Total gaseous mercury emissions from mercury-enriched soil in Guizhou, China

Guizhou is located in the Circum-Pacific Global Mercuriferous Belt, and mercury concentrations in soil in this area are enriched. In-situ total gaseous mercury （TGM） exchange fluxes between air and soil surface were intensively measured at four sampling sites in Guiyang from 21 May to 16 June, 2003, and five sites in the Lanmuchang mercury mining area in December 2002 and May 2003, respectively. The in-situ Hg flux measurement was conducted with a dynamic flux chamber （DFC） of quartz. Overall, net emissions were obtained from all sampling sites. Soil mercury concentration and solar radiation have been proved to be the two most important parameters to control mercury emissions from soil. Meanwhile, rain events can enhance mercury emission rate significantly.     

Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.     

Preparation of a geotechnical microzonation model using Geographical Information Systems based on Multicriteria Decision Analysis

The purpose of this study is to develop a geotechnical microzonation model using Geographical Information Systems (GIS) based on Multicriteria Decision Analysis (MCDA). As study area, the Eskişehir downtown area has been chosen. Eskişehir is one of the most rapidly growing cities in central Turkey. The model inputs include slope, flood susceptibility, soil, depth to groundwater table, swelling potential, and liquefaction potential. The weight and rank values are assigned to the layers and to the classes of each layer respectively. The assignment of the weight/rank values and the analysis are realized by the application of two different decision models, namely Simple Additive Weighting (SAW) and Analytic Hierarchy Process (AHP) methods. The geotechnical microzonation maps prepared as outputs of these methods are found to be consistent with each other and confirmed by the experts within the study area. The geotechnical microzonation map prepared using the AHP method is recommended as the final map of the study.     

Mineralogical and chemical transformation of Oldoinyo Lengai natrocarbonatites, Tanzania

The minerals of Oldoinyo Lengai natrocarbonatite lavas are unstable under atmospheric conditions. Subsolidus mineral assemblages in natrocarbonatites were studied in 105 samples from contemporary eruptions ranging from present day to about 100 years old. The subsolidus minerals in natrocarbonatites were formed (i) along cracks on the lava surface from hot gases escaping during cooling, (ii) as atmospheric alteration by solution of water-soluble minerals, in particular halides and gregoryite, and by hydration of nyerereite under the influence of meteoric water and (iii) by reaction with fumarole gases. After solidification, the lavas were cut by a network of thin cracks, the edges of which are covered by polymineralic encrustations. Samples collected 2–24 h after eruption contain nahcolite, trona, sylvite, and halite with accessory kalicinite and villiaumite. Atmospheric humidity results immediately (≥ 2 h after eruption) in alteration of black lavas that is marked by the appearance of white powdery thermonatrite with nahcolite on the lava surface. Subsequent reaction (weeks, months, years) of natrocarbonatite with meteoric water and the atmosphere results in the formation of pirssonite, gaylussite, shortite, trona, thermonatrite, nahcolite and calcite. Generally, the first important step is the formation of pirssonite and the end-members are calcite carbonate rocks or loose aggregates. Fumarolic activity is common for the active northern crater of the volcano. Reaction of hot (54–141 °C) fumarolic gases with natrocarbonatite leads to the formation of sulphur, gypsum, calcite, anhydrite, monohydrocalcite, barite and celestine. Changes in mineralogy of the natrocarbonatite lead to substantial chemical transformation. The most obvious chemical changes in this process are the loss of Na, K, Cl and S, combined with an increase in H₂O, Ca, Sr, Ba, F and Mn. The oxygen and carbon isotopic composition of altered natrocarbonatites shows a significant shift from the primary “Lengai Box” to high values of δ¹⁸O and δ¹³C. Calcite exhibits δ¹³C values between − 2‰ and − 4‰ PDB and δ¹⁸O values of + 23‰ to + 26‰ SMOW. The observed assemblages of secondary minerals formed by reaction with atmosphere and meteoric water, the changes in chemical composition of the natrocarbonatite and field observations suggest that alteration of natrocarbonatite is an open-system low-temperature process. It takes place at temperatures between 8 and 43 °C with the addition of H₂O to the system and the removal of Na, K, Cl and S from the carbonatites. Low-temperature thermodynamic models developed for alkali carbonate systems can be used for the interpretation of Oldoinyo Lengai subsolidus mineralization.     

