Are peatlands in different states with respect to their thermodynamic behaviour? A simple test of peatland energy and entropy budgets

Whilst all ecosystems must obey the second law of thermodynamics, these physical bounds and controls on ecosystem evolution and development are largely ignored across the ecohydrological literature. To unravel the importance of these underlying restraints on ecosystem form and function, and their power to inform our scientific understanding, we have calculated the entropy budget of a range of peat ecosystems. We hypothesize that less disturbed peatlands are ‘near equilibrium’ with respect to the second law of thermodynamics and thus respond to change by minimizing entropy production. This ‘near equilibrium’ state is best achieved by limiting evaporative losses. Alternatively, peatlands ‘far-from-equilibrium’ respond to a change in energy inputs by maximizing entropy production which is best achieved by increasing evapotranspiration. To test these alternatives this study examined the energy balance time series from seven peatlands across a disturbance gradient. We estimate the entropy budgets for each and determine how a change in net radiation (ΔR_n) was transferred to a change in latent heat flux (ΔλE). The study showed that: (i) The transfer of net radiation to latent heat differed significantly between peatlands. One group transferred up to 64% of the change in net radiation to a change in latent heat flux, while the second transferred as little as 27%. (ii) Sites that transferred the most energy to latent heat flux were those that produced the greatest entropy. The study shows that an ecosystem could be ‘near equilibrium’ rather than ‘far from equilibrium’.     

Structural damage detection using the optimal weights of the approximating artificial neural networks

This work presents a novel neural network‐based approach to detect structural damage. The proposed approach comprises two steps. The first step, system identification, involves using neural system identification networks (NSINs) to identify the undamaged and damaged states of a structural system. The partial derivatives of the outputs with respect to the inputs of the NSIN, which identifies the system in a certain undamaged or damaged state, have a negligible variation with different system errors. This loosely defined unique property enables these partial derivatives to quantitatively indicate system damage from the model parameters. The second step, structural damage detection, involves using the neural damage detection network (NDDN) to detect the location and extent of the structural damage. The input to the NDDN is taken as the aforementioned partial derivatives of NSIN, and the output of the NDDN identifies the damage level for each member in the structure. Moreover, SDOF and MDOF examples are presented to demonstrate the feasibility of using the proposed method for damage detection of linear structures. Copyright © 2001 John Wiley & Sons, Ltd.     

瑞雷面波在防渗墙无损检测中的应用

瑞雷面波均匀介质理论和弹性层状介质中的频散理论都是在半无限弹性空间基础上进行的，本文通过理论分析将瑞雷面波引申在水平方向宽度有限的墙状介质中应用，结合室内实验和防渗墙施工问题，得出一套完整的无损检测技术，用以控制防渗墙施工质量。     

雄关漫道真如铁——论中国油气二次创业

半个多世纪以来，中国经历了油气资源的第一次创业，在祖国大陆和近海大陆架地区的新生代陆相碎屑岩沉积盆地中，发现了一批油气田，使原油年产量达1．67亿吨，位居世界第五，天然气疸这241亿立方米，居世界第十五位，成绩是巨大的，但是，1993年开始进口原油3000万吨，2000年进口原油7200万吨，严重影响国家经济建设，而且这种趋势还在不断发展，预测2010年将进口原油1亿吨，天然气200亿立方米，那么，中国油气资源的出路何在？作者指出，从中国大地构造演化来看，前新生代海相残留盆地还有巨大的油气潜力，尽管其勘探的难度是世界级的，但是，只要我们切实地依靠科学技术，进行油气资源的二次创业，困难上，在实践中克服困难，就可以发现更多的石油天然气，支持国家经济建设的持续发展。     

Kinetics,Mechanistic and Thermodynamics of Zn(II) Ion Sorption: A Modeling Approach

Biosorption potential of Cedrus deodara sawdust (CDS) in terms of sorption of Zn(II) ion across liquid phase has been evaluated in the present investigation. The surface of the CDS biomass before the sorption of Zn(II) ions seemed to be more porous, non‐crystalline and heterogeneous. The maximum uptake capacity of CDS was 97.39 mg g^?1. Sorption of Zn(II) ion on the surface of CDS sawdust was maximum at pH 5, temperature 45°C, initial concentration of Zn(II) ion 100 mg L^?1, biomass dose 1 g L^?1, contact time 150 min, and agitation rate 160 rpm. Pseudo second‐order kinetics with the highest linear regression coefficient (R² = 0.99), and lowest values of error functions, i.e., chi (χ²) and sum of square errors (SSE) against pseudo first‐order rate kinetics showed that the sorption of Zn(II) ion on the surface of CDS was mediated by chemosoprtive forces of attraction rather than physical adsorption. Mechanistically, relatively higher proportion of sorption of Zn(II) ion in early phase of contact time was profoundly explained by Bangham's equation and film diffusivity (D^f). Intraparticle or pore diffusion (D_p) of Zn(II) ion inside the pores of CDS was rate limiting step at the later stage of contact time. Furthermore, the thermodynamic study on sorption of metal ion delineated the fact that the Zn(II) sorption on the surface of CDS was spontaneous, endothermic together with increased entropy at solid liquid interface.     

