Zinc-rich Pyrite from the TAG Active Mound, the TAG Hydrotherma Field, Mid-Atlantic Ridge

Abstract: Pyrite rich in Zn, up to 3.1 wt%, was found in the TAG active mound of the TAG hydrothermal field, the slow-spreading Mid-Atlantic Ridge at 26°08'N and 44°49'W. The Zn-rich pyrite is characterized by an optical homogeneity, a homogeneous distribution of Zn in the back-scattered electron images, both at a magnification of about 500, a negative correlation between Fe and Zn contents of the pyrite and a rather small unit cell edge (a₀ = 5.4117 ± 0.0008Å), strongly indicating that the detected Zn is present in the pyrite in solid solution. Such Zn concentrations are observed exclusively in dendritic pyrite, suggesting that the Znrich pyrite grew from hydrothermal fluids of a high degree of supersaturation due to quenching on the seafloor.     

遗传算法在非线性地下水经济管理模型中的应用

通常采用基于梯度的数学规划方法求解地下水管理模型,如线性规划和非线性规划。但对于高度非线性、非凸的优化问题,尤其是涉及到经济或环境的地下水管理模型,传统方法难以有效地寻找全局最优解。本文介绍了一种求解非线性地下水资源管理模型的遗传算法,并以山东羊庄盆地分布参数地下水系统非线性管理模型为例,给出了用遗传算法在求解这类问题的一般步骤。结果表明该方法能快速有效地找到全局最优解。     

计算样本相似性在油气预测中的应用

介绍了计算样本相似性方法在油气预测中的应用的基本原理和技术。提出了利用参数的显著性进行参数优化和加权的方法。该方法简单、实用，并在塔北某区的应用取得了满意结果。由此证明了该方法的有效性及在综合信息预测工作中进行参数优化和加权工作的重要性。     

An Unusual Texture: Skeletal Sphalerite in Pyrite from Dajing Tin-polymetallic Deposit, China

Abstract. Skeletal sphalerite with stellar, cruciform and snowflake-like (or cauliflower-like) shapes included in pyrite is widely found in the Dajing tin-polymetallic deposit. It occurs only in chalcopyrite-pyrite mineralization stage. The compositions of all sphalerites in the chalcopyrite-pyrite stage are characterized by high Cu content (3.9 - 7.0 wt% with a mean of 5.4 wt%), while the skeletal crystal sphalerite has higher zinc and cadmium contents, and lower copper and iron contents, compared with other sphalerites of the same stage. The skeletal crystal sphalerite in pyrite is possibly generated by exsolution.     

含油气盆地蒸发盐矿物成因类型及其地质意义*

中国是一个多盐湖国家,然而盐湖研究主要集中于分析湖水化学性质、盐类物质来源和盐矿资源开发等,对盐类矿物沉积特征和埋藏成岩改造研究较少,造成从蒸发岩角度去理解古代盐湖盆地的油气富集规律较为困难。在广泛阅读国内外大型盐湖文献的基础上,笔者介绍了盐湖分类方案和蒸发岩中盐类矿物的主要成因类型,并总结了中国陆相含油气盆地中常见的硫酸盐、氯化物、含钠碳酸盐和硼酸盐的沉积—成岩过程及其古环境和古气候意义。同时,尝试利用盐湖沉积最新研究成果去探讨中国含油气盆地蒸发岩研究中存在争议或值得关注的问题,得出: (1)深部热液可为湖泊输送大量元素离子,但要在湖泊环境下富集大量蒸发岩,则(半)干旱气候和蒸发浓缩作用是前提条件;(2)易溶蒸发岩(如石盐)在沉积中心单层厚度大,而在斜坡—边缘区缺失,这是季节性气温变化和温跃层浮动引发“中心聚集效应”的结果;(3)温度可影响蒸发岩中盐类矿物溶解度、晶体结构形态和发育深度,而部分无水盐类矿物在常温常压下却无法结晶,这一现象可用来指示古地温和地层埋藏史;(4)碳酸盐型盐湖中的Na-碳酸盐种类可指示大气CO₂浓度和古温度。     

