Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

The influence of aerosol particle composition on cloud droplet formation

A difference in partitioning between cloud droplets and interstitial air for two chemical species (elemental carbon and sulphur) with different expected behaviour in nucleation scavenging was observed in clouds at Mt. Kleiner Feldberg (825 m asl), near Frankfurt, Germany. The fraction of sulphur incorporated in cloud droplets was always higher than the fraction of elemental carbon. This difference in partitioning has also been observed in fog but under different pollution conditions in the Po Valley, Italy. Both these studies were based on bulk samples. In the present study at Kleiner Feldberg, impactor samples of the particles in the interstitial air and the cloud droplet residuals were taken and a single particle analysis was done on the samples. It was found that, for a given particle size, the majority of particles forming cloud droplets were soluble and that insoluble particles preferentially remained in the interstitial air.     

Gradient theory of nucleation in polar fluids

Gradient theory (GT), a form of density functional theory (DFT), was applied to water, methanol, and ethanol using the cubic perturbed hard body (CPHB) equation of state (EOS). Compared to the standard form of classical nucleation theory (CNT), the GT results for water showed an improved temperature dependence, but the supersaturation dependence was slightly poorer. GT and several forms of CNT were also found to be in good agreement with a single high T molecular dynamics rate for TIP4P water. The rates predicted by GT for methanol and ethanol were improved by several orders of magnitude compared to CNT, but no improvement in the predicted temperature dependence of the rates was found.     

气球携带碘化银焰弹技术研究

主要介绍在北京地区开展气球携带碘化银焰弹雨雪作业的作业技术，经济效益等问题。通过各种增雨雪技术比较，认敢球携带碘化银焰弹增雨雪作业在北方干旱地区的抗旱工作中或作为收音机增雨雪作业的补充手段具有应用价值     

机载碘化银发生器燃烧室残留物成分分析

通过对碘化银发生器残留物样本化学分析,残留物附着规律及其成因研究,最后提出了减少残留物的对策。     

河北大茂山碘化银地面发生器增雪作业影响分析

利用常规气象资料、MICAPS资料和NECP/NCAR再分析资料,结合高斯模拟,分析了2012年11月10日唐县大茂山地基碘化银发生器增雪作业的作业条件。结果发现,此次天气背景为自西南向东北移动的冷涡云系,根据帕斯奎尔(Pasquill)稳定度分类法得出作业时间段大气处于中性层结状态;高斯模式模拟得出,有效的AgI浓度向上扩散范围高达3.0 km;作业点作业时段上空至3.2 km均处于上升气流区,计算出作业点发生器出口温度1.0℃。因冬季人工观测云底高度多为2.5~3.0 km,综合分析认为,该作业点的选址是合适的,此次作业条件较好,可以将催化剂输送到云中,起到催化作用。     

The Characteristics of Atmospheric Ice Nuclei Measured at Different Altitudes in the Huangshan Mountains in Southeast China简

The concentration of ice nuclei （IN） and the relationship with aerosol particles were measured and analyzed using three 5-L mixing cloud chambers and a static diffusion cloud chamber at three altitudes in the Huangshan Mountains in Southeast China from May to September 2011.The results showed that the mean total number concentration of IN on the highest peak of the Huangshan Mountains at an activation temperature （Ta） of-20℃C was 16.6 L-1.When the supersaturation with respect to water （Sw） and with respect to ice （Si） were set to 5％,the average number concentrations of IN measured at an activation temperature of-20℃C by the static diffusion cloud chamber were 0.89 and 0.105 L-1,respectively.A comparison of the concentrations of IN at three different altitudes showed that the concentration of IN at the foot of the mountains was higher than at the peak.A further calculation of the correlation between IN and the concentrations of aerosol particles of different size ranges showed that the IN concentration was well correlated with the concentration of aerosol particles in the size range of 1.2-20 μtm.It was also found that the IN concentration varied with meteorological conditions,such as wind speed,with higher IN concentrations often observed on days with strong wind.An analysis of the backward trajectories of air masses showed that low IN concentrations were often related to air masses travelling along southwest pathways,while higher IN concentrations were usually related to those transported along northeast pathways.     

Nucleation of earthquakes and its implication to precursors

IntroductionIn the middle of 1990s, the argument about nucleation phase occurred. Ellsworth and Beroza(1 995) studied the wave records of 30 earthquake events, which initiated slowly. Ellsworth, et al calledthem as nucleation phase. They discussed the relationship between their moment, duration time andthe relationship with the main shock behind. Scherbaum (1997a, b) proposed his different view andsuggested that some of the recording of the long period initial of seismic wave was misinterpret…     

The initial subevent of the 1994 Northridge, California, earthquake: Is earthquake size predictable?

We examine the initial subevent (ISE) of the M 6.7, 1994 Northridge, California, earthquake in order to discriminate between two end-member rupture initiation models: the preslip and cascade models. Final earthquake size may be predictable from an ISE's seismic signature in the preslip model but not in the cascade model. In the cascade model ISEs are simply small earthquakes that can be described as purely dynamic ruptures. In this model a large earthquake is triggered by smaller earthquakes; there is no size scaling between triggering and triggered events and a variety of stress transfer mechanisms are possible. Alternatively, in the preslip model, a large earthquake nucleates as an aseismically slipping patch in which the patch dimension grows and scales with the earthquake's ultimate size; the byproduct of this loading process is the ISE. In this model, the duration of the ISE signal scales with the ultimate size of the earthquake, suggesting that nucleation and earthquake size are determined by a more predictable, measurable, and organized process. To distinguish between these two end-member models we use short period seismograms recorded by the Southern California Seismic Network. We address questions regarding the similarity in hypocenter locations and focal mechanisms of the ISE and the mainshock. We also compare the ISE's waveform characteristics to those of small earthquakes and to the beginnings of earthquakes with a range of magnitudes. We find that the focal mechanisms of the ISE and mainshock are indistinguishable, and both events may have nucleated on and ruptured the same fault plane. These results satisfy the requirements for both models and thus do not discriminate between them. However, further tests show the ISE's waveform characteristics are similar to those of typical small earthquakes in the vicinity and more importantly, do not scale with the mainshock magnitude. These results are more consistent with the cascade model.     

Experimental solidification of anhydrous latitic and trachytic melts at different cooling rates: The role of nucleation kinetics

Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of  90 vol.%. The phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable quench temperatures, investigated by coupling experiments with Pt wire and Pt capsule sample containers in set 2, again did not produce crystallization of trachyte, whereas latitic samples are characterized by  10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature < 1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass-forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (< 0.125 °C/min), in comparison to latitic melts (Rc > 0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts.