Renewable, controlled and environmentally safe phosphorus release in soils from mixtures of NH4 +-phillipsite tuff and phosphate rocks

̳4;The renewable and controlled-release fertilization system investigated here uses NH₄ ⁺-exchanged phillipsite tuff, from Jordan, to help in the dissolution of phosphate rock. Accordingly, controlled and renewable soluble nitrogen, phosphate and Ca are released as nutrients for plants. NH₄ ⁺ phillipsite can sequester Ca ions released by the dissolution of phosphate rock, therefore, leading to further phosphate rock dissolution. In this study the results show that the amount of phosphate released is more than that released by phosphate rock alone. This method offers an alternative to the use of highly soluble fertilizers and may avoid environmental problems associated with their extensive use in agriculture. Received: 22 May 1997 · Accepted: 12 August 1997     

EH4连续电导率成像技术在矿产勘查中的应用——以内蒙古阿吉勒铜铅锌多金属矿床为例

阿吉勒矿区是新发现的以铜铅锌为主的多金属矿点.EH4连续电导率测量解析度高,可精确探测地下1000 m范围内地质体的形态、规模、产状和埋深等信息.通过在阿吉勒矿区的应用,很好地反映了矿区深部地质体的构造特征,发现了与矿（化）体有关的电性异常,在查明深部地质体特征和寻找隐伏矿体方面取得了良好的效果.     

西安地铁四号线沿线地裂缝的灾害分析与对策研究

西安地裂缝是一种地区性的地质灾害现象。目前西安共发育有14条地裂缝。地铁四号线将穿越13条,给隧道施工造成了诸多考验。文章选取西安市地铁四号线沿线的地裂缝灾害作为研究对象。探讨了地裂缝对隧道工程的影响因素和致灾特点、以及相关的评估理论方法。最后针对地裂缝灾害特征以及工程特点提出若干防治措施,对于科学研究地裂缝的灾害特点、合理防治地裂缝的灾害发生具有一定的指导意义。     

Breakdown of hydrous ringwoodite to pyroxene and spinelloid at high P and T and oxidizing conditions

To get deeper insight into the phase relations in the end-member system Fe₂SiO₄ and in the system (Fe, Mg)₂SiO₄ experiments were performed in a multi-anvil apparatus at 7 and 13 GPa and 1,000–1,200°C as a function of oxygen fugacity. The oxygen fugacity was varied using the solid oxygen buffer systems Fe/FeO, quartz–fayalite–magnetite, MtW and Ni/NiO. The run products were characterized by electron microprobe, Raman- and FTIR-spectroscopy, X-ray powder diffraction and transmission electron microscopy. At fO₂ corresponding to Ni/NiO Fe-ringwoodite transforms to ferrosilite and spinelloid according to the reaction: 9 Fe₂SiO₄ + O₂ = 6 FeSiO₃ + 5 Fe_2.40Si_0.60O₄. Refinement of site occupancies in combination with stoichiometric Fe³⁺ calculations show that 32% of the total Fe is incorporated as Fe³⁺ according to 474k70n/269_2008_281_Article_IEq1.gif" alt="$$ \left ( {{\text{Fe}}_{1.60}^{2 + } {\text{Fe}}_{0.40}^{3 + } } \right)^{\text{VI}} \left ( {{\text{Si}}_{0.60} {\text{Fe}}_{0.40}^{3 + } } \right)^{\text{IV}} {\text{O}}_{4} . $$" align="middle" border="0"> From the Rietveld refinement we identified spl as spinelloid III (isostructural with wadsleyite) and/or spinelloid V. As we used water in excess in the experiments the run products were also analyzed for structural water incorporation. Adding Mg to the system increases the stability field of ringwoodite to higher oxygen fugacity and the spinel structure seems to accept higher Fe³⁺ but also water concentrations that may be linked. At oxygen fugacity corresponding to MtW conditions similar phase relations in respect to the breakdown reaction in the Fe-end-member system were observed but with a strong fractionation of Fe into spl and Mg into coexisting cpx. Thus, through this strong fractionation it is possible to stabilize very Fe-rich wadsleyite with considerable Fe³⁺ concentrations even at an intermediate Fe–Mg bulk composition: assuming constant K _D independent on composition and a bulk composition of x _Fe = 0.44 this fractionation would stabilize spl with x _Fe = 0.72. Thus, spl could be a potential Fe³⁺ bearing phase at P–T conditions of the transition zone but because of the oxidizing conditions and the Fe-rich bulk composition needed one would expect it more in subduction zone environments than in the transition zone in senso stricto.

C_4植物的出现与全球环境变化

C4 光合作用途径 (C4 植物 )的出现和随后的扩展 ,是发生在新生代晚期的重大事件。这一事件是晚新生代全球环境演化的产物。C4 植物在某些生态系统中占据主导地位 ,又通过食物链 ,影响了动物 ,特别是食草动物的演化。以C4 植物为主的干草原环境甚至与人类的起源有着某种成因上的联系。C4 植物的出现对中新世以来全球环境变化和现代环境格局形成过程具有特殊的意义。文中就C4 植物出现和扩展的时间、C4 植物的分布和生态特征、C4 植物出现的环境背景、构造运动 ,特别是印度和欧亚板块碰撞以及由青藏高原强烈隆升引发的侵蚀作用和大气组分变化及其与C4 植物出现的联系等问题作了较为系统的综述。文章还介绍了中国北方现代草本植物的δ13 C值的最新研究结果 ,并就草本植物δ13 C值与环境参数之间可能的关系进行了初步讨论。     

4D architecture and tectonic evolution of the Laverton region,eastern Yilgarn Craton,Western Australia

The Laverton region, located in the eastern Yilgarn Craton (EYC) Western Australia, is second only to the Kalgoorlie region for gold endowment. The integration of high-density, potential-field data, regional- and camp-scale seismic reflection data, regional- and mine-scale structural analysis, and geochronologically-constrained stratigraphy, provided new insights into the 4D architecture and tectonic evolution of Laverton region.     

Structural changes and valence states in the MgCr<Subscript>2</Subscript>O<Subscript>4</Subscript>–FeCr<Subscript>2</Subscript>O<Subscript>4</Subscript> solid solution series

The influence on the structure of Fe²⁺ 48th/xxlarge8594.gif" alt="rarr" align="BASELINE" BORDER="0"> Mg substitution was studied in synthetic single crystals belonging to the MgCr₂O₄–FeCr₂O₄ series produced by flux growth at 900–1200 °C in controlled atmosphere. Samples were analyzed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption-, infrared- and Mössbauer spectroscopy. The Mössbauer data show that iron occurs almost exclusively as ^IVFe²⁺. Only minor Fe³⁺ (<0.005 apfu) was observed in samples with very low total Fe. Optical absorption spectra show that chromium with few exceptions is present as a trivalent cation at the octahedral site. Additional absorption bands attributable to Cr²⁺ and Cr³⁺ at the tetrahedral site are evident in spectra of end-member magnesiochromite and solid-solution crystals with low ferrous contents. Structural parameters a₀, u and T–O increase with chromite content, while the M–O bond distance remains nearly constant, with an average value equal to 1.995(1) Å corresponding to the Cr³⁺ octahedral bond distance. The ideal trend between cell parameter, T–O bond length and Fe²⁺ content (apfu) is described by the following linear relations: a₀=8.3325(5) + 0.0443(8)Fe²⁺ (Å) and T–O=1.9645(6) + 0.033(1)Fe²⁺ (Å) Consequently, Fe²⁺ and Mg tetrahedral bond lengths are equal to 1.998(1) Å and 1.965(1) Å, respectively.     

The Momentum 4-Vector Imparted by Gravitational Waves in Bianchi-Type Metrics

Considering the M48;ller, Weinberg and Qadir-Sharif's definitions in general relativity, we find the momentum 4-vector of the closed universe based on the Bianchi-type metrics. The momentum 4-vector (due to matter plus fields) is found to be zero. This result supports the viewpoints of Albrow and Tryon and extends the previous works by Cooperstock–Israelit, Rosen, Johri et al., Banerjee–Sen and Vargas who investigated the problem of the energy in Friedmann–Robertson–Walker universe and Salt?-Havare who studied the problem of the energy-momentum of the viscous Kasner-type space-times.     

利用空间测地技术结果估计地球平均下地幔粘性(英)

基于IEC－4G冰期后地壳反弹模型,和地球上Laurentia,Fennoscandia,Antarctica,andGreenland四大冰盖最近21000年以来的冰融参数,计算了对地球最大主转动惯量的影响△I33,并进而由现代空间测地技术观测资料分析得到的地球自转非潮汐加速项为约束,估计了地球平均下地幔（670km以下）粘性vLM为（0．9～2．5）·1022Pas,这个结果表明了vLM应具有1022Pas量级．