湛江地区一次冷锋型海雾微物理特征

利用2010年3月31日—4月2日冷锋天气系统影响下湛江海雾综合观测资料,分析了海雾的微物理特征及海雾过程中气溶胶粒子谱的演变特征。结果表明,海雾的生消与风场密切相关,海雾生成和发展与较强的ESE气流相联系,而弱的NE气流则会促使海雾减弱或消散。湛江海雾的雾滴数浓度为100~102cm-3,液态含水量为0.001~0.232 g·m-3,雾滴平均半径小于10μm,雾滴峰值半径多位于1.4μm。海雾雾滴谱分布以单调递减谱为主,谱宽超过20μm,且雾发展过程中雾滴谱谱宽存在突然增宽和迅速减小的现象。海雾过程中雾滴数浓度的变化主要是由半径小于5μm的雾滴数密度变化引起的。海雾过程对气溶胶粒子的湿清除效果并不显著,雾过程中粒径小于0.1μm和大于4μm的气溶胶粒子数密度显著减少,但在雾消散后又迅速恢复到雾发生前的水平。     

The Role of the Aerosol Indirect Effect in the Northern Indian Ocean Warming Simulated by CMIP5 Models

The northern Indian Ocean （NIO） experienced a decadal-scale persistent warming from 1950 to 2000, which has influenced both regional and global climate. Because the NIO is a region susceptible to aerosols emis- sion changes, and there are still large uncertainties in the representation of the aerosol indirect effect （ALE） in CMIP5 （Coupled Model Intercomparison Project Phase 5） models, it is necessary to investigate the role of the AIE in the NIO warming simulated by these models. In this study, the authors select seven CMIP5 models with both the aerosol direct and indirect effects to investigate their performance in simulating the basin-wide decadal-scale NIO warming. The results show that the decreasing trend of the downwelling shortwave flux （FSDS） at the surface has the major damping effect on the SST increasing trend, which counteracts the warming effect of greenhouse gases （GHGs）. The FSDS decreasing trend is mostly contrib- uted by the decreasing trend of cloudy-sky surface downwelling shortwave flux （FSDSCL）, a metric used to measure the strength of the AIE, and partly by the clear-sky surface downwelling shortwave flux （FSDSC）. Models with a relatively weaker AIE can simulate well the SST increasing trend, as compared to observation. In contrast, models with a relatively stronger AIE produce a much smaller magnitude of the increasing trend, indicat- ing that the strength of the AIE in these models may be overestimated in the NIO.     

对流层气溶胶的直接气候效应对平流层的影响

通过WACCM-3模式中气溶胶光学厚度与卫星资料的对比发现,模式可以很好地再现全球气溶胶的主要分布特征,但在一些区域还存在数值上的差异。利用数值试验研究对流层气溶胶的直接气候效应对平流层气候的影响,结果表明:对流层气溶胶对平流层气候有明显影响,平流层化学过程在这一影响中起重要作用,而对流层气溶胶对平流层辐射的影响不是其直接气候效应对平流层影响的主要原因。其机制可能是对流层气溶胶改变对流层的辐射平衡,影响对流层的温度和大气环流,进而影响行星波的上传,使得平流层气候发生变化;影响区域主要位于高纬度和极地地区,南半球的变化比北半球大,温度变化最大达10 K,纬向风变化最大可达12 m/s,臭氧体积分数最多减少0.8×10-6。     

The Characteristics of Atmospheric Ice Nuclei Measured at Different Altitudes in the Huangshan Mountains in Southeast China简

The concentration of ice nuclei （IN） and the relationship with aerosol particles were measured and analyzed using three 5-L mixing cloud chambers and a static diffusion cloud chamber at three altitudes in the Huangshan Mountains in Southeast China from May to September 2011.The results showed that the mean total number concentration of IN on the highest peak of the Huangshan Mountains at an activation temperature （Ta） of-20℃C was 16.6 L-1.When the supersaturation with respect to water （Sw） and with respect to ice （Si） were set to 5％,the average number concentrations of IN measured at an activation temperature of-20℃C by the static diffusion cloud chamber were 0.89 and 0.105 L-1,respectively.A comparison of the concentrations of IN at three different altitudes showed that the concentration of IN at the foot of the mountains was higher than at the peak.A further calculation of the correlation between IN and the concentrations of aerosol particles of different size ranges showed that the IN concentration was well correlated with the concentration of aerosol particles in the size range of 1.2-20 μtm.It was also found that the IN concentration varied with meteorological conditions,such as wind speed,with higher IN concentrations often observed on days with strong wind.An analysis of the backward trajectories of air masses showed that low IN concentrations were often related to air masses travelling along southwest pathways,while higher IN concentrations were usually related to those transported along northeast pathways.     

