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101.
102.
为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究。土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿。结果表明:苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的升高而迅速下降;可用零级反应动力学方程拟合铁氧化物还原溶解反应,针铁矿溶解反应的强度与介质的pH值呈负相关关系;天然针铁矿对酚类污染物的氧化降解能力明显高于合成针铁矿,pH值对天然针铁矿溶解反应影响较大;可用一级指数衰减方程拟合锰氧化物还原溶解反应,锰氧化物溶解反应的强度与介质的pH值呈指数衰减关系;pH值对软锰矿还原溶解反应的影响大于对土壤中氧化锰的影响,pH值越小,影响越显著;对比pH值对铁和锰还原作用的影响发现,在pH=6.5时,锰氧化物仍有较强的氧化性能。 相似文献
103.
Natural and compacted soils are usually characterized by aggregation of particles. The mechanical behaviour of these materials
depends on soil structure. The oedometric compression tests performed on aggregated samples presented here showed that these
materials exhibit a yield limit depending not only on stress history and stress state but also on soil structure. Evidence
is provided using the neutron tomography technique. These results revealed that soil structure modification occurs together
with plastic deformations. The experimental results are used to propose a new state parameter to quantify the soil structure.
Based on pore-scale experimental observations, an evolution law for this parameter is proposed as a function of associated
plastic strains. Considering both soil fabric and inter-particle bonding effects, a new yield limit depending on stress state,
stress history and soil structure is introduced for the aggregated soils. Accordingly, a new constitutive framework consistent
with strain hardening plasticity is proposed to consider soil structure effects in the modelling of aggregated soils. 相似文献
104.
Changing grading of soil: effect on critical states 总被引:3,自引:3,他引:3
Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles
leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine
material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical
states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the
dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state
conditions as the grading changes. 相似文献
105.
106.
在引入围桩-土耦合式抗滑结构的基础上建立数值分析模型;通过分析该抗滑结构中围桩-土的应力、应变分布规律,详细探讨围桩-土整个结构的耦合效应特征。进一步开展模型试验,测试并分析围桩前、后土压力和桩身弯矩分布特征,论证了围桩-土耦合式抗滑结构的作用机制。最后,分析了桩后距离、不同深度及不同土体强度参数对土拱效应的影响。得到:(1)围桩与桩内土体耦合呈现出4种应力拱形态:紧邻围桩后为扩肩型拱、围桩间双曲线型拱、围桩间凸向桩外的抛物线型拱、围桩间凸向桩内的抛物线型拱;(2)相邻围桩采用约4倍桩径间距、正六边形布置并顶部用圈梁固结、锚固一定深度可形成一种耦合式抗滑结构。该结论对于该新型抗滑结构的推广应用具有一定的指导意义。 相似文献
107.
This paper discusses the results of an investigation on the influence of rainfall intensity and duration on the suction distribution within a soil mass. A series of numerical analyses were conducted on an infinite slope model to simulate the responses of the slope consisting of typical soil types to various rainfall intensities and durations from selected locations in the Malaysian Peninsular. The study showed that the critical duration was governed by three major factors: the saturated permeability of the soil, the geographical location, and the depth of the slip plane. The critical rainfall duration for highly permeable soil was 1 day, while 30 days of antecedent rainfall were required for the stability analysis of a slope made of soil with low saturated permeability. The critical duration of antecedent rainfall in soils with intermediate saturated permeability was found to vary with the rainfall pattern. A chart is proposed to determine the critical duration, critical intensity and critical suction for each type of soil. 相似文献
108.
109.
《Geomechanics and Geoengineering》2013,8(1):28-35
Establishing the soil water retention curve, SWRC or the soil water characteristic curve, SWCC, is very useful for determination of unsaturated properties of soils. However, it has been observed that SWRC of a soil is not unique and depends on various factors such as the initial moisture content, density of soil, method of compaction, soil fabric and the path (drying or wetting) adopted for establishing it. In this context, many techniques and instruments have been employed by earlier researchers for determination of the SWRC of soils. However, these techniques entail weighing of the samples during prolonged testing, manually, and hence yield discrete data points. In this situation, AquaSorp® Isotherm Generator (manufactured by Decagon Devices Inc., USA) has been found to be quite useful for continuous determination of the drying-path SWRC of fine-grained soils. This device has been primarily employed for food products, powders and amorphous materials. Hence, demonstration of the utility and limitations of this device for SWRC determination of fine-grained soils becomes essential. With this in mind, extensive studies were conducted on commercially available soils (Kaolinite and Bentonite) by employing this device. In order to understand the influence of specimen specific parameters on the obtained SWRCs, the molding water content and thickness of the specimens were varied and the results have been evaluated critically. Details of the methodology adopted for these investigations, and the findings of the study are presented in this technical note. Based on a critical comparison of the results obtained from this device with those obtained from the dewpoint potentiameter, WP4®, the utility of this device for continuous determination of drying-path SWRC of the soils has also been demonstrated. 相似文献
110.
紫色土丘陵区典型小流域水体N、P含量及其环境特征 总被引:8,自引:0,他引:8
N、P各形态浓度在川中丘陵区小流域的水体中显示出明显的时空特征,在地表水中,以旱地为主的小流域上部的硝态氮、氨态氮、全氮要低于小流域下部水田的,而以流域人口密度较大的群英池和小流域下部的沟道水中氨态氮浓度较高,说明人为活动对其影响较大。在地下水中以小流域上部为最高,明显高于该流域的中下部;它们的季节变化与流域降水的季节变化基本是一致的。紫色土丘陵区水体富N,地下水NO_3~--N超标率达60%,;地表水和地下水均尚未出现P的富营养,但潜在的污染不可忽视。 相似文献