云南兰坪-思茅盆地生物地球化学找钾技术方法研究初探

在生物地球化学和“深穿透”理论的指导下,在兰坪-思茅盆地勐野井钾盐矿区及周边开展了生物地球化学找钾技术方法的探索性研究。沿江城县勐野井钾盐矿区及周边一线,对乔木类植物叶子进行了取样,分析,数据处理,特征指标筛选,获得了研究区植物样品主量和微量组分含量背景值,初步圈定了异常区,与以往圈定的找钾远景区较吻合。该区生物地球化学找钾技术取得较好的效果,今后还需扩大采样区域,获得更多样本数据,将找钾特征指标及其异常值的阈值进一步补充完善。     

南极长城站地区现代环境地球化学特征

本文通过环境背景值、风化壳地球化学、对流层(大气气溶胶)地球化学和人为地球化学异常,初步探讨了南极长城站地区的现代环境地球化学特征。分析表明:环境要素固有的地球化学性质、区域环境条件和自然环境演变之间具有深刻的内在联系。     

使用价值分析优化方法在功能—技术矩阵求解中的应用

功能—技术矩阵,经众多工作者的努力研究,已渐趋成熟与实用。但如何利用功能—技术矩阵构造在广义现代设计领域中适用的科学模式,解决多学科设计方案的组成与评价问题,还存在薄弱环节。本文利用“使用价值分析优化”的概念,从设计方案技术先进性和经济合理性的协调统一的角度出发,较好地实现了功能—技术矩阵可行优化组合链的组成与评价,弥补了以往的缺陷。     

Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

A novel strategy using biodegradable EDDS for the chemically enhanced phytoextraction of soils contaminated with heavy metals

For the sake of cost and potential environmental risk, it is necessary to minimize the amount of chelates used in chemically-enhanced phytoextraction. In the present study, a biodegradable chelating agent, EDDS was added in a hot solution at 90℃ to the soil in which garland chrysanthemum （Chrysanthemum coronarium L.） and beans （Phaseolus vulgaris L., white bean） were growing. The application of hot chelate solutions was much more efficient than the application of normal chelate solutions （25℃） in improving the uptake of heavy metals by plants. When 1 mmol kg1 of EDDS as a hot solution was applied to soil, the concentrations ofCu, Zn and Cd and the total phytoextraction by the shoots of the two plant species exceeded or approximated those in the shoots of plants treated with 5 mmol kg^-1 of normal EDTA solution. The concentrations of metals in the shoots of beans were significantly correlated with the relative electrolyte leakage rate of root cells, indicating that the root damage resulting from the hot solution might play an important role in the process of chelate-enhanced metal uptake. The soil leaching study demonstrated that decreasing the dosage of chelate resulted in decreased concentrations of soluble metals in soils. On the 28th day following the application of chelate, the concentrations of soluble metals in the EDDS treated soil were not significantly different from the concentrations in the control soil to which chelates had not been applied.     

Estimating the minimum in-stream flow requirements via wetted perimeter method based on curvature and slope techniques

Under the assumptions of triangular cross section channel and uniform stable flow, an analytical solution of the minimum ecological in-stream flow requirement (MEIFR) is deduced. Based on the analytical solution, the uncertainty of the wetted perimeter method is analyzed by comparing the two techniques for the determination of the critical point on the relationship curve between wetted perimeter, P and discharge, Q. It is clearly shown that the results of MEIFR based on curvature technique (corresponding to the maximum curvature) and slope technique (slope being 1) are significantly different. On the P-Q curve, the slope of the critical point with the maximum curvature is 0.39 and the MEIFR varied prominently with the change of the slope threshold. This indicates that if a certain value of the slope threshold is not available for slope technique, curvature technique may be a better choice. By applying the analytical solution of MEIFR in the losing rivers of the Western Route South-to-North Water Transfer Project in China, the MEIFR value via curvature technique is 2.5%-23.7% of the multi-year average annual discharge, while that for slope technique is 11%-105.7%. General conclusions would rely on the more detailed research for all kinds of cross-sections.     

基于Intergraph GIS的基础空间数据库一体化建设研究

阐述了基于Intergraph GIS的城市基础空间数据的结构和建库的内容,提出了一体化的建库、质量控制、空间数据动态更新以及基于版本信息的历史数据存储与恢复的方法,介绍了一体化建库实例。     

黑龙江省中部森林沼泽区 超低密度深穿透地球化学调查采样介质的确定

通过对王水溶矿法与四酸溶矿法的对比,元素在泛滥平原A层、B层沉积物及水系沉积物中的分配,以及这3种介质圈定的异常对比等综合因素的研究,确定了泛滥平原A层沉积物是黑龙江省中部森林沼泽区开展超低密度深穿透地球化学调查的有效采样介质。     

青藏高原中部的东西向扩张构造运动

系统分析了1933~2003年间青藏高原及其周缘发生的745个中、强地震的震源机制解,研究了高原地壳构造运动及其动力学特征。结果表明,大量正断层型地震集中发生在青藏高原中部海拔4000m以上的地区,其中许多地震是纯正断层型地震。震源机制结果显示,该区正断层型地震的断层走向多为南北方向,断层位错矢量的水平分量均位于近东西方向,这表明青藏高原高海拔地区存在着近东西方向的扩张构造运动。地震震源应力场的研究结果表明,在高原中部高海拔地区,E-W向或WNW-ESE向的水平扩张作用控制着该区的地壳应力场。青藏高原高海拔地区近东西方向的扩张构造运动是该区引张应力场的作用结果,其动力学原因可能与持续隆升的高原自重增大引起的重力崩塌及其周边区域构造应力状况有关。而青藏高原周缘地区,除了东部边缘外,南部的喜马拉雅山前沿以及青藏高原的北部、西部边缘所发生的绝大部分地震都是逆断层型或走滑逆断层型地震。在青藏高原周缘地区,北东或者北北东方向水平挤压的构造应力场为优势应力场。在中国西部的大范围内,主压应力P轴水平分量位于NE-SW方向,形成了一个广域的NE-SW方向的挤压应力场。青藏高原及其周缘应力场特征表明,印度板块的北上运动以及它与欧亚板块之间的碰撞所形成的挤压应力场是高原强烈隆起的直接原因。在青藏高原中南部形成了近东西向引张应力场为主的区域,并以东西向扩张构造运动部分释放其应力积累。研究高原高海拔地区的引张应力场和近东西向扩张构造运动的特征,对于认识青藏高原强烈隆起的地球动力学过程与机制,有着重要的理论意义。