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701.
Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy 下载免费PDF全文
Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample). 相似文献
702.
An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry 下载免费PDF全文
Bouchaïb Tibari Arnaud Vacherat Martin Stab Raphaël Pik Delphine Yeghicheyan Pascal Hild 《Geostandards and Geoanalytical Research》2016,40(3):365-375
Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure. 相似文献
703.
Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting 下载免费PDF全文
Matthew S. A. Horstwood George Gehrels Simon E. Jackson Noah M. McLean Chad Paton Norman J. Pearson Keith Sircombe Paul Sylvester Pieter Vermeesch James F. Bowring Daniel J. Condon Blair Schoene 《Geostandards and Geoanalytical Research》2016,40(3):311-332
The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess 230Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation. 相似文献
704.
Zhe Zeng Tong Zhang Qingquan Li Zhongheng Wu Haixiang Zou Chunxian Gao 《International journal of geographical information science》2016,30(4):660-690
Map matching method is a fundamental preprocessing technique for massive probe vehicle data. Various transportation applications need map matching methods to provide highly accurate and stable results. However, most current map matching approaches employ elementary geometric or topological measures, which may not be sufficient to encode the characteristic of realistic driving paths, leading to inefficiency and inaccuracy, especially in complex road networks. To address these issues, this article presents a novel map matching method, based on the measure of curvedness of Global Positioning System (GPS) trajectories. The curvature integral, which measures the curvedness feature of GPS trajectories, is considered to be one of the major matching characteristics that constrain pairwise matching between the two adjacent GPS track points. In this article, we propose the definition of the curvature integral in the context of map matching, and develop a novel accurate map matching algorithm based on the curvedness feature. Using real-world probe vehicles data, we show that the curvedness feature (CURF) constrained map matching method outperforms two classical methods for accuracy and stability under complicated road environments. 相似文献
705.
Xiaoyi Ma Ci Song Chenghu Zhou 《International journal of geographical information science》2016,30(12):2401-2420
In the high-speed urbanization process of China, the urban population has been increasing significantly, leading to a high-density aggregation of population. However, the sharp increase in population density has not produced commensurate improvements in the road networks. On the contrary, the population increase induced a serious evacuation vulnerability, which cities experience during various hazards and catastrophic events. Therefore, research on evacuation vulnerability is important to urban planning. To assess the evacuation vulnerability, the optimal and worst scenarios should be considered because all possible evacuation plans occur between these extremes. However, most previous evacuation vulnerability studies are based on the worst-case scenario, only providing an upper bound of a potential evacuation assessment. To provide a more comprehensive theoretical basis for decision-makers to understand the consequences caused by all possible evacuations, this paper proposes an optimal evacuation vulnerability assessment model that provides the lower bound on potential evacuation difficulties. The model is solved by a stepwise spreading algorithm based on Graph Theory. Subsequently, to evaluate the effectiveness of the model, the study adopts the model to assess the evacuation capability of different road network topologies. A comparison with previous research was performed. The model was demonstrated in an application to the South Luogu Alley of Beijing, China. The significance of this paper is that the combination of our model with previous research may provide a more complete theoretical basis for an evacuation vulnerability assessment. 相似文献
706.
Weijian Xue 《International journal of geographical information science》2016,30(3):554-572
ABSTRACTTo collect and dispose growing amounts of municipal solid waste (MSW) changed to be a hot topic along with the rapid urbanization in past decades. Cities are more and more dependent on the incineration instead of landfilling due to the cost-efficiency and environmental concerns. Considering the limited number of incineration plants and complicated situation of transportation in both spatial and temporal dimensions in different cities, the optimal routing for waste collection turns to be meaningful research topic. In this research, the ant colony optimization (ACO)-based multi-objective routing model coupled with min-max model and Dijkstra’s algorithm is proposed to address the question of which route to take from these waste-generating points to the target incineration plant(s) considering travel time, accident probability (black spots), and population exposure, so as to support the routing decision-making. The model is successfully implemented in Singapore and the effectiveness of the model has also been justified. Besides, few limitations of this research have also been discussed, some of which would also be the future directions of our research, especially the design and integration of a web-based routing decision-making support system. 相似文献
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710.
《世界地质(英文版)》2016,(4):261-276
The beginning of the XXI century was marked a new rising of the international tectonic cartography as a result of analysis and synthesis of a huge volume of geological information obtained for the territory of Asia especially during the last 30 years. The previous tectonic maps for Asia were created in the 1960 s--1970 s of the last century. Since that time,the national geological surveys have compiled tectonic maps exclusively in the limits of their own state boundaries. The international cooperation of five countries since 2002( Russia,China,Mongolia,Kazakhstan and Republic of Korea) gave a unique possibility to join the data into a united cartographic form as Atlas of Geological Maps( since 2002-Atlas of Geological Maps of Central Asia and since 2007-Atlas of Geological Maps of Northern-Central-Eastern Asia). Both atlases include four maps: geological,tectonic,metallogenic,and energy resources. Tectonic Map of Northern-Central-Eastern Asia and Adjacent Areas at scale 1 ∶ 2 500 000 was the key map for further compilation of the metallogenic and energy resources( coal,oil and gas) maps. By this reason,special attention was given to showing the structure and composition of the Mesozoic sedimentary basins in Northern-Central- Eastern Asia as the most perspective structures for oil-and-gas and coal prospect. 相似文献