纳如松多矿集区电性结构特征及对成矿作用的约束

为了研究西藏纳如松多矿集区的电性结构特征和对成矿作用的约束,对覆盖矿集区的大地电磁测深数据进行全面的数据处理分析,得到了可靠的二维电性结构模型.研究结果表明,分别在深度为40~50 km,20~30 km和10 km处见高导体,推测这些高导体可能为部分熔融和水流体共同所致.由于纳如松多矿集区内矿床为岩浆-热液型,深部岩浆的上涌在成矿作用中起到关键作用,所以壳内高导体可能为与成矿有关岩浆房的电性痕迹,将这些高导体连起来可能代表着深部热液向上运移的古通道.电性结构主要体现了壳内高导体与区域成矿动力作用的关系,向上运移的富矿岩浆也可能通过局部的隐伏构造运移到Pb-Zn和Fe-Cu矿床的位置,再演化形成矿体.     

苏北淮安盐盆杨槐区块浦二段盐韵律特征及其古气候意义

盐湖沉积因具有成盐多期性和连续完整性的特点,是恢复成盐期古环境的重要研究对象,形成的不同级次盐韵律记录了不同尺度周期下古气候的干湿变化。上白垩统浦口组是淮安盐盆的主要含盐层系,对含盐层段盐韵律的研究有助于恢复该地区成盐期的古气候特征。在对资料井A1井取心段岩心精细观察和岩样矿物成分分析的基础上,分析资料井岩性的垂向变化,对浦口组盐韵律特征进行识别并划分。根据盐韵律对古气候的指示作用研究成盐期区块短尺度气候周期下的古气候变化。将淮安盐盆杨槐区块浦口组划分出Ⅰ、Ⅱ、Ⅲ、Ⅳ、Ⅴ级韵律,识别出完整的盐韵律组合,即泥岩—钙芒硝质盐岩—盐岩—钙芒硝质盐岩。含盐段中广泛发育暖温相矿物钙芒硝,指示气候特征为炎热的暖旱型。在Ⅳ级韵律尺度下建立了气候干湿性变化曲线,表明区块气候干湿性波动频繁,但仍以干旱为主,韵律厚度大致反映了气候波动频率大小。     

CO2驱微观可视化技术在超低渗储层中的应用可行性研究:以鄂尔多斯盆地为例

CO₂驱油是提高特低渗、超低渗油藏驱油效率的重要途径,但目前由于匮乏CO₂驱油微观可视化实验技术,制约了CO₂驱油微观机理研究及驱油效果评价。本研究提出特低、超低渗油藏高温高压下CO₂驱油微观可视化实验技术,为该类油藏CO₂驱油机理研究提供良好的研究手段。以鄂尔多斯盆地超低渗储层为例,利用首次研制成功的高温、高压、防暴真实砂岩模型,成功进行了CO₂驱油微观可视化实验研究,首次镜下观察不同相态CO₂在超低渗储层复杂孔喉中驱替原油的动态现象,重新认识超低渗油藏注CO₂驱油时不同孔喉结构中CO₂赋存状态和渗流规律。结果表明,储层微观孔喉结构,尤其是孔喉大小分布的均匀程度,对CO₂驱油效率的重要影响超出预期,直接决定着CO₂能否进入储层以及其后的渗流路径。CO₂驱油微观可视化实验技术可有效进行CO₂驱油微观机理研究及驱油效果评价研究,并为后期进行油藏矿场试验提供指导意见。     

ZTEM二维非线性共轭梯度反演研究

ZTEM(Z轴倾子电磁法)是一种天然场源的频率域航空电磁法,其特点是磁场垂直分量在空中机载平台测量,磁场水平分量在地面的固定基站测量,具有勘探深度大、速度快、成本低、覆盖面积大等技术优势。本文实现了ZTEM二维有限差分正演和二维非线性共轭梯度(NLCG)反演算法。研究对象是倾子资料,反演过程中通过解"拟正演"问题来避开雅克比矩阵的直接计算。通过理论模型合成数据反演试算,验证了ZTEM倾子资料二维NLCG反演算法的稳定性与可靠性。与大地电磁(MT) TE模式阻抗资料反演结果进行对比,发现在异常体横向边界的约束方面,ZTEM倾子反演比MT阻抗反演更具优越性。     

