松辽盆地庆深气田异常氢同位素组成成因研究

对松辽盆地徐家围子断陷庆深气田天然气组分、碳氢同位素和稀有气体同位素的分析表明,天然气以烷烃气为主,烷烃气碳同位素组成随着碳数增加呈变轻趋势,且δ13C1＆gt;-30‰, R/Ra一般大于1.0,δ13CCO2值介于-16.5‰~-5.1‰之间;氢同位素组成δD1=-205‰~-197‰,平均值为-203‰,δD2=-247‰~-160‰,平均值为-195‰,δD3=-237‰~-126‰,平均值为-163‰,且存在氢同位素组成倒转现象,即δD1＆gt;δD2＆lt;δD3。根据对庆深气田天然气不同地球化学特征分析,认为该气田烷烃气中重烃主要为有机成因,而 CH4有相当无机成因混入。庆深气田烷烃气氢同位素组成具有 CH4变化小,而重烃（δD2,δD3）变化大的特点。根据与朝阳沟地区天然气烷烃气氢同位素组成对比分析,认为 CH4主要表现为无机成因,而重烃气（δD2,δD3）主要为有机成因,且无机成因CH4氢同位素组成重于有机成因CH4。     

青海湖沙柳河流域土壤水氢氧稳定同位素组成与土壤贮水量关系北大核心CSCD

氢氧稳定同位素技术和土壤贮水量是探究区域土壤水分特征的有效手段。基于青海湖沙柳河流域土壤水氢氧稳定同位素组成(δ2H和δ^(18)O)和土壤贮水量数据,分析其在流域的空间分布特征,探讨土壤水氢氧稳定同位素组成和土壤贮水量之间的相关性。结果表明:(1)沙柳河流域土壤水δ^(18)O值从西北向东南呈现富集—贫化—富集的趋势;土壤水d-excess值在流域南部最低,在流域东北部支流上游地区最高。(2)土壤贮水量在流域空间分布上表现为北高南低的趋势。(3)土壤水δ^(18)O值、d-excess值与土壤贮水量间存在分段线性关系。当0—30 cm各土层土壤贮水量≤30 mm时,各土层土壤贮水量与土壤水δ^(18)O值分别显著负相关、与d-excess值显著正相关。青海湖沙柳河流域自然地理环境和植被特征的空间差异导致其土壤水氢氧稳定同位素组成和土壤贮水量表现出明显的空间变异性。温度变化对土壤水氢氧稳定同位素组成与土壤贮水量之间的相关性影响是通过其对土壤蒸发作用的影响来实现的。     

蓬莱9-1潜山岩性组成及其对储层发育的控制

PL9-1潜山油藏是渤海湾盆地储量最大的古潜山油气藏之一,探明储量过亿吨.该油藏发育于庙西北凸起鞍部的中生界花岗岩侵入体顶部.凸起端部变质岩中没有油气发现.油气的分布受岩性控制明显.综合岩心观察、薄片鉴定、X粉晶衍射以及常量元素分析等技术手段,通过对比不同岩石类型的矿物组成、储集空间类型及发育程度,探讨了岩性组成对储层发育的控制作用.研究表明,变质岩中裂缝和孔隙均不发育,不能形成有效储层.花岗岩主要储集空间类型为孔隙-裂缝型,总体具有从砂质风化带→砾质风化带→裂缝带→基岩带,储集空间组合类型从孔隙→孔隙+裂缝→裂缝→不太发育的微裂缝的变化特征.储层厚度大,成层性强,可形成有效的规模性储层.花岗岩与变质岩的矿物组成差异控制了研究区优质储层的发育.变质岩中长石含量极低,不能形成溶蚀孔隙,较高含量(30%~50%)的片状矿物使其在应力作用下易发生塑性变形,不易产生裂缝.花岗岩具有很高的长石含量和含量很低的片状矿物,不仅容易被风化并产生溶蚀孔隙,而且易于发生脆性变形形成裂缝.      

