Intact Polar and Core Tetraether Lipids in Sediments from the Haiyang 4 Cold-seep of the Northern South China Sea and their Implications

A number of cold seeps have been discovered in the northern South China Sea (SCS) including the Haiyang 4 cold-seep area where Core 973-5 was collected. Intact polar lipids (IPLs) and core lipids (CLs) were analyzed separately in sediments from Core 973-5. The most abundant lipid biomarkers were isoprenoidal GDGTs (isoGDGTs), with Crenarchaeol and GDGT-0 predominating. IPL-isoGDGTs and CL-isoGDGTs were mainly derived from Thaumarchaeota. IPL-isoGDGTs were mainly produced and retained in situ thus containing most of the in situ microbiological information. Branched GDGTs were predominantly derived from generated in marine production, and mixed with some terrestrial inputs. All IPLs groups presented a high value in the sulfate-methane transition zone (SMTZ). Furthermore, IPL and CL-MI, IPL-R0/4 showed the highest values within the SMTZ, while IPL and CL-R4/i had the lowest values at the SMTZ, suggesting that the contribution of Methanophila and methanogenic to GDGTs increased, while the contribution of ammonia-oxidizing Archaea to GDGTs decreased at the SMTZ.     

EH4电磁系统在云南红河地区地下水勘查中的应用

本文介绍了EH4电磁成像系统的基本原理、技术特点和适用范围,结合该系统在云南红河地区不同类型地下水勘查中的应用实例,证明该系统能够查清厚覆盖层下的地质构造、地下河形态及含水岩溶带。利用该系统确定的井位已成功地打出地下水,有效地解决了当地的供水问题。     

冰川区不同气温估算方法评估 ——以藏东南帕隆4号冰川为例

冰川作为地表特殊的下垫面,冰川区内气温明显低于同高度非冰川区大气温度。如何利用低海拔非冰川区观测资料精确估算高海拔冰川区气温,直接关系着青藏高原冰川消融估算及其水文效应的评估。利用架设在藏东南帕隆藏布4号冰川不同高度带的四台自动气象站资料,分析了冰川区与非冰川区气温的波动特征,评估了迄今为止通用的线性递推模型（DT模型）、分段拟合模型（SM模型）和简化热力学模型（GB模型）三种方法在藏东南冰川区气温估算方面的应用效果。对比研究发现：SM模型在帕隆4号冰川上的模拟效果最为理想且操作相对简单;传统DT模型在消融区存在严重的高估,帕隆4号冰川表面夏季（6-8月）正积温的高估比例接近39%;GB模型由于受到诸如冰川风边界层厚度等不确定性的影响,降低了大范围温度估算的可操作性。     

A grain-size record from Beijing region in Northern China: Late Quaternary paleoclimate oscillation in response to global change

Numerous samples taken from one core at the Beijing plain were utilized to characterize the paleoclimatic configuration of the study area and its possible relation to global control since the last interglaciation. We presented here a detailed grain-size record for the full length of Late Pleistocene, along with the optical simulated luminescence (OSL) dating. Our findings revealed that Late Pleistocene of the study area started approximately at 110 ka B.P. represented by the thick sediments of 31 m in Changping depression. Four sedimentary cycles were outlined in the core during Late Pleistocene, corresponding to marine isotope stage (MIS) 5 to 2. Controlled by regional geology and global climatic setting, eight paleoclimatic periods were identified simultaneously in the study area on the time scale of 10⁴ year, with the warm and moist climate being found at 110 — 96, 92 — 76, 67 — 56, and 28 — 18 ka B.P.. The climatic instabilities on a millennial scale in Late Pleistocene were characterized largely by the occurrence of 6 strong Heinrich events shown by comparatively coarse groups. These variations correlate well with those documented in the GRIP Greenland and in the Northern Atlantic Ocean, though more complex features may exist on the long time scale.     

S210线芦山-宝兴段崩塌灾害危险性分析及防治对策建议

＂4·20＂芦山地震发生后,作为进出地震灾区的生命线工程省道S210芦山-宝兴段多处发生崩塌滚石等次生地质灾害,堵断交通,威胁来往群众的生命安全,严重影响了抗震救灾和灾后的恢复重建。通过对此路段进行崩塌灾害现场考察,得出此路段的崩塌灾害多发生在大于40°的坡体上,坡向为SW、W和NW,易发岩性为灰岩、砂岩、白云岩和砾岩,切割深度多大于16m。通过GIS进行因子叠加分析,将此路段划分为3级危险度区域,并根据芦山地震灾区崩塌滚石灾害成因机制、分布与活动特征、成灾方式与危害对象,提出了相应的防治对策与建议。     

工业革命以来青藏高原与南极冰芯高分辨率甲烷记录对比研究

自工业革命以来全球大气CH4含量呈快速的增长趋势, 但达索普冰芯记录所显示的北半球中低纬度地区大气CH4增长的启动时间要晚于极地冰芯记录近100 a. 由于受北半球人类活动CH4排放、CH4在大气中的寿命及大气中CH4的传输等过程的影响, 最近150 a以来, 中低纬度大气CH4与南极大气CH4含量在不同的时段表现出不同的净积累量和增长速率, 且20世纪两次世界大战期间达索普冰芯记录明确显示出人类活动排放的减缓使大气CH4呈负增长. 对比研究认为, 到20世纪中叶人类活动的甲烷排放已达到极高值, 中低纬度大气中CH4增长率及年积累逐步趋于平稳且略有降低. 可以认定, 工业革命以来中低纬度地区大气CH4与南极大气CH4含量的变化在不同的时段在受控于人类活动影响的同时, CH4在大气中的行为和传输过程以及东亚中低纬度季风气候的影响决定了两地之间大气CH4含量变化存在显著的差异.     

