小体积液液萃取气相色谱-质谱法测定地下水中的克百威与3-羟基克百威

克百威和3-羟基克百威是一对典型的农药母体及其代谢产物,由于其水溶性高、毒性大,可通过地表水或地下水进行长距离迁移,对人类健康和环境安全造成危害.以往通常采用液相萃取或固相萃取的方式提取样品中的克百威和3-羟基克百威,但这些方法操作繁琐、耗时较长,不利于室内模拟实验中多组样品的检测.为实现克百威与3-羟基克百威在地下水...     

A modified analytical method for the shipboard determination of nanomolar concentrations of orthophosphate in seawater

A method for the determination of nanomolar concentrations of orthophosphate in oligotrophic seawater developed by Liang et al. (2007) has been modified to make it fully feasible for shipboard application and for faster sample throughput with minimized sample volume. The technique is based on the flow injection method with solid phase extraction on a Sep-Pak C18 cartridge and colorimetric detector. The Schlieren effect was minimized by rinsing the cartridge sequentially with 5 mL water and 2 mL 95% ethanol solution. With three micro pumps in parallel, savings of up to 80% in amount of reagents and 25% volume of seawater samples could be achieved in comparison to the previous method. Variation of stopped flow time and sample loading time gave 3 different standard curves, which corresponded to 3 linear ranges within 3.4 and 515 nM. The modified method permits the analysis of samples over a wide range of concentrations, and has been successfully applied to shipboard determination of trace orthophosphate in more than 200 seawater samples during a one-month cruise in the South China Sea. For seawater at concentrations of 20.6, 82.5, 206.2 nM orthophosphate, the relative standard deviations (RSD) (n = 6), determined daily for 6 days on board ship were 4.45%, 4.73% and 6.75%, respectively. Five seawater samples collected in the Station SEATS (South East Asia Time Series Station at 18°N, 116°E) were analyzed using the present method both on board and in a land-based laboratory, as well as with the magnesium hydroxide-induced coprecipitation (MAGIC) method, and showed no significant difference according to the statistical t-test.     

3S技术支持下的小型遗址提取方法

针对仅利用地物光谱分析方法不能识别某些小型遗址的现状,提出基于地物空间关系知识,多源信息复合提取遗址的思路获取目标信息。以安徽省巢湖柘皋地区为例,利用SPOT-5卫星影像和地形图数据,综合运用3S技术进行小型遗址信息提取研究。经过和巢湖文管部门普查记录对比,证明了该方法有效性。该方法可缩小遗址探查范围,为考古普查工作节约大量时间、人力和物力。     

灌注桩基础工程质量事故的处理

灌注桩基础是珠江三角洲地区工业与民用建筑广泛采用的基础形式之一,但由于各种原因,发生质量问题的灌注桩基础屡见不鲜.本文简明地介绍了灌注桩基础工程质量事故概况、灌注桩质量检测和评价方法以及灌注桩质量事故处理的常用方法.     

浅析如何在溶剂萃取机理研究中正确使用斜率法

斜率法是萃取机理研究最为常用的方法之一。尽管其理论基础和使用方法非常简单,但该方法却常常被误用,导致其非但不能有效的确定萃取机理,反而产生了误导性结论。本文以t-BAMBP萃取碱金属离子(K~+、Rb~+、Cs~+)体系为例讨论了常见的错误用法以及造成这类情况的根源问题,之后对其他萃取体系中类似错误用法进行了简要评述,表明斜率法的错误使用主要源于对萃取反应方程式的错误假定及对工作方程推导过程中引入的近似处理理解不当。最后总结了在萃取机理研究中正确使用斜率法的几点注意事项。     

The effect of terrain factors on rice production: A case study in Hunan Province

Journal of Geographical Sciences - Rice (Oryza sativa L.) is the most important staple crop of China, and its production is related to both natural condition and human activities. It is fundamental...     

Characterization of Turbot(Scophthalmus maximus) Skin and the Extracted Acid-Soluble Collagen

The biochemical composition of the turbot skin was investigated. The moisture level of the skin was found to be 51.4%. Based on dry matter content, there were relatively high protein(82.1%) and lipid(13.1%) concentrations in the turbot skin. Mineral element analysis revealed that the turbot skin had high Ca content(2069.0 mg kg^-1), and the concentrations of toxic heavy metals Hg and Pb were less than 0.005 mg kg^-1, which indicates that the turbot skin is a safe resource for collagen production. The sodium dodecyl sulfate-polyacrylamide gel electrophoresis(SDS-PAGE) analysis showed that acid-soluble collagen(ASC) extracted from the turbot skin was type-I collagen. The imino acid content of the ASC was 241.6 per 1000 amino acids, which suggests a relatively high denaturation temperature. The Fourier transform infrared(FTIR) spectra of ASC reflected a highly stable structure, and the measured denaturation temperature of ASC was 29.5℃, which is higher than those from many temperate fishes. ASC was the most soluble at pH 4.0, and when the pH values were below or above 4.0, the solubility decreased rapidly. The ASC exhibited a relatively high solubility when NaCl concentration was lower than 2%. These results show that turbo skin can be employed as a source for producing collagen with high quality.     

Farmer-based Rice Cropping Systems in the Poyang Lake Region,China: Analysis of Characteristics and Policy Implications

This paper examines the spatial characteristics of farmer/household behaviors in regional rice cropping systems (RCS), and the results provide necessary information for developing strategies that will maintain regional food security. Through field study and statistical analysis based on 402 households questionnaires finished in 2014-2015 in the Poyang Lake Region (PLR) of China, we arrived at two main conclusions. First, single- and double cropping rice were found across the study area, but showed a general distribution trend, with double cropping rice in the southeast part (especially in Jinxian county) and single cropping rice in the northwest (particularly in De’an county). Second, the household decisions concerning RCS varied in different parts of the PLR, but double cropping was the dominant type, with about 63.57% of the respondent households in the PLR cultivating double cropping rice. However, the multiple-cropping index of paddy rice was only 1.55. About 3% of interviewed households had altered their RCS during this period. Based on these findings, the local governments should guide farmers’ paddy field cultivation behaviors by increasing the comparative efficiency of rice production, promoting appropriate scale operations and land conversion, as well as optimizing rice growing conditions to improve the multiple cropping index and enhance food provision. Finally, land-use efficiency and more sustainable use of land resources should be improved.