俄罗斯奥斯泊矿区(11~#矿)碧玉的宝石矿物学研究

本文以采自俄罗斯奥斯泊矿区11#矿的碧玉样品作为研究对象,采用常规的宝石学测试、傅里叶变换红外光谱仪、扫描电子显微镜、X射线粉晶衍射仪,对其表面微观形貌、矿物组成、化学成分特征进行了较全面的研究。研究表明,俄罗斯奥斯泊11#矿区碧玉主要的矿物组成为透闪石,内含的黑色点状矿物为铬铁矿。结晶度较好,矿物结晶颗粒局部具有定向性,结构主要为毛毡状纤维交织变晶机构,使其具很高的韧性。俄罗斯奥斯泊11#矿碧玉的主要化学成分为MgO、SiO2、CaO,与透闪石类玉一致,与含铁量较高的新西兰碧玉不同,其主要矿物成分为透闪石。     

A review on bivalve shell,a tool for reconstruction of paleo-climate and paleo-environment

Environmental information can be extracted from bivalve shell geochemistry. In this review, the latest research progress and the existing problems as well as the focus of future research on stable oxygen and carbon isotopic composition and trace elemental ratios of bivalve shell were investigated. Oxygen isotopic signatures of bivalve shell have been proved precipitate in equilibrium with their host water and used as a robust tool to reconstruct ancient water temperature. In order to reconstruct quantitative paleo-temperature information, the future research on bivalve shell oxygen isotope should combine with the study of ancient water oxygen isotope. Metabolic effect pre- vents the direct application of stable carbon isotopic composition of bivalve shell from extracting dissolved inorganic carbon information. The contribution of metabolic carbon to bivalve shell is species specific. Stable carbon isotopic composition of dissolved inorganic carbon could be reconstructed if the metabolic contribution could be accounted for. Explore ways to remove contribution of metabolic effects to bivalve shell is the future focus of the research. There is no consensus on the effect of temperature on bivalve trace element ratios, which may be also species spe- cific, each proxy should ideally be validated and calibrated for each species before being used to interpret past climate and environmental conditions. Future research needs to pay attention to the bivalve shell biomineralization process, which controlled bivalve shell trace element ratios. Cultivation experiment is an important way to obtain the relevant conclusions.     

Science揭示全球生物多样性的变化规律

正2014年4月18日,Science杂志发表了题为《时序数据集揭示生物多样性变化规律,未发现生物多样性系统性丧失》(Assemblage Time Series Reveal Biodiversity Change but Not Systematic Loss)的文章。文章基于1874年以来全球范围内监测得到的100个时序变化数据集,评估了随着时间的推移全球范围内物种的变化规律。研究结果表明,生物群落正在演替进程中,生态系统服务功能正在发生变化,但全球范围内的生物多样性丧失并不存在系统一致性。生物多样性可通过α多样性指数和β多样性指数来反映。其中,α多样性主要关注相对均匀的局域生     

http://www.sciencedirect.com/science/article/pii/S1674987113001114

The Deccan Syneclise is considered to have significant hydrocarbon potential.However,significant hydrocarbon discoveries,particularly for Mesozoic sequences,have not been established through conventional exploration due to the thick basalt cover over Mesozoic sedimentary rocks.In this study,near-surface geochemical data are used to understand the petroleum system and also investigate type of source for hydrocarbons generation of the study area.Soil samples were collected from favorable areas identified by integrated geophysical studies.The compositional and isotopic signatures of adsorbed gaseous hydrocarbons(methane through butane) were used as surface indicators of petroleum micro-seepages.An analysis of 75 near-surface soil-gas samples was carried out for light hydrocarbons(C1-C4) and their carbon isotopes from the western part of Tapti graben,Deccan Syneclise,India.The geochemical results reveal sites or clusters of sites containing anomalously high concentrations of light hydrocarbon gases.High concentrations of adsorbed thermogenic methane(C_1 = 518 ppb) and ethane plus higher hydrocarbons(ΣC_(2+) = 977 ppb) were observed.Statistical analysis shows that samples from 13% of the samples contain anomalously high concentrations of light hydrocarbons in the soil-gas constituents.This seepage suggests largest magnitude of soil gas anomalies might be generated/source from Mesozoic sedimentary rocks,beneath Deccan Traps.The carbon isotopic composition of methane,ethane and propane ranges are from-22.5‰ to-30.2‰ PDB,-18.0‰to 27.1‰ PDB and 16.9‰-32.1‰ PDB respectively,which are in thermogenic source.Surface soil sample represents the intersection of a migration conduit from the deep subsurface to the surface connected to sub-trappean Mesozoic sedimentary rocks.Prominent hydrocarbon concentrations were associated with dykes,lineaments and presented on thinner basaltic cover in the study area,which probably acts as channel for the micro-seepage of hydrocarbons.     

Geochemical characteristics and possible origin of natural gas in the Taibei Depression,Turpan-Hami Basin,China

292 chemical composition data and 82 isotopic composition data of gas samples collected from the Taibei Depression of the Turpan-Hami Basin, West China, were used in the study of their origin. Non-hydrocarbon gas is poor in most samples whereas abundant nitrogen in some samples is positively correlated with δ13C1. Although methane is the main constituent, higher molecular gaseous hydrocarbons, from ethane to pentane, are detected in most samples, in accordance with the distribution of oil reservoirs. The stable carbon isotope ratios of methane, eth-ane and propane are defined as d13C1: -45.5‰ to -33.5‰, d13C2: -30.2‰ to -10.5‰, and d13C3: 27.6‰ to -11.2‰, respectively. According to the distribution of carbon isotope ratios, 2 families of gas can be grouped, most showing normal distribution of carbon isotopes, and others having obvious heavier carbon isotopes and being of abnormal distribution. Based on the isotopic composition, the disagreement between the relationship of Δ(d13C1-d13C2) and d13C2 and that of Δ(d13C1-d13C2) and d13C2, and the calculated Ro, there are oil-associated gas, coal-derived gas and mixture of them. Other samples with obviously heavier isotopic compositions from the Yanmuxi oilfield of the Taibei Depression have been degraded by organisms.     

Source and commingling features of light oils from the Chepaizi uplift in the Junggar Basin,Northwest China

Geochemical composition characteristics of light oils from the Tertiary in the west of the Chepaizi uplift in the Junggar basin, northwest China, are distinct from those of biodegraded oils derived from the Permian in the study area and crude oils from some adjacent oil fields such as the Chepaizi and Xiaoguai oilfields. Oil source correlation shows that light oils in the study area have similar n-alkane and isoprenoid distribution patterns and carbon isotope compositions with the coal-derived oils from the Jurassic, and display obvious discrepancy on biomarker composition characteristics with the Cretaceous source rock extracts, inferring that they are probably the mixed oils from the Jurassic coal measures and Cretaceous source rocks. In this study, combined with the geochemical data of coal-derived oils from the Jurassic and Cretaceous source rocks or crude oils from the Cretaceous, the source and commingling features of the Tertiary crude oils of Well Pai 2 and Well Pai 8 were investigated. The proportion of the two sources in the mixed crude oils was estimated, and the hydrocarbon accumulation pattern of reservoirs in the study area was established.     

天然实验流域降雨径流现象发生的悖论

作为滁州水文实验系统一部分的1号天然实验流域,面积7897m2,以安山岩为基底,上覆平均厚度2.46m的第四系沉积物。实测了包括地面径流和地面下径流的各种降雨径流响应,后者包括来自非饱和带的壤中流和饱和带的地下水径流。表明这些径流成分有着复杂的组合类型,主要是以地面径流为主的SR型和以地面下径流为主的SSR型,以及中间的和演化的类型。SR型实例中的地面径流量可占总径流的65%,而SSR实例中的地面下径流量可有90%。主要降水的7月,地面下贡献占54.5%,其中地下水径流即占33%。大部分地面径流与降水的18O组成有不小的差异,比较了同时进行测验的3个实验流域,在1400min的降水径流过程中,降水的平均δ18O为-1.210%,而同期地面径流的平均δ18O,2号水文山流域(512m2)为-1.132%,1号南大洼天然流域为-1.065%,3号只有薄层风化碎屑的牵牛花流域(4573m2)为-0.801%。这质疑了现行同位素流量过程线划分方法8个假定中的两个:地面径流的同位素组成不同于降水,天然流域尤其如此;各种水源在汇集过程中的同位素分馏影响并非都可忽略不计。实验流域因降水而产生径流,但所产生的径流却有着非本次降水的组分,这一降水径流悖论发生于各个实验流域。SR型和SSR型总的非本次降水组分分别达16%和64%。