东亚季风区近地面大气气溶胶中OCPs和PCBs纬度分布：以7Be为参照系

连续一年在北京、青岛、广州以每周3d的时间尺度同步采集近地面大气中气溶胶中7Be的测定数据以及在春、秋季节变换时期我国5个不同纬度城市大气气溶胶中7Be和典型持久性有机污染物（有机氯农药和多氯联苯1的同步观测数据,并对文献上发表的我国其他城市近地面大气中气溶胶中’Be年平均值数据进行了分析。通过对以上数据资料的总结和分析,观察到在东亚季风区近地表大气气溶胶中7Be浓度的年平均值呈现正态分布模式,并且在中纬度北纬40°N附近达到极大值。大气气溶胶中7Be在春、秋季节变换时期我国不同纬度城市的瞬时纬度分布仍呈现正态分布模式,但以30°N为最大值。在秋季大气颗粒相中HCHs和PCBs浓度最大值出现在30°N。气相中PCB-28所占百分比随纬度增高而增大,而颗粒相中PCB-28的纬度变化不大。蒸汽压较低的PCB-180在气相中的浓度基本上不随纬度变化,而颗粒相中PCB-180则基本上集中在纬度36。N左右,表明在东亚季风区大气中挥发性较低的POPs化合物具有某种纬度聚焦作用。以宇宙射线成因核素7Be作为大气环流的参照系,可以得出东亚季风区大气环流可影响持久性有机污染物纬度分布的结论。     

乌鲁木齐冬季黑碳气溶胶污染特征初步研究

利用2010年2月乌鲁木齐大气成分观测站黒碳仪观测数据,结合散射系数及常规观测资料,对乌鲁木齐冬季黑碳气溶胶浓度变化特征进行了分析,并通过气流后向轨迹进行了来源分析。结果表明：(1)观测期间BC质量浓度日平均值为12707±4673 ng.m-3,浓度变化范围为4916~22997 ng.m-3,散射系数日均值为1086±561Mm-1,变化范围为350~2232 Mm-1。BC质量浓度和散射系数日均值变化趋势基本一致;(2)BC质量浓度日变化具有明显的峰值和谷值,峰值分别出现在9~11时和20~22时,谷值分别出现在4~6时和16~18时,散射系数与BC质量浓度日变化趋势基本一致,相对其有一定的滞后。春节期间燃放烟花爆竹对空气污染物浓度上升有明显作用,显著影响BC质量浓度日变化规律;(3)乌鲁木齐冬季大气层结稳定,污染物不易扩散,风速和降水对黑碳气溶胶浓度具有明显的稀释作用。在乌鲁木齐特殊的地形和气象条件下,本地源排放与来自周边城市群污染物输送的叠加使得污染更加严重。     

The Seasonal Variabilities in the Concentration of Atmospheric Aerosols over Qingdao, China

Mass concentrations of Total Suspended Particles （TSP） and size-segregated particles were obtained from July 2001 to June 2002 in Qingdao to characterize the seasonal variations of atmospheric aerosols and to show the impact of dust events on the air quality in Qingdao. Data on size-segregated aerosols show that 73.74% of the TSP mass concentration is contributed by particles with diameters less than 11 μm. Particles with diameters less than 1.1μm have a higher concentration during the winter. In spring, larger particles tend to have higher mass concentrations. Bimodal particle size distributions have been observed, with maxima around 4.7-7 μand 0.43-0.65 μm in the winter season, and 7-11 μm and 0.65-1.1 μm in the autumn season. Measurements made during the dust events in March 2002 show high concentrations of particles in the size range 2.1-7μm.     

北京地区Landsat 8 OLI高空间分辨率气溶胶光学厚度反演

卫星气溶胶光学厚度(AOD)反演中,传统暗目标方法在反射率较低的水体、浓密植被覆盖区域取得了较好效果,在反射率较高且结构复杂的高反射地表上空目前多采用深蓝算法,但存在空间分辨率较低,对细节分布描述性较差等问题。为解决这一问题,本文首先以5年(2008年—2012年)长时间序列MODIS地表反射率产品为基础,采用最小值合成法建立500 m分辨率逐月地表反射率产品数据集,然后利用地物波谱库中典型地物波谱数据,分析建立MODIS与Landsat 8 OLI传感器蓝光波段反射率转换模型,最后北京地区AERONET地基观测数据确定了气溶胶光学物理参数,并反演获取了北京地区上空500 m分辨率的AOD分布。为验证反演算法的精度,分别将反演结果同AERONET及MODIS/Terra气溶胶产品(MOD04)进行交叉对比,同时利用相关系数R,均方根误差RMSE,平均绝对误差MAE以及MODIS AOD产品预期误差EE共4个指标进行衡量。结果表明:算法反演获取的AOD与AERONET观测值具有较高的一致性,各指标分别为R=0.963,RMSE=0.156,MAE=0.097,EE=85.3%,稍优于MOD04产品(R=0.962,RMSE=0.158,MAE=0.101,EE=75.8%),并且有效的对比点数也高于MOD04。通过与地基观测相比,卫星遥感获取的高分辨率城市地区AOD精度可作为定量评估城市空气质量的有效依据。     

淄博洪山—寨里煤矿地下水串层污染治理区水化学和硫同位素特征

在明确淄博洪山—寨里煤矿地下水串层污染治理区内水文地质状况、地下水流场特征等基础上,通过对矿井水、采空区水.、矿排水、奥灰水、雨水、地表水的取样分析,掌握治理区的地下水水化学、硫同位素特征。选择接受大气降雨补给的区域.、煤矿水聚集区、奥灰水聚集区以及奥灰水与煤矿水交叉混合区,分区对地下水水质现状及煤矿水和奥灰水之间水力联系情况进行分析判断。通过对比分析治理前后研究区水质情况,发现治理后奥灰水仍呈现高SO₄^2-浓度、高硬度、高TDS特征,且硫酸盐主要来源于煤矿水,治理后洪山、寨里煤矿地下水串层通道依然存在,串层污染情况持续进行,且污染较治理前有加重趋势。则今后治理工作应进一步查清、控制导水通道,控制矿坑水水位,避免其污染奥灰水。