白云凹陷第三系储层中铁白云石的成因机理及与CO2活动的关系

白云凹陷第三系储层中发育大量的铁白云石,受研究区热流背景的影响,铁白云石主要见于高地温梯度地区埋深1000～3000m、地层温度60～130℃的浅—中部地层中及CO_2热流体活动区域。铁白云石的δ~(13)C值(-2.83‰～-1.83‰)具有无机成因的特征,与研究区气藏中幔源岩浆成因CO_2的δ~(13)C值较为一致,铁白云石的δ~(18)O值(-9.45‰～-5.37‰)和~(87)Sr/~(86)Sr值(0.7101～0.7161)也反映了其沉淀受到深部热流体活动的影响。以两口典型CO_2气井为例,储层中流体包裹体均一温度及蒙脱石向伊利石的演化特征证明储层经历了热流体侵入;CO_2热流体活动区域不仅是铁白云石集中分布地带,并出现片钠铝石+铁白云石+菱铁矿等示踪CO_2运移、聚集的自生矿物组合。地层中铁白云石、高岭石含量与气藏中CO_2的含量呈正相关关系,绿泥石含量与CO_2、铁白云石含量呈反消长关系。高地温梯度地区丰富的CO_2热流体活动是该地区储层中铁白云石沉淀与含量高的重要原因,无机岩浆成因CO_2是铁白云石沉淀的主要碳源,CO_2热流体充注造成绿泥石等黏土矿物异常转化,为铁白云石沉淀提供了所需的Fe~(2+)、Mg~(2+)离子。     

Mineralogy and geochemistry of marine glauconitic siliciclasts and phosphates in selected Cenomanian–Turonian units,Bohemian Cretaceous Basin,Czech Republic: Implications for provenance and depositional environment

Glauconitic siliciclastic rocks and phosphate components from the Pecínov Member of the Peruc–Korycany Formation (Upper Cenomanian), the lower part of the Bílá Hora Formation (Lower Turonian) and the lower part of the Teplice Formation (Upper Turonian) are studied. Geochemical indices suggest that the siliciclasts were derived from the weathering and recycling products of variable rock types of the Bohemian Massif, with a pronounced signature of felsic-derived source lithologies and a minor contribution from the sources of a chemically intermediate nature. Geochemical and mineralogical criteria suggest that the climate in the mid-Cretaceous was generally humid with possible intermittent arid episodes, which resulted in a long-term weathering of source rocks and the development of residual clay minerals in the source area. Several geochemical indications point toward highly reducing marine conditions during deposition of the mudstones, which are composed of quartz, glauconite, kaolinite, smectite, apatite and calcite. The glauconites show a highly mature character with >8 wt. % K₂O and bear evidence of long residence time near the sediment–water interface. They are depleted in Fe and rich in Al indicating a mixed layer mica–smectite as a precursor. Carbonate-fluorapatite is the only phosphate phase identified in the phosphate components, with up to 8 wt. % CO₃²⁻, excess F⁻ and significant amounts of Na⁺ and SO₄²⁻ in the apatite structure. A short-lived phosphogenic event(s) took place in the latest Cenomanian and involved large areas of the Bohemian Cretaceous Basin in association with the Oceanic Anoxic Event 2. The phosphate nodules were initially precipitated under suboxic conditions around the Cenomanian–Turonian boundary and were later reworked and emplaced in the earliest Turonian units. Phosphate coprolites mark another phosphogenic event in the early Upper Turonian. The development of the phosphate coprolites took place under variable redox conditions; the release of organically-bound phosphate and subsequent phosphatisation of fecal material took place under suboxic environment, followed by reworking in oxic realms.     

The Yamato-type (CY) carbonaceous chondrite group: Analogues for the surface of asteroid Ryugu?

We report new mineralogical, petrographic and noble gas analyses of the carbonaceous chondrite meteorites Y-82162 (C1/2_ung), Y-980115 (CI1), Y-86029 (CI1), Y-86720 (C2_ung), Y-86789 (C2_ung), and B-7904 (C2_ung). Combining our results with literature data we show that these meteorites experienced varying degrees of aqueous alteration followed by short-lived thermal metamorphism at temperatures of >500 °C. These meteorites have similar mineralogy, textures and chemical characteristics suggesting that they are genetically related, and we strongly support the conclusion of Ikeda (1992) that they form a distinct group, the CYs (“Yamato-type”). The CY chondrites have the heaviest oxygen isotopic compositions (δ¹⁷O ˜12‰, δ¹⁸O ˜22‰) of any meteorite group, high abundances of Fe-sulphides (˜10 ‒ 30 vol%) and phosphates, and contain large grains of periclase and unusual objects of secondary minerals not reported in other carbonaceous chondrites. These features cannot be attributed to parent body processes alone, and indicate that the CYs had a different starting mineralogy and/or alteration history to other chondrite groups, perhaps because they formed in a different region of the protoplanetary disk. The short cosmic-ray exposure ages (≤1.3 Ma) of the CY chondrites suggest that they are derived from a near-Earth source, with recent observations by the Hayabusa2 spacecraft highlighting a possible link to the rubble-pile asteroid Ryugu.     