Groundwater study using remote sensing and geographic information systems (GIS) in the central highlands of Eritrea

Remote sensing, evaluation of digital elevation models (DEM), geographic information systems (GIS) and fieldwork techniques were combined to study the groundwater conditions in Eritrea. Remote sensing data were interpreted to produce lithological and lineament maps. DEM was used for lineament and geomorphologic mapping. Field studies permitted the study of structures and correlated them with lineament interpretations. Hydrogeological setting of springs and wells were investigated in the field, from well logs and pumping test data. All thematic layers were integrated and analysed in a GIS. Results show that groundwater occurrence is controlled by lithology, structures and landforms. Highest yields occur in basaltic rocks and are due to primary and secondary porosities. High yielding wells and springs are often related to large lineaments, lineament intersections and corresponding structural features. In metamorphic and igneous intrusive rocks with rugged landforms, groundwater occurs mainly in drainage channels with valley fill deposits. Zones of very good groundwater potential are characteristic for basaltic layers overlying lateritized crystalline rocks, flat topography with dense lineaments and structurally controlled drainage channels with valley fill deposits. The overall results demonstrate that the use of remote sensing and GIS provide potentially powerful tools to study groundwater resources and design a suitable exploration plan.The online version of the original article can be found at     

Effect of a submerged bay-mouth breakwater on tsunami behavior analyzed by 2D/3D hybrid model simulation

The hybrid numerical model had been developed to simulate a complicated 3D flow around structures generated by tsunami. In the model, the conventional 2D model is adopted for the wide region far from structures and the 3D non-hydrostatic pressure model is used in the limited region adjacent to structures. The applicability of the model is shown by comparisons of the numerical results with the experimental results of the laboratory model tests and the numerical analysis results of the conventional whole 2D simulation. In addition, the effect of a submerged structure at the opening of a breakwater is discussed from the numerical simulations by the hybrid model. The submerged structure improves the stability of the rubble mound and reduces the tsunami inflow into the bay, while it increases the water surface velocity around the opening of the breakwater. The increase of surface velocity causes the increases of impulsive forces by collision with drafts and so on.     

Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.     

Assessment of sand encroachment in Kuwait using GIS

Assessment of sand encroachment in Kuwait using Geographical Information System (GIS) technology has been formulated as a Multi-Criteria Decision Making problem. The Delphi method and Analytical Hierarchy Process were adopted as evaluating techniques, in which experts’ judgments were analyzed for objectively estimating and weighting control factors. Seven triggering factors, depicted in the form of maps, were identified and ordered according to their priority. These factors are (1) wind energy; (2) surface sediment; (3) vegetation density; (4) land use; (5) drainage density; (6) topographic change and (7) vegetation type. The factor maps were digitized, converted to raster data and overlaid to determine their possible spatial relationships. Applying a susceptibility model, a map of sand encroachment susceptibility in Kuwait was developed. The map showed that the areas of very high and high sand encroachment susceptibility are located within the main corridor of sand pathway that coincides with the northwesterly dominant wind direction.     

Experimental and numerical studies of rock salt strain hardening

The work presented in this paper comes as part of a research program dealing with the thermomechanical behaviour of rock salt. It aims to study laboratory and in-situ long-term behaviour by means of creep tests with deviator and temperature changes. The laboratory results, using a triaxial multi-stages creep tests, highlighted the strain hardening character of rock salt. Furthermore, the in-situ results, using a borehole dilatometer multi-step creep test, have shown that the drilling is carried out in a weakly stressed pillar. The interpretation of the laboratory results, using the J.LEMAITRE law, did not indicate full agreement with all the test results. As a result a ‘double’ J.LEMAITRE model, which takes into account a double strain hardening variable, has been put forward. The validation of this model on the laboratory creep tests is very satisfactory. Furthermore, the activation energy seems satisfactory to represent the influence of the temperature. The in-situ behaviour modelling is clearly more complex than the modelization based on laboratory tests. In fact, it seems that if the rock salt behaviour is maintained by J.LEMAITRE law, it is necessary to vary with the stress, at least, one of the parameters assumed constant in the basic law.     

A Bay–River Coupled Model for Storm Surge Prediction Along the Andhra Coast of India

The paper describes a two-dimensional bay–river coupled numerical model for storm surges along the Andhra coast of India. The effect of the Krishna and Godavari rivers on the surge development is analysed. A comparative study of the surge generated by a tropical cyclone with and without the inclusion of rivers is done in detail. Three cyclones that struck the Andhra coast in November 1977, May 1990 and November 1996 were used for the simulation studies. It is found that the idealized model without a river overestimates the sea-level elevation as compared to a more realistic bay–river coupled model. The temporal variation of surge values at the mouth of the rivers is also studied for all three cyclone cases. It is found that the effect of the presence of rivers depends on the strength of the cyclone, its point of landfall and the location of the rivers with respect to the landfall point.