有机物和海洋碳循环

有机物和海洋碳循环ＮｏｂｕｈｉｋｏＨａｎｄａ大洋是控制大气二氧化碳的决定因素，所以海洋系统中的碳循环以及空气—海洋相互作用引起的二氧化碳转换均集中在体现其化学和生物过程。该过程主要包含由浮游植物光合作用、有机物从表层至深部水的垂直搬运以及其降解作用又...     

网箱养鱼诱发有机物污染的生物监测

介绍三种通过底栖动物群落结构的变化对有机物污染监测和评价的方法,并分别对澳大利亚塔斯马尼亚州Nubeena鳟鱼养殖场内由高密度网箱养鱼诱发的有机物污染进行了检测。结果表明:距网箱垂线0m处为严重污染区域,10m处为中度污染区域,30m为过渡类型,其有机物对该处底栖生物仍具有害影响,60m处为轻度有机物富集区,但该处有机物对底栖生物的总效应是有益的,60m以外为正常区域。本文还对三种方法的适用性进行了讨论。     

厦门湾有色溶解有机物的光吸收特性研究

研究了厦门湾九龙江河口区、西海域、同安湾及东侧水道海水中有色溶解有机物(CDOM)的光吸收特性,分析了CDOM的河口行为,并讨论了CDOM光吸收特性与其荧光性质之间的关系。结果表明,厦门湾表层海水CDOM光吸收系数a(355)的水平分布表现为河口区最高、东侧水道最低、西海域和同安湾介于两者之间,底层水a(355)的分布与表层基本相似,表明陆源河流输入是厦门湾CDOM的主要来源;a(355)的垂直分布为表层高于底层,主要受水文和生物因素控制。厦门湾表层水CDOM光谱斜率S的平均值介于0.014—0.018nm-1,但河口低盐度区S值较小,反映陆源腐殖质的影响。a(355)在河口混合中呈保守行为,表明CDOM具有良好的保守性质。CDOM的吸收系数a(355)与其荧光强度之间表现为较好的相关关系,指示可以用灵敏度更高的荧光方法来研究CDOM的分布和行为。     

Occurrence of Organic Matter in Calcimicrobialites across Permian-Triassic Boundary in Huayingshan Region, Sichuan, South China

Calcimicrobialites across the Permian-Triassic boundary in Huayingshan (华蓥山) region were investigated using the fluorescence microscopic measurements to understand the occurrence of organic matter. The microbialites are composed of micrite matrix and coarse spar cement. Abundant rhombic or magnetic needle-like carbonate minerals were observed adrift within the cement. The fluorescence microscopic measurement indicates the micrite matrix in microbialites shows the most abundant organic matter, with the rhombic or magnetic needle-like carbonate minerals and coarse spar cement coming to the 2nd and the 3rd, respectively. Organic matter is mainly preserved in the space between the grains of the micrite minerals but almost evenly distributed in the rhombic or magnetic needle-like carbonate minerals. As one of the common diagenesis types, dolomitization is observed to occur in the microbialites in Huayingshan. However, the carbonate cement in microbialites still has high content of element Sr as shown by the microprobe analysis, reflecting that the dolomitization might have happened in a restricted environment. Observation under the fluorescence microscope shows that dolomitization just led to the redistribution of organic matter in the grain space of dolomite minerals, inferring that the diagenesis has a slight effect on the preservation, and thus on the content of organic matter in the microbialites.     

Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.     

石家庄市水环境中微量有机物的污染规律研究

利用色谱-质谱联机分析技术，结合现场调查，研究了石家庄市地表水环境中微量有机物的污染分布规律，可为城市水源保护提供科学依据。     

The Role of Organic Matter During Metal Enrichment in Permian Kupferschiefer of the Rudna Mine,Southwest Poland

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.     

SMBR中污染物处理效率随污泥浓度变化的数学模型

以一体式膜生物反应器(SMBR)对生活污水进行处理,研究不同水力停留时间(HRT)条件下污泥浓度对有机物去除率的影响,并对所得试验数据进行曲线拟合,建立有机物去除率与污泥浓度的数学模型。试验结果表明:在溶解氧(DO)浓度为2.0～3.0mg/L的条件下,HRT为3h、2h和1h时,有机物去除率(η)随着污泥浓度的增大而增大,但当污泥浓度增大到6000mg/L时,η增大趋势逐渐减小,并趋于稳定。有机物去除率与污泥浓度的数学模型表明:有机物去除率(η)与水力停留时间(τ)、进水COD浓度(S_o)和污泥负荷率(N_s)等主要运行参数有关,并可以通过调节运行参数τ、S_o和N_s来达到所需要的COD去除率。     

Biomarkers in the Molar Tooth （MT）-Bearing Limestones in the Jilin-Liaoning Area of China

The origin of Molar Tooth (MT) carbonates has been argued for more than 100 years, which are a kind of Proterozoic carbonates especially composed of microsparite with ptygmatically folded and sheet-like structures. Biomarkers detected in the microcalcsparite from the Wanlong and Xingmincun formations in the Jilin-Liaoning area showed there are abundant normal alkanes, isoprenoids, hopanes, steranes, alkylmethylcyclohexanes, and alkyleyclohexanes, indicating a diversity of biological source: long-chain isoprenoids, the major components of chlorophyll, such as C19, C20, a kind of major biomarkers synthesized early by isoprenoid monomers; hopanes a type of characteristic biomarkers from prokaryote, such as archaebacteria and cyanobacteria; sterane a biomarker for eukaryote; and two kinds of alkanes with C17, C18 as the main peaks representing aquatic bacteria and with C23, C24 as the main peaks representing fungi, respectively. Biomarker analysis showed that MT is the result of bacterial and algal activities, which is a kind of organisms between aerobic and anaerobic bacteria, reproducing well in normal or slightly saline sea water under weak oxidation-reduction conditions, resulting in rapid deposition of calcite as microsparite clue to some mechanisms.     

GC-MS法测定地下水中28种半挥发性有机物

本文针对地下水监测网运行维护规范(DZ/T 0307-2017)中的半挥发性有机物,建立了一种液/液萃取-气相色谱质谱联用法,可同时测定28种半挥发性有机物(SVOCs),涵盖规范中除多氯联苯外全部的27个SVOCs.方法 采用二氯甲烷萃取,SIM模式经气相色谱质谱联用仪(GC-MS)对样品进行测定,内标法定量,可实现...