西秦岭西成矿集区郭家沟超大型铅锌矿床成矿地质特征与控矿因素

郭家沟铅锌矿床位于甘肃省西成矿集区东端,是近年来在西秦岭新发现的超大型矿床,也是寻找厂坝式矿床的重大突破。该矿床的矿体主要赋存于中泥盆统安家岔组生物灰岩、硅化-铁白云石化灰岩以及千枚岩中,明显受层间断裂带的控制。由于其新发现不久,该矿床控矿因素和成因认识尚不清楚。文章在系统成矿地质特征观察的基础上,将成矿期次划分为沉积成矿期和热液成矿期,其中,热液成矿期包括:石英-闪锌矿-方铅矿-铁白云石(菱铁矿)阶段(Ⅰ)、石英-方铅矿-闪锌矿-碳酸盐阶段(Ⅱ)和方解石-硫化物阶段(Ⅲ)。在综合分析该矿床成矿过程与控矿因素的基础上,认为成矿受压扭性逆冲断层相关的断裂构造系统和褶皱构造变形带控制,硅化和铁镁碳酸盐化与铅锌矿化密切伴生,表现出热液交代蚀变矿化为主的特征,矿脉穿切矿区内的花岗岩墙,推测成矿作用发生在三叠纪或者更晚,后生热液成矿作用造成了铅锌的巨量富集。     

功能性Fe3O4磁纳米粒子的合成

本研究以PNIPAM(聚N-异丙基丙烯酰胺)为单体,先制备出来Fe3O4@SiO2纳米颗粒,再与DMP(十二烷基三硫代碳酸酯)链转移剂进行酯化反应,制备的产物作为新的链转移剂,在偶氮二异丁腈为引发剂的条件下,利用可逆加成-断裂链转移自由基聚合(RAFT)活性聚合法制备温度响应性磁纳米粒子。通过红外光谱法、核磁共振法对聚合物的结构进行表征,谱图表明成功地合成出所需的产物。通过扫描电镜对其进行分析,所得到的Fe3O4@SiO2-PNIPAM聚合物纳米颗粒分布比较均匀。     

水库水体二氧化碳分压研究进展

天然水体中存在同化二氧化碳(CO2)的光合作用,也存在释放CO2的微生物呼吸过程。地球表层水体与大气之间的CO2交换构成全球碳循环的一个重要环节。水-气之间CO2交换的方向和通量主要受大气圈和水体表层CO2分压(pCO2)的制约。水体pCO2值可以通过对近水面气体成分变化过程的现场仪器检测或者根据测定的水体化学参数运用经验公式计算求得。迄今对陆地水体,尤其河流筑坝形成的"蓄水河流"(下称水库)水体CO2动态研究中,由于水域及其近表层大气成分的时空多变,一般采用水化学参数计算方法求得水体的pCO2值。全球约70.97%的水库表层水体pCO2高于大气pCO2。全球尺度上水库表层水体pCO2自热带向寒温带逐渐递减;单个水库水体的pCO2一般呈现"出库>入库>库中"、pCO2随深度而增加的变化规律。水库表层水体pCO2的时间变化一般表现为"冬季>夏季、消融期>冰冻期、黑夜>白天"。水库水体的pCO2是其水化学平衡的结果,受水温、水体pH、水生生物活动以及外来水体的混合等多种因素影响,变化较为复杂。为精确量化水库水-气界面CO2交换通量,水文学、湖沼学、生态学和地球化学等领域的学者有必要合作,共同努力进行水库流域尺度的实地观测,完善水体溶解无机碳计算模型,深入探讨水库水体碳动力学机制,为全球碳循环研究和气候变化预测提供可靠的基础数据。