全文获取类型
收费全文 | 5929篇 |
免费 | 1189篇 |
国内免费 | 1691篇 |
专业分类
测绘学 | 644篇 |
大气科学 | 1091篇 |
地球物理 | 1342篇 |
地质学 | 3052篇 |
海洋学 | 1264篇 |
天文学 | 254篇 |
综合类 | 425篇 |
自然地理 | 737篇 |
出版年
2024年 | 31篇 |
2023年 | 98篇 |
2022年 | 236篇 |
2021年 | 263篇 |
2020年 | 301篇 |
2019年 | 358篇 |
2018年 | 279篇 |
2017年 | 278篇 |
2016年 | 314篇 |
2015年 | 327篇 |
2014年 | 427篇 |
2013年 | 463篇 |
2012年 | 359篇 |
2011年 | 436篇 |
2010年 | 300篇 |
2009年 | 408篇 |
2008年 | 426篇 |
2007年 | 416篇 |
2006年 | 443篇 |
2005年 | 358篇 |
2004年 | 329篇 |
2003年 | 253篇 |
2002年 | 222篇 |
2001年 | 170篇 |
2000年 | 184篇 |
1999年 | 160篇 |
1998年 | 150篇 |
1997年 | 137篇 |
1996年 | 125篇 |
1995年 | 103篇 |
1994年 | 99篇 |
1993年 | 76篇 |
1992年 | 79篇 |
1991年 | 45篇 |
1990年 | 48篇 |
1989年 | 22篇 |
1988年 | 24篇 |
1987年 | 8篇 |
1986年 | 14篇 |
1985年 | 11篇 |
1984年 | 12篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1954年 | 3篇 |
排序方式: 共有8809条查询结果,搜索用时 62 毫秒
901.
902.
We have performed X-ray Raman scattering (XRS) measurements on the oxygen K and silicon L absorption edges of four silica minerals: α-quartz, α-cristobalite, coesite, and stishovite. We have also calculated the
partial electron densities of states (DOSs) and compared these with the XRS spectra. This study demonstrates that the short-range
structure around the atom of interest strongly influences the XRS spectral features. Importantly, the oxygen K-edge XRS spectra are found to reflect the p-orbital DOS while the silicon L-edge spectra reflect the s- and d-orbital DOSs, even when a product of a momentum transfer and a mean radius of a electron orbit (1s for oxygen and 2p for silicon), Qr, is close to or larger than unity. Building on this, calculations of the partial DOSs for other silica phases are presented,
including ultra-high-pressure phases, which provide a good reference for further XRS study of silica and silicate minerals.
XRS measurements should be performed on not only either of oxygen or silicon but also on many kinds of constituent elements
to reveal the structural change of glasses/melts of silicates under extreme conditions. 相似文献
903.
Breakdown of hydrous ringwoodite to pyroxene and spinelloid at high P and T and oxidizing conditions
To get deeper insight into the phase relations in the end-member system Fe2SiO4 and in the system (Fe, Mg)2SiO4 experiments were performed in a multi-anvil apparatus at 7 and 13 GPa and 1,000–1,200°C as a function of oxygen fugacity.
The oxygen fugacity was varied using the solid oxygen buffer systems Fe/FeO, quartz–fayalite–magnetite, MtW and Ni/NiO. The
run products were characterized by electron microprobe, Raman- and FTIR-spectroscopy, X-ray powder diffraction and transmission
electron microscopy. At fO2 corresponding to Ni/NiO Fe-ringwoodite transforms to ferrosilite and spinelloid according to the reaction: 9 Fe2SiO4 + O2 = 6 FeSiO3 + 5 Fe2.40Si0.60O4. Refinement of site occupancies in combination with stoichiometric Fe3+ calculations show that 32% of the total Fe is incorporated as Fe3+ according to From the Rietveld refinement we identified spl as spinelloid III (isostructural with wadsleyite) and/or spinelloid V. As
we used water in excess in the experiments the run products were also analyzed for structural water incorporation. Adding
Mg to the system increases the stability field of ringwoodite to higher oxygen fugacity and the spinel structure seems to
accept higher Fe3+ but also water concentrations that may be linked. At oxygen fugacity corresponding to MtW conditions similar phase relations
in respect to the breakdown reaction in the Fe-end-member system were observed but with a strong fractionation of Fe into
spl and Mg into coexisting cpx. Thus, through this strong fractionation it is possible to stabilize very Fe-rich wadsleyite
with considerable Fe3+ concentrations even at an intermediate Fe–Mg bulk composition: assuming constant K
D independent on composition and a bulk composition of x
Fe = 0.44 this fractionation would stabilize spl with x
Fe = 0.72. Thus, spl could be a potential Fe3+ bearing phase at P–T conditions of the transition zone but because of the oxidizing conditions and the Fe-rich bulk composition
needed one would expect it more in subduction zone environments than in the transition zone in senso stricto.
相似文献
M. Koch-MüllerEmail: |
904.
