太湖入湖河口和开敞区CDOM吸收和三维荧光特征

应用吸收和三维荧光光谱对2007年夏季太湖入湖河口和大太湖开敞区有色可溶性有机物(CDOM)浓度及来源进行研究.结果表明,河口区和开敞区CDOM吸收系数a(355)存在显著空间差异,河口区明显大于开敞(ANOVA,P<0.001),a(355)最大值出现在大浦河口和竺山湾漕桥河几附近,最小值出现在东太湖和胥口湾.a(355)与溶解性有机碳、化学耗氧量浓度存在显著正相关.所有样品一般都含有4个明显的荧光峰,包括1个可见光区的类腐殖质荧光C峰,1个紫外光区的类腐殖酸荧光A峰,2个类蛋白荧光B峰和D峰.河口区外源输入的类腐殖质荧光非常强,最著大于开敞区(ANOVA,P<0.05).而河口区和开敞区类蛋白荧光没有显著性差异,反映开敞区除外源河流输入外,内源生物降解等对类蛋白荧光贡献增加.在河口区B、C峰的比值r(B/C)/b于1,均值为0.62±0.14、在开敞区r(B/C)除12#是0.92,其他值均大于1,均值为1.12±0.13,初步判断r(B/C)可以作为区分CDOM来源的重要参数.CDOM吸收a(355)与类腐殖质荧光C峰、A峰均存在极显著的正相关,而与类蛋白荧光相关性则明显下降,与D峰存在显著正相关,与B峰没有显著相关.     

竖向断层对场地地面运动的影响

本文采用二维显式有限元结合透射边界的数值方法,考虑均匀弹性半空间内存在着不同宽度及深度的断层,由下向上分别垂直和斜(30°)入射一个脉冲波,研究非发震断层地面运动的一些特点。通过计算断层内外地震地面运动传递函数的幅值谱,并与自由场反应对比,以说明竖向断层对地震波传播和附近地面运动的影响,在此基础上进一步对断层周边一般结构抗震设计是否要考虑断层影响提出了几点建议。     

GNMF小波谱分离在地震勘探噪声压制中的应用

地震勘探资料噪声压制及信噪比提高是整个地震勘探信号处理过程中的重要任务,随着地震勘探深度的增加及其复杂性,人们对地震数据质量的要求越来越高.勘探环境的复杂化使得采集到的地震资料中有效信号被大量噪声淹没,无法清晰辨识,严重影响后续的数据处理与解释.小波去噪是地震勘探中常用且发展较成熟的一种方法,但是其涉及到的阈值函数选取问题一直令人困扰,虽然已有多种阈值函数被提出,但仍存在各自的缺陷.本文利用小波分解在时域及频域良好的信号细节体现特性,引入模式识别中的非负矩阵分解(NMF)谱分离思想,针对小波系数阈值优化问题,提出了一种小波域图非负矩阵分解(GNMF)消噪算法.该方法首先在小波分解基础上,利用GNMF算法实现小波分解系数谱中信号分量与噪声分量的谱分离,然后通过反变换重构各分离子谱对应的子信号,最后利用K均值聚类算法将得到的多个子信号划分为信号类及噪声类,最终得到重构信号及分离噪声.合成记录和实际地震资料的消噪结果验证了新方法在提高信号与噪声分离准确性和精度方面的有效性,同时新方法避免了阈值选取造成的噪声压制不理想或有效成分损失问题.与小波消噪结果的对比及数值分析也说明了新方法在噪声压制及有效成分保持方面的优势.     

AHDEB油田白垩系油藏油气充注期次的流体包裹体证据

伊拉克AHDEB油田油藏成藏规律对油田后期开发具有重要意义, 与埋藏史相结合的流体包裹体研究是揭示油藏油气成藏期次和时间的有效手段.利用伊拉克AHDEB油田白垩系油藏储层样品对流体包裹体特征进行了分析, 并且通过流体包裹体的显微观察、荧光颜色、单一包裹体的红外光谱和均一温度测定, 结合地质背景对该油田的油充注期次进行了研究.研究表明, 油包裹体以发绿色和黄绿色荧光为主, 少数发浅黄色和黄褐色荧光.油包裹体的显微傅立叶红外光谱测定结果计算的CH_2a/CH_3a、X_inc、X_std可划分油的成熟度, 表明存在两种成熟度的油.最后, 根据均一温度测定结果, 结合埋藏史和热史, 认为该油田可能存在4期油充注成藏相关的流体活动: 第1成藏期发生在95.0~96.5Ma, 相当于晚白垩世早期; 第2成藏期为71.0~78.5Ma, 相当于晚白垩世晚期, 第1期和第2期烃源岩排烃规模小, 产生中-重质油, 后期遭受氧化而形成沥青; 第3成藏期发生在14.0~15.0Ma, 相当于中中新世, 处于生排烃高峰期, 为主要成藏期; 第4期发生在10.0Ma左右, 与第3期为多幕连续充注.      