Vertical dynamic response of a disk on a saturated poroelastic half-space

This paper considers the vertical dynamic response of a disk on a saturated poroelastic half-space. Firstly the pressure-solid displacement form of the harmonic equations of motion for a poroelastic solid are developed from the form of the equations originally presented by Biot. These equations are solved by a new method. Then the mixed boundary value problem for the vertical harmonic vibration of a disk on a poroelastic half-space is studied. The two types of drainage conditions at the surface of the poroelastic half-space are considered: (a) the surface of the poroelastic half-space is assumed to be completely pervious both within and exterior to the plate; (b) The interface between the plate and the poroelastic half-space is assumed to be impervious and the exterior region is assumed to be pervious. By using the Hankel transform techniques, the paper develops the governing dual integral equations. These governing integral equations are further reduced to systems of standard Fredholm integral equations of the second kind by Abel transform.     

A finite element solution for the fractional advection–dispersion equation

The fractional advection–dispersion equation (FADE) known as its non-local dispersion, has been proven to be a promising tool to simulate anomalous solute transport in groundwater. We present an unconditionally stable finite element (FEM) approach to solve the one-dimensional FADE based on the Caputo definition of the fractional derivative with considering its singularity at the boundaries. The stability and accuracy of the FEM solution is verified against the analytical solution, and the sensitivity of the FEM solution to the fractional order α and the skewness parameter β is analyzed. We find that the proposed numerical approach converge to the numerical solution of the advection–dispersion equation (ADE) as the fractional order α equals 2. The problem caused by using the first- or third-kind boundary with an integral-order derivative at the inlet is remedied by using the third-kind boundary with a fractional-order derivative there. The problems for concentration estimation at boundaries caused by the singularity of the fractional derivative can be solved by using the concept of transition probability conservation. The FEM solution of this study has smaller numerical dispersion than that of the FD solution by Meerschaert and Tadjeran (J Comput Appl Math 2004). For a given α, the spatial distribution of concentration exhibits a symmetric non-Fickian behavior when β = 0. The spatial distribution of concentration shows a Fickian behavior on the left-hand side of the spatial domain and a notable non-Fickian behavior on the right-hand side of the spatial domain when β = 1, whereas when β = −1 the spatial distribution of concentration is the opposite of that of β = 1. Finally, the numerical approach is applied to simulate the atrazine transport in a saturated soil column and the results indicat that the FEM solution of the FADE could better simulate the atrazine transport process than that of the ADE, especially at the tail of the breakthrough curves.     

物元法在苏州市第Ⅱ承压地下水水质评价中的应用

本文在物元分析理论的基础上,将水质量标准、评价指标及其特征值作为物元,并以苏州市第Ⅱ承压地下水为例进行了水质评价。通过建立评价模型,对评价标准及实测数据进行归一化,得到模型的经典域、节域、权系数及关联度,评价结果表明,苏州市大部分第Ⅱ承压地下水水质优良,达到了Ⅰ、Ⅱ类水,未遭受外来物质的污染,评价结果符合实际情况。     

地层格架正则化约束下的二维立体层析反演

通过把地层格架信息作用于立体层析Fréchet导数矩阵,使得更新后的速度模型呈现出符合地质规律的块状特征.地层格架信息基于立体层析反演中得到的反射点位置进行非规则B样条插值拟合得到,因此在反演中它将会随着反射点位置的更新自然得到更新.与前人提出的保边缘层析算法或多层立体层析算法相比,本文提出的地层格架正则化无需引入混合正则化项或定义某种复杂的混合速度格式,更为直接也更容易实现.理论和实际数据算例证实了该正则化技巧的稳健性和可靠性,能够得到与实际地质构造特征更为一致的地质一致性反演结果.

     

Tsunami 2004: the villages of Birek and Seungko Mulat,Indonesia

The purpose of this study was to investigate the potential of imaging spectroscopy for the discrimination between eucalyptus species. High spectral reflectance signatures of 11 eucalyptus species were measured in the laboratory and significant differences at a number of wavelength positions were detected. There were differences in terms of absolute reflectance, depths of absorption features and the relative position of change in terms of the wavelength. The differences between species were more noticeable in the first derivative spectra when compared with the raw spectra. This was attributed to the ability of derivatives to remove the noise from raw reflectance spectra. The results also indicate the possibility of utilizing the common vegetation indices and ratios used in remote sensing for discriminating species and highlight the need to select spectral channels at pertinent positions where the differences are the greatest. This study has identified many of these positions in relation to some eucalyptus species. However, the study also shows that there is no single wavelength which will discriminate between all species and it also shows that even with hyperspectral data, issues with detailed level of mapping will still exist.