Peter W. L. Vojak Clive Edwards Martin V. Jones 《Estuarine, Coastal and Shelf Science》1985,20(6):661-671
Water samples from the Tamar Estuary oxidized manganese when supplemented with Mn2+ (2 mgl−1). The rates of oxidation were depressed in the presence of various metabolic inhibitors. The effect of Mn2+ and temperature on the rate of manganese oxidation suggested that a biological process was largely responsible for converting Mn2+ to Mn4+. Rates of manganese oxidation were much higher in freshwater (3·32 μgl−1 h−1 in water containing 30 mgl−1 of suspended matter) than in saline water (0·7 μgl−1 h−1 in water of salinity 32‰) containing the same amount of particulate matter. The rate of manganese oxidation was proportional to the particulate load (up to 100 mgl−1 particulates). 相似文献
905.
Large areas of Europe, especially in the Alps, are covered by carbonate rocks and in many alpine regions, karst springs are important sources for drinking water supply. Because of their high variability and heterogeneity, the understanding of the hydrogeological functioning of karst aquifers is of particular importance for their protection and utilisation. Climate change and heavy rainfall events are major challenges in managing alpine karst aquifers which possess an enormous potential for future drinking water supply. In this study, we present research from a high-alpine karst system in the UNESCO Biosphere Reserve Großes Walsertal in Austria, which has a clearly defined catchment and is drained by only one spring system. Results show that (a) the investigated system is a highly dynamic karst aquifer with distinct reactions to rainfall events in discharge and electrical conductivity; (b) the estimated transient atmospheric CO2 sink is about 270 t/a; (c) the calculated carbonate rock denudation rate is between 23 and 47 mm/1000a and (d) the rainfall-discharge behaviour and the internal flow dynamics can be successfully simulated using the modelling package KarstMod. The modelling results indicate the relevance of matrix storage in determining the discharge behaviour of the spring, particularly during low-flow periods. This research and the consequent results can contribute and initiate a better understanding and management of alpine karst aquifers considering climate change with more heavy rainfall events and also longer dry periods. 相似文献
906.
Previous studies on multiple sulfur isotopes (32S, 33S, and 34S) in sedimentary pyrite at the end-Permian suggested a shoaling of anoxic/sulfidic deep-water contributing to the extinction. This scenario is based on an assumption that the sedimentary sulfur cycle was largely controlled by benthos activity, though a stratigraphic correlation between the sulfur records and ichnofabrics of the sediments at the end-Permian has not yet been examined. We report the multiple sulfur isotopic composition of pyrite in the Permian–Triassic boundary interval at Chaotian, South China. Our data can be generally explained by a mixing of sulfur in sulfide from two different sources: one produced via sulfate reduction in an open system with respect to sulfate and the other produced in a closed system. In particular, the former with the substantially low δ34S (<−40 ‰) and high ∆33S (up to +0.100 ‰) values was likely produced via water-mass sulfate reduction or via sulfate reduction in oxic sediments with common burrows. The frequent occurrence of small pyrite framboids (mostly <5 μm in diameter) in the Lopingian (Late Permian) Dalong Formation of deep-water facies supports the enhanced water-mass sulfate reduction in an anoxic deep-water mass. The negative ∆33S values are observed only in the oxic limestones, and no substantial ∆33S change is observed across the extinction horizon despite of the disappearance of bioturbation. Our results are apparently inconsistent with the previous shoaling model. We expand the model and infer that, when the deep-water was sulfidic and its shoaling rate was high, a substantial amount of hydrogen sulfide (H2S) was supplied onto the shelf via the shoaling; that resulted in the positive ∆33S value of the bulk sediments. The observed ∆33S variation on a global scale suggests a substantial variation in H2S concentration and/or in upwelling rate of shoaling deep-waters during the Permian–Triassic transition. 相似文献
907.
该文就总量控制工作进行理论探讨,提出控制平均浓度的排污等效模型,同时对计算区段控制浓度的确定进行定量化模型研究。该模型简便、易操作、实用性强,具有一定的理论意义和实用价值。 相似文献
908.
909.
910.
M. Mapelli B. Moore E. Ripamonti L. Mayer M. Colpi L. Giordano 《Monthly notices of the Royal Astronomical Society》2008,383(3):1223-1231
We simulate the collisional formation of a ring galaxy and we integrate its evolution up to 1.5 Gyr after the interaction. About 100–200 Myr after the collision, the simulated galaxy is very similar to observed ring galaxies (e.g. Cartwheel). After this stage, the ring keeps expanding and fades. Approximately 0.5–1 Gyr after the interaction, the disc becomes very large (∼100 kpc) and flat. Such extended discs have been observed only in giant low surface brightness galaxies (GLSBs). We compare various properties of our simulated galaxies (surface brightness profile, morphology, H i spectrum and rotation curve) with the observations of four well-known GLSBs (UGC 6614, Malin 1, Malin 2 and NGC 7589). The simulations match quite well the observations, suggesting that ring galaxies could be the progenitors of GLSBs. This result is crucial for the cold dark matter (CDM) model, as it was very difficult, so far, to explain the formation of GLSBs within the CDM scenario. 相似文献