Actinic flux and photolysis frequency comparison computations using the model PHOTOGT

The accurate radiative transfer model GOMETRAN, initially designed to yield radiances at TOA in the wavelength range 240–790 nm, has been extended to allow for the computation of actinic fluxes down to 175 nm and for the calculation of photolysis frequencies in the atmosphere. The capability of the extended model PHOTOGT (PHOTOGOMETRAN) is demonstrated in a number of successful comparison studies both with recent experiments (ground-based, balloonborne, airborne) and model calculations of radiances, actinic fluxes and photolysis frequencies in the stratosphere and troposphere. In an atmospheric case study, the impact of new quantum yield data for the O₃ » O₂+O(¹ d) photodissociation channel on the photolytic production of O(¹ d) atoms in the lower atmosphere has been quantified.     

RATIONAL UTILIZATION OF MOUNTAIN SOILS IN SOUTHEAST QINGHAI-XIZANG (TIBETAN)PLATEAU

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Subarcsec 10μm imaging of bipolar flow sources

We have started a program of high-resolution (0.4/pixel) 10m imaging of bipolar outflow sources using the 10m camera CAMIRAS. We present recent results obtained at the Canada France Hawaii Telescope which reveal extended emission or IR companions in several luminous objects. The extended emission we detected probably arises from transiently heated very small grains, while the newly discovered companions could contribute significantly to the outflow activity and extended far-IR emission usually attributed to the main optical source.     

Sub-arcsec 10 μm imaging of β pictoris and other star disk candidates

We have used the ESO 10 m camera, TIMMI, to image with a very high angular resolution (PFoV: 0.3; FWHM:0.9) several main-sequence star disk candidates. Information on the -Pictoris dust disk has been obtained in a region largely inaccessible to previous observations: 0–80 AU, with a resolution of about 5 AU after deconvolution. Another promising target for 10 m imaging, 51 Ophiuchi, appears point-like.based on data collected at the European Southern Observatory (ESO), La Silla, Chile     

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

地下水非稳定流的LTFAM算法

渗流域内应用拉普拉斯变换(LT)建立相应的有限分析(FAM)方程,顾及渗流域内地下水流的初始条件和边界条件,可在LT空间构成一个封闭的以水头像函数为变量的线性方程组。将此方程组所得的解,通过Stehfest数值反演公式,可归化为时间域的解(水头)。由于时间t被隐含在数值方程内,从而克服了传统数值法按时段(△t)逐步迭代的缺陷,提高了计算效率,也为用嵌入法建立地下水流管理模型提供了一条捷径。     

随钻测录井地质导向二维分解实时绘图方法

根据随钻测录井实时地质导向和大斜度、水平井评价成图技术需求，针对传统绘图方法存在的弊端，提出了将测录井信息、井眼轨迹和地质模型进行二维分解的实时绘图方法。针对二维分解绘图方法绘图时空复杂度较高的问题，给出了不同事件驱动下的局部实时计算和拷屏重绘算法，控制了对CPU和内存的消耗、提高了绘图效率，消除了实时绘图的闪烁和卡顿现象。应用实例表明，二维分解实时绘图方法能够实现大尺度随钻测录井地质导向图形的流畅、无卡顿实时绘图，可提高大斜度、水平井储层模型评价的刻画精度和时效。     

Channel overflows of the Pōhue Bay flow,Mauna Loa,Hawai'i: examples of the contrast between surface and interior lava

A number of overflows from a large lava channel and tube system on the southwest rift zone of Mauna Loa were studied. Initial overflows were very low viscosity gas-rich phoehoe evidenced by flow-unit aspect ratios and vesicle sizes and contents. Calculated volumetric flow-rates in the channel range between 80 and 890 m³/s, and those of the overflows between 35 and 110 m³/s. After traveling tens to hundreds of meters the tops of these sheet-like overflows were disrupted into a surface composed of clinker and phoehoe fragments. After these 'a' overflows came to rest, lava from the interiors was able to break out on to the surface as phoehoe. The surface structure of a lava flow records the interaction between the differential shear rate (usually correlated with the volumetric flow-rate) and viscosity-induced resistance to flow. However, the interior of a flow, being better insulated, may react differently or record a later set of emplacement conditions. Clefts of toothpaste lava occurring within fields of clinker on proximal-type 'a' flows also record different shear rates during different times of flow emplacement. The interplay between viscosity and shear rate determines the final morphological lava type, and although no specific portion of lava ever makes a transition from 'a' back to phoehoe, parts of a flow can appear to do so.     

Diagenesis of vascular plant organic matter components during burial in lake sediments

Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither ¹³C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.