Low temperature alteration of magmatic Ni-Cu-PGE sulfides as a source for hydrothermal Ni and PGE ores: A quantitative approach using automated mineralogy

Magmatic Ni-Cu-PGE sulfide assemblages are almost ubiquitously comprised of pyrrhotite-pentlandite-chalcopyrite(-pyrite). Sulfide alteration is common during syn- or post-magmatic fluid interaction, usually replacing sulfides with amphiboles or serpentine. However, some are altered to a low temperature (<200 °C) hydrothermal assemblage of pyrite-millerite-chalcopyrite (PMC). An example is the Ni-Cu-PGE mineralisation in the Grasvally-Norite-Pyroxenite-Anorthosite (GNPA) Member, northern Bushveld Complex, which displays a continuum of mineralogical styles formed through progressive alteration: Style 1 primary pyrrhotite-pentlandite-chalcopyrite; which is altered to Style 2 pyrrhotite-pyrite-pentlandite-chalcopyrite; Style 3 pyrite-pentlandite-chalcopyrite; Style 4 pyrite-pentlandite-millerite-chalcopyrite; and Style 5 pyrite-millerite-chalcopyrite-cubanite. Modelling using CHILLER confirms this mineralogical sequence is thermodynamically possible at ∼200 °C. Quantitative characterisation using automated Energy-Dispersive X-ray spectroscopy mapping alongside in situ laser ablation analyses determined mineral proportions, major and trace element concentrations and deportments in each style. The early loss of pyrrhotite removes over half of the bulk Fe and S during the initial stages of PMC alteration, increasing Cu, Ni and PGE tenors of the remaining sulfides significantly. As water–rock interaction progresses, pyrrhotite is replaced by pyrite and pentlandite by millerite, with concurrent losses in Fe, S and Ni. Copper is lost throughout the alteration, and is most pronounced in the more advanced stages. The fluids responsible were most likely acidic and oxidised, with metals mobilised as chloride complexes. Using Rh as an immobile normalising element, the overall mass loss in the most altered samples is calculated to be up to 90%, consistent with textural relationships that indicate 40–90% volume loss from Styles 2–5, with sulfides replaced by secondary silicates, including phlogopite, quartz, chlorite, pyroxenes and minor amphiboles. Magnetite is not a significant alteration product and thus Fe is mobilised, or incorporated into silicates. Most trace elements present in the magmatic sulfide (the IPGE, Rh and Bi) remain in the sulfide phases, and are effectively transferred to pyrite during PMC alteration, except Pd, which remains in pentlandite, and is liberated from the sulfide assemblage when pentlandite disappears. Selenium tenors increase slightly with alteration, demonstrating that alteration decreases S/Se ratios. The significant mobilisation of Ni, Cu and Pd during PMC alteration produces fluids enriched in these elements that may represent a metal source for a number of enigmatic hydrothermal Ni deposits such as Avebury, Enterprise and Talvivaara, whose metal sources remain speculative. The PMC alteration of the GNPA Member may be specifically a source for the nearby Waterberg hydrothermal Pt deposit. Furthermore, this study has implications not only for magmatic ore deposits, but also for the general implications of sulfide transformation and metal transfer in ore systems in general.     

2010年10月大气环流和天气分析

2010年10月大气环流特征是:北半球高纬度地区存在两个极涡中心,强度偏弱;中高纬呈现4波型,其中乌拉尔山高压脊偏强,对应大片40 gpm的正距平区;副高强度偏弱.全国平均气温为10.1℃,比常年同期(9.6℃)偏高0.5℃.全国平均降水量为42.6 mm,比常年同期(37.0 mm)偏多15.1%.月内我国主要天气事...     

Eutrophication and hypoxia in four streams discharging in Guanabara Bay, RJ, Brazil, a case study

Four streams in the city of São Gonçalo, were sampled to evaluate their potential as sources of nutrients to Guanabara Bay aiming to contribute with the government program to decrease the levels of pollution in this area. Imbuaçu, Guaxindiba, Marimbondo and Brandoas streams were sampled in 2007, 2008 and 2009. The streams revealed to be hipereutrophic with severe limitation of primary production by nitrogen, as shown by the N/P molar ratio. Phosphate levels were abnormally high varying between 4.35 and 130.82 μM, whereas nitrate and nitrite ranged from 0.06 to 54.05 μM and from 0.28 to 19.23 μM, respectively. The streams also presented severe hypoxia and anoxia, with oxygen values varying from non-detected to 3.72 ml l⁻¹. Heavy loads of particulate suspended material were recorded in the studied streams, ranging between 6.00 and 400.00 mg l⁻¹. The streams were considered inexorable sources of nutrients, enhancing the severe eutrophication process in Guanabara Bay.     