Environmental significance of C/C and O/O ratios of modern land-snail shells from the southern great plains of North America

¹³C/¹²C and ¹⁸O/¹⁶O ratios of aragonite shells of modern land snails from the southern Great Plains of North America were measured for samples from twelve localities in a narrow east-west corridor that extended from the Flint Hills in North Central Oklahoma to the foothills of the Sangre de Cristo Mountains in Northern New Mexico, USA. Across the study area, shell δ¹⁸O values (PDB scale) ranged from −4.1‰ to 1.2‰, while δ¹³C values ranged from −13.2‰ to 0.0‰. δ¹⁸O values of the shell aragonite were predicted with a published, steady state, evaporative flux balance model. The predicted values differed (with one exception) by less than 1‰ from locality averages of measured δ¹⁸O values. This similarity suggests that relative humidity at the time of snail activity is an important control on the δ¹⁸O values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells. Correlated δ¹³C values of coexisting Vallonia and Gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern Great Plains plant ecology. Although there is considerable scatter, multispecies, transect average δ¹³C values of the modern aragonite shells are related to variations in the type of photosynthesis (i.e., C₃, C₄) in the local plant communities. The results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals, species, etc., and thus better represent the “neighborhood” scale temporal and/or spatial environmental variations of interest in studies of modern and ancient systems.     

Breakdown of hydrous ringwoodite to pyroxene and spinelloid at high P and T and oxidizing conditions

To get deeper insight into the phase relations in the end-member system Fe₂SiO₄ and in the system (Fe, Mg)₂SiO₄ experiments were performed in a multi-anvil apparatus at 7 and 13 GPa and 1,000–1,200°C as a function of oxygen fugacity. The oxygen fugacity was varied using the solid oxygen buffer systems Fe/FeO, quartz–fayalite–magnetite, MtW and Ni/NiO. The run products were characterized by electron microprobe, Raman- and FTIR-spectroscopy, X-ray powder diffraction and transmission electron microscopy. At fO₂ corresponding to Ni/NiO Fe-ringwoodite transforms to ferrosilite and spinelloid according to the reaction: 9 Fe₂SiO₄ + O₂ = 6 FeSiO₃ + 5 Fe_2.40Si_0.60O₄. Refinement of site occupancies in combination with stoichiometric Fe³⁺ calculations show that 32% of the total Fe is incorporated as Fe³⁺ according to 474k70n/269_2008_281_Article_IEq1.gif" alt="$$ \left ( {{\text{Fe}}_{1.60}^{2 + } {\text{Fe}}_{0.40}^{3 + } } \right)^{\text{VI}} \left ( {{\text{Si}}_{0.60} {\text{Fe}}_{0.40}^{3 + } } \right)^{\text{IV}} {\text{O}}_{4} . $$" align="middle" border="0"> From the Rietveld refinement we identified spl as spinelloid III (isostructural with wadsleyite) and/or spinelloid V. As we used water in excess in the experiments the run products were also analyzed for structural water incorporation. Adding Mg to the system increases the stability field of ringwoodite to higher oxygen fugacity and the spinel structure seems to accept higher Fe³⁺ but also water concentrations that may be linked. At oxygen fugacity corresponding to MtW conditions similar phase relations in respect to the breakdown reaction in the Fe-end-member system were observed but with a strong fractionation of Fe into spl and Mg into coexisting cpx. Thus, through this strong fractionation it is possible to stabilize very Fe-rich wadsleyite with considerable Fe³⁺ concentrations even at an intermediate Fe–Mg bulk composition: assuming constant K _D independent on composition and a bulk composition of x _Fe = 0.44 this fractionation would stabilize spl with x _Fe = 0.72. Thus, spl could be a potential Fe³⁺ bearing phase at P–T conditions of the transition zone but because of the oxidizing conditions and the Fe-rich bulk composition needed one would expect it more in subduction zone environments than in the transition zone in senso stricto.

明矾石综合利用途径的探析和热熔提Al的试验研究

明矾石综合利用的研究,有多种方法可供参考,通常是利用明矾石中的Ｋ、Ｓ、Ａｌ三种元素。碱熔法从明矾石中提Ａｌ的研究 从明矾石中提Ａｌ的物理工作参数和综合利用明矾石的方向。     

铵(氮)在岩石和矿物中地球化学行为研究进展

地壳中的氮大都以NH4 储存在矿物中.由于成岩时含氮有机物质的分解作用,氮广泛分布在沉积岩和低级变质岩中;在岩浆岩和变质岩中,氮主要以NH4 存在于含钾硅酸盐(长石和云母类)中;岩浆岩的δ(15N)值和氮浓度明显地不同于沉积物和变沉积岩,主要是由于有机物的缺乏.具有明显铵含量的火成岩主要是含钾矿物的深成岩.因而NH4 可以作为一个"示踪元素"而用于成矿作用等方面的研究.文章还提出了未来的研究方向.