单站GPS遥感水汽含量范围的确定及结果分析

随着GPS技术的日益成熟和研究的不断深入,GPS的定位精度得到了大幅度的提高,为其在测绘、交通、林业资源、石油勘探、精细农业等行业的应用提供了更广阔的空间。GPS气象学(GPS/Meteorology简称GPS/MET)的诞生改善了原有大气监测技术的局限性,极大的提高了气象监测的时空分辨率,但是在将这项技术由试验阶段向推广普及应用的过程中,单站地基GPS监测的有效范围以及水汽解的精度一直为广大气象学家们所忽略,本文在对以往GPS气象数据收集和整理的基础上,根据理论计算和实际验算,得出了一些有益的结论。     

Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.     

长江三角洲地区对流层臭氧的变化趋势

Analysis of tropospheric ozone residual (TOR) data from satellite measurements indicates an increasing trend of tropospheric ozone over the Yangtze Delta region of China. The increasing trend can be derived both from the annual mean TOR and from the monthly mean TOR except for January and March. The increase rate of the decadal mean TOR was 0.82 DU during 1978-2000. The impact of this long-term trend on the climate and atmospheric oxidizing capacity over the region should be further studied. Data comparison shows a significant correlation between the TOR and surface ozone data collected at Lin'an background station in the Yangtze Delta region, suggesting an internal connection between both quantities.     

Retrieval of the Change of Precipitable Water Vapor by GPS Technique

The feasibility of GPS precipitable water vapor (PWV) is discussed based on the comparison of Radiosonde and GPS PWV where the correlation coefficient is 0.94 and the RMS is 4.0 mm. PWV change in the C...     

A Three-year Study of Nonmethane Hydrocarbons in Surface Air over Saxony (Germany)

Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source.     

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Inference of surface concentrations of nitrogen dioxide (NO2) in Colombia from tropospheric columns of the ozone measurement instrument (OMI)

For the first time, maps of surface concentration of nitrogen dioxide (NO₂) are presented for the Colombian territory. NO₂ surface concentrations for the year 2007 are inferred based on two sources of tropospheric NO₂ column data: (1) a simulation using a three-dimensional global model (GEOS-Chem) and (2) measurements made by the ozone monitoring instrument (OMI) onboard the NASA Aura satellite. Results show monthly averages between 0.1 and 6 ppbv. We compare these inferred values to corrected ground measurements of NO₂. We find correlation coefficients of up to 0.91 between the inferred data and the corrected observational data. A significant source of NO₂ is biomass burning, which can be diagnosed by data of fire radiative power (FRP) from the Monitoring of Atmospheric Composition and Climate (MACC) reanalysis. We find a close relationship between high values of inferred NO₂ surface concentrations and biomass burning for a large area which encompasses the departments of Caquetá, Meta, Guaviare, Vichada, and Putumayo.     

对流层大气温度"蝴蝶形"震前异常

利用美国国家和海洋大气管理局(NOAA)的大气温度数据, 分析陆地地震和海洋地震震前震中上空的大气温度变化, 研究其作为地震短临前兆的可能性.地震样本包括2014年2月12日于田M_s7.3地震、2008年5月12日汶川M_s8.0地震、2011年3月11日日本M_s9.0地震、2014年4月1日智利M_s8.1海洋地震、2013年3月27日台湾南投县M_s6.1地震和2014年5月30日云南盈江M_s6.1地震.结果表明: (1)震前, 震中位置300~1 000 hPa大气温度有较为一致的变化趋势; (2)200 hPa与400 hPa处(根据不同地点可选择其他, 诸如350 hPa、300 hPa等高度数据)温度折线图在震前趋近或者相交, 出现类似蝴蝶翅膀的"蝴蝶形"特殊曲线形状; (3)200 hPa与400 hPa温度差等值线图在(震前数月、数周或数天不等)震中附近区域的数值减小, 温度差等值线图的塌陷最低点对应震中位置.以上规律有望应用于地震短临预测的时间与震中的确定.      

亚洲地区EGNOS天顶对流层延迟模型单站修正与精度分析

以亚洲地区46个IGS站2008-2011年实测的高精度天顶对流层延迟（ZTD）数据为参考值,通过对2008-2010年EGNOS模型计算ZTD的日均偏差进行频谱分析,建立了亚洲地区EGNOS模型的单站修正模型（SSIEGNOS）,对EGNOS和SSIEGNOS模型在亚洲地区的精度和适用情况进行了评估,结果表明：（1）EGNOS模型偏差和RMS在时间分布上呈现明显的季节变化规律,而SSIEGNOS模型偏差和RMS变化较小且平稳;（2）在空间分布上,两种模型的偏差随着经纬度和高程的变化均无明显规律,但随着高程或者纬度的增加RMS总体上都有递减的趋势;（3）SSIEGNOS模型预测ZTD的精度相对于EGNOS模型有明显提高。     

COMPASS三频数据线性组合优化选取分析

以北斗卫星1支路频点为例,从消除或减弱电离层影响、对流层影响和观测噪声与多路径误差3个方面分析COMPASS三频数据线性组合的优化选取问题,并通过MATLAB模拟,给出一些典型的组合,分析它们可能的应用,为COMPASS三频数据线性组合的优化选取提供一些借鉴。