青藏高原西部及东南周边地区季风前大气边界层结构分析

利用2008年JICA项目第一阶段(2008年2月25日至3月19日)的加密探空资料,分析了青藏高原西部及东南周边的大气边界结构特征.结果表明:青藏高原位温廓线均有明显的日变化,午后白天对流边界层达到最大,夜间稳定边界层在清晨达到最大.理塘和大理的稳定边界层绝大多数情况下在傍晚就开始发展,凌晨开始增强,清晨达到最大.对...     

0608号超强台风"桑美"强度变化位涡诊断分析

利用位涡(PV)收支诊断和质点轨迹追踪等方法对2006年影响中国最严重的超强台风"桑美"强度变化的成因进行了分析和研究.结果表明:台风中心四周的垂直风切变、涡度、散度变化对台风强度变化有重要影响;通过位涡诊断揭示出在台风增强和减弱时,凝结潜热、垂直平流和水平平流起着不同的作用.在台风迅速发展之前和迅速发展初期,凝结潜热...     

Mineralogy,geochemistry and age dating of shear zone-hosted Nb-Ta-, Zr-Hf-, Th-, U-bearing granitic rocks in the Ghadir and El-Sella areas,South Eastern Desert,Egypt

The rare metal minerals of mineralized altered granites within the Ghadir and El-Sella shear zones, are represented by betafite, U-minerals (uraninite and uranophane), zircon, monazite, xenotime, and rutile in the Ghadir shear zone. While they are columbite-tantalite minerals as ferrocolumbite, pyrochlore, and fergusonite, Th-minerals (cheralite, uranothorite, and huttonite monazite), Hf-zircon, monazite and xenotime in the El-Sella shear zone. Hf-zircon in the El-Sella and Ghadir shear zones (increasing from the core to the rim) contains high inclusions of U-Th, and REE minerals such as cheralite, uranothorite, huttonite monazite and xenotime especially in the El Sella shear zone. The rare-metal minerals, identified from peralkminous granites of the shear zones are associated with muscovite, quartz, chlorite, fluorite, magnetite, and biotite that are restricted to the two shear zones. Uraninite (low Th content) occurring in the Ghadir shear zone indicates the hydrothermal origin, but there are thorite, uranothorite, cheralite, and Hf-zircon in the El Sella shear zone, also indicating the hyrothermal proccess after magmatic origin. Compositional variations of Ta/(Ta+Nb) and Mn/(Mn+Fe) in columbite from 0.07-0.42 and 0.04-0.33, respectively, and Hf contents in zircon are so high as to be 12%, especially in the rim in the El Sella shear zone. This feature re-flects the extreme degree of magmatic fractionation. Four samples from the altered granites of the Ghadir shear zone also are very low in TiO2 (0.04 wt%-0.17 wt%), Sr [(82-121)×10-6], and Ba [(36-380)×10-6], but high in Fe2O3T (0.46 wt%-0.68 wt%), CaO (0.64 wt%-1.23 wt%), alkalis (8.59 wt%-8.88 wt%), Rb [(11-203)×10-6], Zr [(98-121)×10-6], Nb [(9-276)×10-6], Ta [(2-139)×10-6], U [(14-63)×10-6], Th [(16-105)×10-6], Pb [(13-32)×10-6], Zn [(7-8)×10-6], Y [(15-138)×10-6], Hf [(3-9)×10-6], and ∑REE [(81-395)×10-6, especially LREE [(70-322)×10-6]. They are very high in Zr/Hf (15.07-85.96) and Nb/Ta (7.17-21.48), and low in Rb/Sr (2.56-3.36) and Th/U (0.096-3.36). Four samples of the altered granites from the El Sella shear zone are very low in TiO2 (0.23 wt%-0.38 wt%), Sr [(47-933)×10-6], and Ba [(82-175)×10-6] , with high Fe2O3T (1.96 wt%-2.87 wt%), CaO (0.43 wt%-0.6 wt%), alkalis (4.46 wt%-10.7 wt%), Rb [(109-313)×10-6], Zr [(178-1871)×10-6], Nb [(11-404)×10-6], U [(56-182)×10-6], Th [(7-188)×10-6], Ta [(0.5-57)×10-6], Pb [(12-28)×10-6], Zn [(1-13)×10-6], Y [(62-156)×10-6], Hf [(3-124)×10-6], and ∑REE [(101-184)×10-6], especially HREE [(7-139)×10-6]. This is consistent with the very fractionated, fluorine-bearing granitic rocks that were altered and sheared in the El Sella shear zone. Zr/Hf (14.23-39.79) and Nb/Ta (1.98-7.01) are very high, and Rb/Sr (0.14-1.7) and Th/U (0.25-2.5) are low in the Ghadir shear zone. Field evidence, textural relations, and the composi-tion of ore minerals suggest that the main mineralizing event was magmatic (615+/-7 Ma, and 644+/-7 Ma CHIME monazite), especially in the El Sella shear zone, with later hydrothermal alteration and local remobilization of the high-field-strength elements.     