我国藻菌生物成因的金矿研究

生物成矿作用分为生物直接成矿作用和生物间接成矿作用,生物直接成矿作用的标志结构为生物有机胶体结构。生物间接成矿作用的标志结构为“矿交代生物”结构,我国陕西二台子－半仓沟金矿,四川东北寨金矿、川甘拉尔玛金矿和云南金厂金矿等均为典型为实例,矿石中普遍含有多种金属矿物生物结构,还含多种生物有机组分。成矿物质具有多源性特征,硫同位素具混合型特征,矿床成型机制可与“人工碳吸附系统”聚金机制相类比,含金层位可     

Characterization of an Area Polluted by Copper and Zinc:the Relation between Soil Texture,Mineralogy and Pollutant Concentration

Abstract: Twenty-four soil samples were collected at three depths from an approximately 2.5 acre contaminated site in southern Piedmont (Italy) and then analyzed. The main soil parameters determined were: pH, Cation Exchange Capacity (CEC), particle size distribution, total organic carbon (TOC) content and retained metal concentration. The mineral phases were identified by X-Ray Powder Diffraction (XRPD). All of the samples contained Zn and Cu resulting from industrial contamination during the last century, and those obtained at depths of 20-40 cm consistently showed the highest levels. To determine which size fraction was most active in the retention process, the samples were separated into four fractions (≤2 mm, ≤63 μm, ≤30 μm and ≤2 μm) and the amount of pollutant measured in each. It was found that metal retention was the highest in the clayey fraction, whose clay minerals were identified by XRPD after K+ and Mg2+ saturation, glycerol treatment and heating to 550°C. The clayey fraction was also the richest in TOC, and a direct correlation between TOC amount and metal retention was observed.     

Application of PSO-LIBSVM in Recognition of Potassium Salt Deposits

The shortage of potassium salt seriously restricts the development of China's agriculture. Increasing the exploration and development of potash will help improve the self-sufficiency of potassium in China. With rich potassium salt resources, Sichuan basin is one of the most important research areas for potash exploration and development in China. Polyhalite is an important solid potassium salt mineral in Sichuan basin, often intercalated in rock minerals such as anhydrite, rock salt and dolomite. Aiming at the problem that conventional log interpretation methods are difficult to accurately identify polyhalites, this paper proposed a new Support Vector Machine (SVM) recognition method based on Particle Swarm Optimization (PSO) to classify polyhalites in Sichuan basin. Based on particle swarm optimization and support vector machine theory, combined with logging interpretation theory, the effective data sensitive to polyhalite logging response were selected as input samples to generate training sets and test sets randomly. The Radial Basis Function (RBF) parameters were optimized by particle swarm optimization, and the classification and prediction model of polyhalite was established. Compared with mud logging results, the recognition accuracy of SVM model based on particle swarm optimization reached 97.5758%, which is obviously better than that of SVM model optimized by cross validation method in recognition accuracy and speed. The results show that the model has broad application prospects in potash exploration in Sichuan basin.     

基于PSO-PP的围岩稳定性评价

围岩的稳定性评价是一个复杂的不确定系统问题。结合投影寻踪方法、粒子群算法和逻辑斯谛曲线函数,建立了围岩稳定性评价的粒子群优化投影寻踪(projection pursuit based on particle swarm optimization,PSO-PP)模型。该模型一方面采用粒子群算法优化投影指标函数及逻辑斯谛曲线函数参数,确保了模型的准确性;另一方面利用逻辑斯谛曲线函数建立投影值与经验等级之间的非线性关系。模型的测试结果显示了良好的精度,实例分析结果与实际状态完全一致,表明该模型在围岩稳定性评价中的可行性和有效性。     

支持向量回归机在滑坡安全可靠度评价中的应用研究

探讨支持向量机的参数优化方法,将学习能力较强的支持向量机引入滑坡可靠度评价当中,并根据数理统计的理论,对滑坡稳定性敏感性因素作数据处理,并证明其合理性,在此基础上提出一种改进的可靠度指标的计算方法。为便于对比,分别选取49个学习样本和121个学习样本两种计算模型,计算实例表明,这两种计算模型与蒙特卡洛模型计算结果非常接近,充分体现了在小样本的情形下支持向量机的优势,说明将其应用于滑坡安全可靠度评价中是可行的。