3D behaviour of contamination in landfill sites using 2D resistivity/IP imaging: case studies in Portugal

Aiming at defining a valid spatial contamination model, resistivity and induced polarization (IP) measurements were used to investigate contamination plumes in the vicinity of two municipal landfills (Ovar and ílhavo). Previous geophysical surveys and underground water samples confirmed the contamination. However 2D resistivity/IP surveys enabled in obtaining a more accurate spatial model. The Ovar survey consisted of two profiles with nine Wenner soundings each; the ílhavo survey was carried out along two individual lines using a Wenner standard pseudo-section. In both situations, negative IP values were found associated with positive IP values, which can be explained mainly by 2D or 3D geometric effects caused by the presence of the conductive plumes. The data were modelled using a 2D inversion program (RES2DINV) and the resulting resistivity and chargeability distributions were displayed as pseudo-sections. The resistivity and chargeability pseudo-sections define the contamination plumes and the sedimentary structure. These case studies illustrate the advantages of 2D resistivity/IP surveys for the mapping of shape and dimension of contamination associated with landfills.     

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.     

大湾铀矿田铀-镭平衡系数及迁移富集特征研究

从分析大湾铀矿田各矿床(点)的铀镭平衡系数变化特征出发,结合放射性同位素比值特征分析铀镭迁移富集行为,指出了各矿床(点)氧化带的深度,以了解各铀矿床(点)潜在的工业价值.     

云南元-磨公路某高堑坡灾害发生机制及防治对策

论文根据现场地质调查,应用地质力学分析方法,分析了元-磨公路K235 160~600段高堑坡地质条件、病害发生机制和诱发因素。堑坡所在区域位于红河深大断裂与哀牢山深大断裂所夹持的哀牢山褶皱带内,属强烈侵蚀切割的低中山区,河流下切严重,河流阶地不发育。南溪河及其支流小曼萨河、叉河依附于不同时期生成的构造发育而成,堑坡位于小曼萨河注入南溪河的交汇部位小曼萨河的左岸。小曼萨河及南溪河所夹持的山体,尤其是堑坡所在的部位,已严重破碎、松弛,岩石似大块石堆垒状,坡面上的树木均明显地向小曼萨河方向倾倒。经地质力学配套分析,堑坡所依附的山梁形成于红河深大断裂生成期(γ4),堑坡岩体受多期构造活动的作用,其中NW65/°SW64°及NW63/°SW35°两组倾向临空的构造面控制坡体的稳定。堑坡具备发生变形破坏的地质条件,分析认为由于组成坡体的岩土强度不足而引起既有构造面的大型坍塌。连续降雨及温差是诱发因素。基于目前国内边坡防治技术、施工能力,提出了以“治”或“避”为主的防治对策。     

江苏省矿山的主要生态环境问题及治理对策

江苏的经济发展较快,对矿产资源的需求量亦大。多年来的无序开采,对生态环境造成很大的破坏和影响,出现了山体植被遭受破坏、土地被占用、环境受污染、诱发地面沉降、地面塌陷等一系列问题,已影响到国民经济的发展。随着省人大和省政府关于限制开山采石和保护环境等政策、法规出台和落实,近几年乱采滥挖现象基本得到了有效的遏制。人们的环保意识得到了加强,不少矿山已逐步开始对环境治理,且初见成效。文章介绍了江苏生态环境现状、存在的主要问题和治理对策,以期引起各级政府和广大民众在对矿产资源开采的同时更要注重环境保护。     

考虑滑脱效应和温度场的煤层气渗流数值模拟

由于煤层气的解吸热效应,煤层气的运移过程是一个非等温过程。因此,温度场对煤层气渗流有着重要的影响。前人在研究煤层气渗流规律的研究中并没有同时考虑滑脱效应和温度场因素的影响,而在实际的深部开采中综合考虑滑脱效应和温度场的影响对研究深部煤层气运移规律有着重要的意义。因此本文建立了考虑滑脱效应及温度场的煤层气渗流数学模型,利用有限元数值方法研究了考虑滑脱效应和温度场耦合的煤层气运移规律;研究了考虑滑脱效应和温度场对压力场分布的影响;对考虑滑脱效应及温度场因素的煤层气产量进行了预测。得出了随着温度的升高煤储层的压力在降低,温度的升高对煤层气的产量有着负面的影响这一重要结论。     

利用三维地震在戈壁沙漠区解决复杂地质构造问题

在分析戈壁沙漠地区地球物理特征的基础上，针对性的提出了解决煤田地质构造问题的方法，包括三维地震野外施工方法的选取、施工因素的选择、资料处理手段；并以获得的实际地质成果证实三维地震在解决复杂地质构造问题的可行性。     

Superdense CO2 inclusions in Cretaceous quartz–stibnite veins hosted in low-grade Variscan basement of the Western Carpathians, Slovakia

CO₂ inclusions with density up to 1,197 kg m⁻³ occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO₂ as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO₂ phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km⁻¹) and the CO₂–CH₄–N₂ fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover.     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.