ENSO to multi-decadal time scale changes in East Australian Current transports and Fort Denison sea level: Oceanic Rossby waves as the connecting mechanism

The connection between East Australian Current (EAC) transport variability and Australia’s east coast sea level has received little treatment in the literature. This is due in part to the complex interacting physical processes operating in the coastal zone combined with the sparsity of observations available to improve our understanding of these possible connections. This study demonstrates a statistically significant (at the >90% level) relationship between interannual to decadal time scale variations in observed estimates of the EAC transport changes and east coast sea level measured at the high-quality, long record Fort Denison tide-gauge in Sydney Harbour, Australia (33°51′18″S, 151°13′32″E). We further demonstrate, using a linear reduced-gravity ocean model, that ENSO to decadal time-scale variations and the ocean-adjusted multi-decadal trend (approx. 1 cm/decade) in observed sea level at Fort Denison are strongly connected to modulations of EAC transports by incoming westward propagating oceanic Rossby waves. We show that EAC transport and Fort Denison sea level vary in a manner expected from both Tasman Sea generated Rossby waves, which account for the interannual and multi-annual variability, and remotely forced (from east of New Zealand) Rossby wave connections through the mid-latitudes, accounting for the ocean-adjusted multi-decadal trend observed at the New South Wales coast - with the regional-Tasman Sea forcing explaining the greatest overall proportion of EAC transport and sea-level variances.     

ECHAM5-Simulated Impacts of Two Types of El Nio on the Winter Precipitation Anomalies in South China

The authors used an atmospheric general circulation model(AGCM) of European Centre Hamburg Model(ECHAM5.4) and investigated the possible impacts of eastern Pacific(EP) and central Pacific(CP) El Nio on the winter precipitation anomalies in South China.A composite analysis suggested much more rainfall during the mature phase of EP El Nio than in the case of CP El Nio,and their corresponding observed wet centers to be located in the southeast coast and the region to the south of the Yangtze River,respectively.Results obtained on the basis of model-sensitive run imply that the modelsimulated rainfall anomalies agree well with the observation,and the magnitude of simulated rainfall anomalies were found to be reduced when the amplitude of sea surface temperature anomaly(SSTA) forcing of EP and CP El Nio was cut down.These results imply that the rainfall anomaly in South China is very sensitive not only to the type of El Nio but also to its intensity.     

超强台风“梅花”(1109号)的转向原因与预报分析

使用高空探测资料、FY-2C卫星云图、CIMSS气象卫星云图分析资料、历年台风路径、NCEP再分析资料,以及欧洲气象中心全球模式(EC)、日本气象厅全球模式(JMA)、国家气象中心全球模式(T639)、上海台风模式(SHTM)等预报资料,基于对2011年第9号台风"梅花"路径以及台风相似路径的预报等,分析影响台风"梅花"移动路径的环境系统演变,从中找出影响台风"梅花"移动转向的关键系统,分析和检验各数值模式对台风路径预报的结果;同时,研究台风路径相似预报方法。结果表明,位于日本的副热带高压南伸并与"梅花"东南侧的弱反气旋打通,引导气流中偏南风分量逐渐加大是"梅花"路径转向以致不在我国登陆的关键点;对数值模式预报的路径,应根据实况天气形势演变订正其预报误差;根据前期路径选多个关键区找台风相似路径更具参考性。