A Three-year Study of Nonmethane Hydrocarbons in Surface Air over Saxony (Germany)

Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source.     

һ�ֻ���Ƶ�׷�����AR�����Ķ������ӳ�Ԥ��ģ��

?????????????????????ZTD????????????????????￡???????????????????????????????????????????????ZTD???????????????????????????ZTD???н?????????????????????????????????????????ZTD?????????????б????????????????????????в???AR?????и???????????????????????????????AR??????ZTD??????????????????????????μ??????????cm????     

Inference of surface concentrations of nitrogen dioxide (NO2) in Colombia from tropospheric columns of the ozone measurement instrument (OMI)

For the first time, maps of surface concentration of nitrogen dioxide (NO₂) are presented for the Colombian territory. NO₂ surface concentrations for the year 2007 are inferred based on two sources of tropospheric NO₂ column data: (1) a simulation using a three-dimensional global model (GEOS-Chem) and (2) measurements made by the ozone monitoring instrument (OMI) onboard the NASA Aura satellite. Results show monthly averages between 0.1 and 6 ppbv. We compare these inferred values to corrected ground measurements of NO₂. We find correlation coefficients of up to 0.91 between the inferred data and the corrected observational data. A significant source of NO₂ is biomass burning, which can be diagnosed by data of fire radiative power (FRP) from the Monitoring of Atmospheric Composition and Climate (MACC) reanalysis. We find a close relationship between high values of inferred NO₂ surface concentrations and biomass burning for a large area which encompasses the departments of Caquetá, Meta, Guaviare, Vichada, and Putumayo.     

对流层大气温度"蝴蝶形"震前异常

利用美国国家和海洋大气管理局(NOAA)的大气温度数据, 分析陆地地震和海洋地震震前震中上空的大气温度变化, 研究其作为地震短临前兆的可能性.地震样本包括2014年2月12日于田M_s7.3地震、2008年5月12日汶川M_s8.0地震、2011年3月11日日本M_s9.0地震、2014年4月1日智利M_s8.1海洋地震、2013年3月27日台湾南投县M_s6.1地震和2014年5月30日云南盈江M_s6.1地震.结果表明: (1)震前, 震中位置300~1 000 hPa大气温度有较为一致的变化趋势; (2)200 hPa与400 hPa处(根据不同地点可选择其他, 诸如350 hPa、300 hPa等高度数据)温度折线图在震前趋近或者相交, 出现类似蝴蝶翅膀的"蝴蝶形"特殊曲线形状; (3)200 hPa与400 hPa温度差等值线图在(震前数月、数周或数天不等)震中附近区域的数值减小, 温度差等值线图的塌陷最低点对应震中位置.以上规律有望应用于地震短临预测的时间与震中的确定.      

亚洲地区EGNOS天顶对流层延迟模型单站修正与精度分析

以亚洲地区46个IGS站2008-2011年实测的高精度天顶对流层延迟（ZTD）数据为参考值,通过对2008-2010年EGNOS模型计算ZTD的日均偏差进行频谱分析,建立了亚洲地区EGNOS模型的单站修正模型（SSIEGNOS）,对EGNOS和SSIEGNOS模型在亚洲地区的精度和适用情况进行了评估,结果表明：（1）EGNOS模型偏差和RMS在时间分布上呈现明显的季节变化规律,而SSIEGNOS模型偏差和RMS变化较小且平稳;（2）在空间分布上,两种模型的偏差随着经纬度和高程的变化均无明显规律,但随着高程或者纬度的增加RMS总体上都有递减的趋势;（3）SSIEGNOS模型预测ZTD的精度相对于EGNOS模型有明显提高。     

COMPASS三频数据线性组合优化选取分析

以北斗卫星1支路频点为例,从消除或减弱电离层影响、对流层影响和观测噪声与多路径误差3个方面分析COMPASS三频数据线性组合的优化选取问题,并通过MATLAB模拟,给出一些典型的组合,分析它们可能的应用,为COMPASS三频数据线性组合的优化选取提供一些借鉴。     

基于再分析资料ERA5的对流层延迟估计方法及精度评估

提出基于再分析资料ERA5的天顶对流层延迟计算方法,使用中国大陆构造环境监测网络提供的26个GNSS测站2017年全年数据,评估由该方法计算的天顶对流层延迟的精度,并与前一代再分析资料ERA-Interim的计算结果进行对比分析。结果显示,ERA5计算的天顶对流层延迟均方根误差比ERA-Interim计算结果低,表明新一代产品的精度有明显提升。     

基于GPS非差技术近实时获取对流层延迟

本文提出一种近实时获取高精度对流层延迟(Zenith Tropospheric Delay,ZTD)的方法。该方法基于全球GPS参考站网络的非差观测值数据和IGU预报产品(卫星轨道和ERP),使用GPS非差技术和卡尔曼滤波近实时估计各参考站的高精度ZTD。将该方法应用于香港GPS参考站网得到的ZTD与基于事后技术计算的ZTD进行比较后发现,两者的平均偏差均优于5mm,RMS均优于6mm。     

GPS对流层延迟模型的比较分析

基于GPS对流层模型,对几种模型进行实际应用的对比,通过GAMIT软件对CORS数据进行处理,分析得出了几种模型在GPS反演大气水汽含量应用中的精度。     

Impacts of Global Emissions of CO, NOx, and CH4 on China Tropospheric Hydroxyl Free Radicals

Using the global chemistry and transport model MOZART,the simulated distributions of tropospheric hydroxyl free radicals(OH) over China and its sensitivities to global emissions of carbon monoxide(CO),nitrogen oxide(NO x),and methane(CH 4) were investigated in this study.Due to various distributions of OH sources and sinks,the concentrations of tropospheric OH in east China are much greater than in west China.The contribution of NO + perhydroxyl radical(HO 2) reaction to OH production in east China is more pronounced than that in west China,and because of the higher reaction activity of non-methane volatile organic compounds(NMVOCs),the contributions to OH loss by NMVOCs exceed those of CO and take the dominant position in summer.The results of the sensitivity runs show a significant increase of tropospheric OH in east China from 1990 to 2000,and the trend continues.The positive effect of double emissions of NO x on OH is partly offset by the contrary effect of increased CO and CH 4 emissions:the double emissions of NO x will cause an increase of OH of 18.1%-30.1%,while the increases of CO and CH 4 will cause a decrease of OH of 12.2%-20.8% and 0.3%-3.0%,respectively.In turn,the lifetimes of CH 4,CO,and NO x will increase by 0.3%-3.1% with regard to double emissions of CH 4,13.9%-26.3% to double emissions of CO and decrease by 15.3%-23.2% to double emissions of NO x.