Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Effects of crab–halophytic plant interactions on creek growth in a S.W. Atlantic salt marsh: A Cellular Automata model

The Bahía Blanca Estuary (38° 50′ S, and 62° 30′ W) presents salt marshes where interactions between the local flora (Sarcocornia perennis) and fauna (Chasmagnathus granulatus) generate some kind of salt pans that alter the normal water circulation and condition its flow and course towards tidal creeks. The crab–vegetation dynamics in the salt marsh presents variations that cannot be quantified in a reasonable period of time. The interaction between S. perennis plant and C. granulatus crab is based on simple laws, but its result is a complex biological mechanism that causes an erosive process on the salt marsh and favors the formation of tidal creeks. To study it, a Cellular Automata model is proposed, based on the laws deduced from the observation of these phenomena in the field, and then verified with measurable data within macroscale time units. Therefore, the objective of this article is to model how the interaction between C. granulatus and S. perennis modifies the landscape of the salt marsh and influences the path of tidal creeks. The model copies the basic laws that rule the problem based on purely biological factors.The Cellular Automata model proved capable of reproducing the effects of the interaction between plants and crabs in the salt marsh. A study of the water drainage of the basins showed that this interaction does indeed modify the development of tidal creeks. Model dynamics would likewise follow different laws, which would provide a different formula for the probability of patch dilation. The patch shape can be obtained changing the pattern that dilates.     

初至层析静校正在复杂山地三维地震勘探中的应用

随着地形高差增大、地貌单元多变、近地表模型复杂,目前被广泛应用的初至折射静校正的精度已无法满足精细勘探的要求。初至层析静校正技术,由给定的初始模型进行正演,用射线追踪方法得到初始模型的初至波,利用该初至波和实际拾取的初至波进行比较,计算地表模型的修正量,反复迭代求得准确的地表模型。山西省国阳新能股份有限公司二矿390水平九采扩区地表标高940～1100m,地貌单元复杂,在对该区资料处理时,利用初至层析折射静校正,经9次迭代计算后,真实地刻划出近地表模型。在二种静校正技术对比中,初至折射静校正不但近地表模型精度低于层析折射静校正,而且其叠加剖面精细程度也远低于层析静校正,如在初至折射静校正叠加剖面同相轴上呈现的凹凸形态,在层析静校正叠加剖面并无显示,且后者剖面的信噪比也比前者明显提高。     

A pronounced dry event recorded around 4.2 ka in brine sediments from the northern Red Sea

Partly laminated sediments were sampled from the brine-filled, anoxic Shaban Deep basin in the northern Red Sea. At about 4200 cal yr BP more than two millennia of anoxic sedimentation is replaced by a sub-oxic facies strongly suggesting the episodic absence of the brine. At the same time stable oxygen isotopes from surface dwelling foraminifera show a sharp increase (within less than 100 yr) pointing to a strong positive salinity anomaly at the sea surface. This major evaporation event significantly enhanced the renewal of deep water and the subsequent ventilation of the small Shaban Deep basin. The timing and strength of the reconstructed environmental changes around 4200 cal yr BP suggest that this event is the regional expression of a major drought event, which is widely observed in the neighboring regions, and which strongly affected Middle East agricultural civilizations.     

A way to synchronize models with seismic faults for earthquake forecasting: Insights from a simple stochastic model

Numerical models are starting to be used for determining the future behaviour of seismic faults and fault networks. Their final goal would be to forecast future large earthquakes. In order to use them for this task, it is necessary to synchronize each model with the current status of the actual fault or fault network it simulates (just as, for example, meteorologists synchronize their models with the atmosphere by incorporating current atmospheric data in them). However, lithospheric dynamics is largely unobservable: important parameters cannot (or can rarely) be measured in Nature. Earthquakes, though, provide indirect but measurable clues of the stress and strain status in the lithosphere, which should be helpful for the synchronization of the models.The rupture area is one of the measurable parameters of earthquakes. Here we explore how it can be used to at least synchronize fault models between themselves and forecast synthetic earthquakes. Our purpose here is to forecast synthetic earthquakes in a simple but stochastic (random) fault model. By imposing the rupture area of the synthetic earthquakes of this model on other models, the latter become partially synchronized with the first one. We use these partially synchronized models to successfully forecast most of the largest earthquakes generated by the first model. This forecasting strategy outperforms others that only take into account the earthquake series. Our results suggest that probably a good way to synchronize more detailed models with real faults is to force them to reproduce the sequence of previous earthquake ruptures on the faults. This hypothesis could be tested in the future with more detailed models and actual seismic data.     

用逐步回归预测棉铃虫发生期和发生量

收集了1973年至2000年的气象，农作物、棉铃虫虫害等196年因子，以运城、汾阳和临汾为山西省代表站，利用最优二分割法把发生量分为10级，5级和不分级3种情况；使用逐步回归计算了219个模型，从中选出27个棉铃虫二、三代发生期，发生量最优模型，在农气服务中应用，预报准确率为95％，效果良好。     

舞阳、襄城盐湖盆地未熟-低熟油成藏模式

舞阳、襄城凹陷下第三生活费为膏、盐岩相盐湖沉积。半咸水-咸水湖相、盐湖相是形成未熟-低熟油的良好环境，沉积旋回中期断坳式沉积形成了主要油源层系，其高丰度未熟烃类推岩体是形成未熟-低熟油藏的物质基础，中-高孔、中-高渗碎屑岩层构成了未熟-低熟油藏的重要储集层，并发育了较好的生储盖组合，这些有利条件为舞阳、襄城凹陷形成未熟-低熟油藏提供了重要保证。指出凹陷陡坡带为背斜、断鼻型油藏分布区，还可能有混合型油藏；中部洼陷带为岩性油藏、裂隙型油藏发育区；斜坡带主要发育断鼻型油藏。     

A non-linear stress-stiffness model for geomaterials at small to intermediate strains

A double exponential fitting model (DEFM) capable of expressing the non-linear stress-stiffness relationship of geomaterials has been proposed by Shibuya et al. (1997). The model comprises two material constants; the elastic stiffness at very small strains and the strength, together with other free parameters to determine the complete stress-stiffness relationship. In this paper, the capability of the original function used for DEFM in simulating the tangent stiffness-stress relationship of geomaterials is first discussed. Second, the methods for determining the free model parameters, as well as its conversion to obtain a stress-strain relationship are proposed. The applicability of DEFM to predicting non-linear stress-stiffness relationship is examined in detail in a total of forty-nine fitting cases of compression test data on sedimentary rock, artificial soft rock and soft clay. It is found that the DEFM is effective in expressing the non-linear stress-stiffness relationship of various kinds of geomaterials at small to intermediate strains, say less than 0.5%. The superiority of this model compared to other fitting models currently in use is also demonstrated in some of the fitting cases.