Calculation of the structure and transition probabilities of low energy levels of Fe and Fe

We use analytical wave functions in intermediate coupling to make a complete relativistic calculation of the structure and transition probabilities for the n = 1, 2, 3 states of Fe⁺²⁴. Data for Fe⁺²⁵ are also given for comparison. The results have a high accuracy and those relating to the n = 3 state are given in detail for the first time here.     

Grain-size spectra maps of beaches in W. Peloponnese, Greece

Grain-size spectra maps of sands from beaches of the western Peloponnese are related to statistical parameters and can be used to infer characteristics of the sedimentation process involved which were unresolved by previous statistical analysis. On the basis of similarities in spectral patterns, the studied beaches fall into four groups: A, B, C, and D. The periodicity observed on the sinuous pattern of the spectra map of groups A and B is interpreted as indicating edge-wave activity. Regarding group D, the gradual W—E increase of particle size along the coast suggests a W—E increase of wave energy, which is also reflected by the inclined trend of the spectra map. Lack of periodicity on the contour pattern of group C probably reflects intensive sample-to-sample sorting variation.     

绝对和相对输入能量谱对比及延性系数的影响研究

利用266条强震记录,在研究绝对输入能量谱和相对输入能量谱衰减规律的基础上,对由衰减关系所确立的两种输入能量谱进行对比分析,讨论了延性系数对这两种输入能量谱的影响. 研究发现,在弹性情况下,两种输入能量谱在周期0.5~1.0 s范围内相差不大; 在非弹性情况下 两种输入能量谱在周期0.5 s处相差不大. 周期较小时,绝对输入能量谱要大于相对输入能量谱;周期较大时,绝对输入能量谱小于相对输入能量谱. 延性系数对这两种输入能量谱影响均比较大, 对绝对输入能量谱而言,周期小于0.3 s时,随着延性系数的增大, 能量谱升高;周期大于0.3 s时,随着延性系数的增大能量谱降低. 不同延性系数的绝对输入能量谱在分界点0.3 s左右相等. 相对输入能量谱受延性系数影响与绝对输入能量谱相似, 但分界点在0.5 s左右. 与绝对输入能量谱相比, 相对输入能量谱在短周期段受延性系数的影响较大, 特别是当场地较软时更为明显.      

Cathodoluminescence of authigenic albite

Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn²⁺- and Fe³⁺-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE).     

On the correction of spectra by a displacement reduction factor in direct displacement-based seismic design and assessment

The application of some design and assessment approaches, such as the direct displacement-based design (DDBD) and the capacity spectrum methods, requires the modification of elastic design spectra by some displacement reduction factor, to account for the appropriate energy dissipation capacity of different structures. While several equations to correlate dissipation and hysteresis cycles are available, once the displacement reduction factor has been obtained, the correction of the spectra is operated reducing the displacement demand accordingly and conserving the period of vibration at each point. This procedure is here discussed and proved to be conceptually inappropriate, because the spectral acceleration rather than the period should be kept at each point. The application of this alternative procedure may result in increased shear strength demand in design and in larger required displacement capacity for the same level of strength in assessment, if all other factors are not modified. However, the calibration of the reduction factors applied in DDBD has been extensive, and the method has proved to be effective in predicting displacement demands consistent with those resulting from refined nonlinear time history analysis; therefore, a possible introduction of the proposed correction will require equally extensive studies and possibly compensating corrections in the calculation of the equivalent damping. On the contrary, an appropriate calibration of the factors to be used in the application of the “capacity spectrum” method is still being developed, and the consideration of a constant acceleration may facilitate the derivation of effective equations.     

REMOTE SENSING OF THE SEASONAL VARIATION IN COLUMN ABUNDANCE OF ATMOSPHERIC CH4*

Infrared solar spectra on clear days were measured automatically by an infrared solar spectrometer(ISS) with 0.4 cm^-1 resolution developed by us.A line-by line(LBL) computation method was used to calculate theoretical atmospheric absorption.In the wavelength range of 3.410-3.438 μm.the absorption is mainly due to atmospheric methane and water vapor.Columnatmospheric methane was retrieved from the recorded infrared solar spectra.The seasonal variation of column atmospheric methane in Hefei has been obtained from the measuremental data of nearly 18 months since the April of 1997.and found that it is similar to that of background data.The instruments.principles of measurement and some of results were introduced,and the results are also discussed briefly in the paper.