X射线荧光光谱法测定高铝粘土中主成分方法研究

使用日本理学ZSX PrimusⅡ型X射线荧光光谱仪,采用熔融玻璃片和经验系数进行基体校正的方法,对我室6件国家标准物质、4件监控样以及用标样和纯值试剂配制的21件混合标准进行组分测定。分析结果表明,此方法能快速、准确测定高铝粘土中主成分Al2O3、SiO2、Fe2O3、TiO2,其准确度和精密度均能达到国家标准方法规定的要求。     

油气化探酸解烃标准样品研制

介绍了油气化探酸解烃标准样品的研制过程,研究了酸解烃标准样品的制备,通过对酸解烃标准样品的均匀性检验、稳定性检验,保证了所研制的酸解烃标准样品是符合标准样要求的。通过对酸解烃标准样品的多次分析数据的统计处理,确定了该标准样品的值和不确定度。另外,通过对酸解烃标准样品的保存试验研究,确定了该样品的包装和有效期。     

丹宁棉分离富集—发射光谱法同时测定地质样品中微量铌钽锆铪

采用丹宁棉对地质样品溶液中的铌、钽、锆、铪进行分离富集，将写信后的丹宁棉在600℃灼烧30min，灰分用发射光谱法同时测定四元素。检出限与通常的发射光谱法相比降低约2个数量级，经国家级标准物质检验，结果与标准值相符，精密度试验，各元素的RSD（n＝20）为2.6％－7.9％。     

Determination of Total Sulfur in Thirty One Geochemical Reference Materials Using an Inductively Coupled Plasma-Atomic Emission Spectrometer Fitted with a Semiconductor Photodiode Detector

The total sulfur contents of thirty one geochemical reference materials were determined using an inductively coupled plasma-atomic emission spectrometer fitted with a semiconductor photodiode detector. Most samples were decomposed using an HF-aqua regia digestion. However, a few were incompletely decomposed by simple acid digestion, and these were decomposed by a fusion method. The agreement between the analytical results from this work and published data is generally good.     

Experimental Studies on Partial Melting of Massive Samples of Granite

As a basis of modern petrology,the equilibrium relations describing the melting of granite were established mainly on melting experiments of Powder samples.Such experiments,however,have serious limitations in providing information about the variations in compositional and fabric features of the minerals and in the composition and distribution of the melt.Our experiments using massive samples indicate that melt occure mainly at the quartz-plagioclase and quartz-potash feldspar boundaries and the composition of the melt is dependent on local characteristics in the melting system,showing no correlation with the bulk composition of the rock samples.At lower temperatures(740-760℃,0.2GPa),the melt plots at or near the eutectic point in Q-Ab-Or-An-H2O diagram,indicating equilibrium melting.At higher temperatures(790-800℃，0.2GPa)the melt becomes lower in SiO2 and higher in Na2O,deviating makedly from the eutectic line but without disappearance of any mineral phase,suggesting a non-equilibrium process.It is obvious that the phase-equilibrium relations in natural massive granites may be greatly different from those deduced from powder experiments.     

计算极谱法同时测定地质样品中铅锡的研究

采用ＪＰ－１Ａ极谱仪与计算机联机技术用卡尔曼滤波数学方法，解析以盐酸为支持电解质的铅（Ⅱ）和锡（Ⅲ）混合试液的极谱重叠波，同时用于地质样品测定，结果令人满意。     

Sampling, Sample Preparation and ICP-MS Chemical Analysis of Lake Baikal Sponges

Procedures for sampling, sample preparation and ICP-MS analysis of endemic sponges from Lake Baikal have been developed. Sample decomposition was carried out using an open acid decomposition with ultrasound treatment. The distribution of nineteen elements (Mg, Al, P, Ca, Ti, Mn, Co, Ni, Cu, Rb, Sr, Y, Cd, Ba, La, Ce, Pb, Th and U) in different parts of a sponge's body (outer and inner layers and layers adjacent to the substratum) was studied. Detection limits were determined; these ranged from 0.013 to 4.12 μg g^-1 for trace elements and from 23 to 130 μg g^-1 for biogenic elements. The degree of elemental uptake by living substances is discussed with regard to the environment.     

Trace Element Determination by ICP-AES and ICP-MS: Developments and Applications Reported During 2004 and 2005

This review describes significant developments in trace element determination using inductively coupled plasma-atomic emission spectrometry (ICP-AES) and inductively coupled plasma-mass spectrometry (ICP-MS) that were reported in 2004 and 2005. It focuses on the application of ICP techniques to geological and environmental samples; fundamental studies in ICP-MS and ICP-AES instrumentation are not included. The literature reviewed indicated that the majority of new publications concerned advances in ICP-MS analysis rather than ICP-AES. However, ICP-AES developments are still being published, particularly in the areas of sample preconcentration and sample introduction. The trend in increasing publication of developments in hyphenated speciation techniques looks set to persist as knowledge of elemental speciation becomes critical for many environmental studies. Collision or reactions cells were the most reported technique for spectral interference removal in ICP-MS, probably reflecting the growing adoption of cell instruments in laboratories during the last few years.     

介绍一种简易快捷的煤层瓦斯含量的计算方法

大量煤层瓦斯解吸资料表明，解吸瓦斯量（Q）与煤样气体解吸时间的开方（θ），呈Q=ab/θ（b＜0）曲线的相关关系一依据这种关系，由现场瓦斯煤样的解吸资料，建立起θ与Q的回归方程，再按《煤层气测定方法（解吸）MT／T77—1994》中的有关规定计算出损失瓦斯及在化验室测试的常温下煤层瓦斯的自然组分、可燃物质量等数据，进而便可求得煤层瓦斯含量值。该方法在江西省丰城矿区石上井田勘探工作中取得了较好的效果。     

同位素稀释等离子体质谱法准确测定地质样品中痕量铼

采用Carius管高温密闭溶样,同位素稀释-电感耦合等离子体质谱法对黄铁矿、岩石等地质样品中痕量铼进行了准确测定。流程空白能够有效控制在1．4～10 pg。对岩石样品中 ng／g量级的Re进行分析,4次重复分析结果的RSD为3．89％(2s)。以辉钼矿国家标准物质作为本方法研究的监控样品,重复分析结果与其标准推荐值(17．39±0．32)μg/g吻合。