrogen content higher than 3%. As shown in a kinetic study of the hydrolysis of a fulvic acid the influence of humic substances on the enzyme activity increases in case of lower nitrogen content. Due to the specificity of the proteolytic enzyme the operationally defined method is limited as shown by a protein of a known amino acid content. The amino acids leucine, valine, tyrosine and histidine are released to the highest extent. The determined total extent for the hydrolysis of Insulin B is 26.34% and for Casein 38.37%. By comparison of the enzymatic hydrolysis with the classic acid hydrolysis the advantages of the biochemical method are the simple experimental handling and the mild reaction conditions. Amino acids which are very unstable like glutamine and asparagine can only be analyzed by the enzymatic hydrolysis. 相似文献
107.
Toxicity of soil spiked with water soluble and insoluble contaminants was assessed with bacteria. Three bioassays were used with common soil bacteria. Water soluble fractions from the soils were estimated in microtiterplates via dehydrogenase activity of B. cereus and growth of P. putida. A new method was developed using B. cereus to include effects of soil particles with bound contaminants. As contaminants p-nitrophenol and 2-naphthol were tested in these systems. Results indicated that the concentration of the contaminants in the soil solution is determined by soil properties. Toxicity of water soluble fractions was not only a result of the toxicant's concentration but further modified by soluble components of the soils. It is not possible to assess soil pollution from toxicity of the water soluble fraction in general, because unknown factors of the soluble soil fraction can influence toxicity greatly. The newly developed contact bioassay with B. cereus showed clearly higher toxicity of 2-naphthol estimated in soil suspension than did the comparable test system with the same bacteria using water soluble fractions only. The results stress the importance of including soil particles into bioassay procedures. It was shown that also water insoluble, bound contaminants can act as toxicants. For an estimation of toxicity under conditions more relevant for the environment, the suggested test system can provide useful information to bioavailability of bound contaminants. 相似文献
108.
Investigating adsorption of methyl parathion on the activated carbons Filtrasorb 400 and F 44 and on the adsorption polymer Wofatit Y 77 we found a stronger adsorption on the carbons at smaller concentration whereas the resin has the larger capacity at higher concentration. Adsorbents were regenerated through hydrolysis of the pesticide at pH = 11.7. The velocity of hydrolysis in the adsorbed state is reduced to a tenth of that in solution. However, a transport resistance in the pores of adsorbents seems to be negligible as may be concluded from the very small measured particle diameter dependence of the velocity constants. In adsorption-regeneration measurements the capacity of the adsorbents stabilized at about 70% of that of the fresh adsorbents. 相似文献
109.
农田生态系统温室气体排放研究进展 总被引:39,自引:0,他引:39
自1985年起,中国科学院大气物理研究所利用自行设计制造的自动观测仪器系统,历时十六年先后对我国四大类主要水稻产区的甲烷排放规律及其与土壤、气象条件和农业管理措施的关系进行了系统野外观测实验,并对稻田甲烷产生、转化和输送机理进行了理论研究,探讨了控制稻田甲烷排放的实用措施,建立了估算和预测稻田甲烷排放的数值模型.在甲烷排放的时空变化规律和转化率研究方面有一系列新的发现,在稻田甲烷产生率、排放率及其与环境条件的关系方面取得一系列新的成果,以充分证据改变了国际上关于全球和中国稻田甲烷排放总量的估算.在对稻田甲 相似文献
110.
YU Wen-fei 《天文研究与技术》2003,(1):12-15
最近对低质量X射线双星中的千赫兹准周期振动的研究表明 ,是辐射压力 ,而不是盘和磁球的相互作用以及处于盘内边界的广义相对论效应在短时标的盘切断机制上起作用。本文给出了一些研究结果及讨论。 相似文献