Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

紫色土典型三角形层状剖面入渗模拟

通过室内特制的土壤水分入渗试验装置,分别设置上粗下细和上细下粗两种典型不同质地紫色土三角形层状剖面,探讨典型不规则层次结构的土壤入渗特性。结果显示,同一三角形层状剖面入渗,粗质土半剖面的垂直湿润锋随时间推进速度快于细质土。对于粗质土,上细下粗剖面设置下其半剖面的垂直湿润锋随时间推进速度快于上粗下细,但对于细质土,两种层状剖面设置下其垂直湿润锋随时间推进速度差异不明显。无论上粗下细,还是上细下粗,两种层状剖面对斜面湿润锋变化曲线影响不大。两种层状剖面入渗,湿润锋、入渗速率与时间均呈极显著幂函数关系。建立的紫色土典型三角形层状剖面入渗模型,经验证,模拟值与实测值具有非常好的一致性,且可与经验模型相互转换,模型参数也具有一定的物理意义。     

帕米尔东北缘地区构造变形特征与盆山结构

帕米尔东北缘乌泊尔地区是正确认识帕米尔北缘盆山结构和构造变形特征非常关键的地区,本文利用连续电磁剖面(CEMP)资料和地震资料,并结合野外地质调查资料和钻井资料,对帕米尔东北缘乌泊尔地区的盆山结构和构造变形特征进行了研究。认为帕米尔东北缘及其以北地区的盆山结构表现为帕米尔造山带向北冲断和南天山向南冲断所形成的对冲结构; 帕米尔山前为基底卷入式构造,古生界—中生界沿高角度的逆冲断层推覆到新近系和第四系之上,形成山前的古生界—中生界逆冲推覆带; 北侧由受乌泊尔断裂控制的深部隐伏冲断体系和浅部的第四纪背驮盆地所构成。研究区的新生代构造变形时间开始于上新世晚期,并持续变形至今,形成了下更新统西域组（Q1x）与下伏上新统、Q2与Q1和Q3 4与Q2之间的不整合。研究区最小构造缩短量为486 km,缩短率为481％。     

华北地区砂性土的卸荷回弹试验研究

超采深层地下水引起的地面沉降、地裂缝等灾害已经成为华北地区大中城市的主要地质灾害。本文以华北地区地下水开采漏斗边缘的砂性土为研究对象,通过反复加荷卸荷试验,分析了砂性土的卸荷回弹特征,阐述了砂土并不是完全弹性的,它同样存在一定的塑性特征,并且说明了砂土的回弹量的大小是个变量,其回弹能力随着反复回弹次数、回弹应力大小及哪一应力进行回弹而变化。该研究结果对治理开采深层地下水引起的地面沉降等灾害有重要意义。     

Hydrous pyrolysis of a Type III source: fractionation effects during primary migration in natural and artificially matured samples

A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores.     

北京地区遥感环形构造信息提取与金矿预测

解译了北京地区航片上的环形构造，对环形构造解译图进行了数字化处理，运用数理统计方法分析了环形构造的空间分布特征及其与金矿化作用的关系，最后得到了环形构造密度异常与金矿分布之间具有正相关关系等新认识。     

典型高光谱图像端元提取算法在黄河口湿地应用评价研究

端元提取是混合像元分解的基础,也是高光谱遥感的研究热点。对于特定区域的高光谱图像应该使用哪种端元提取算法,需要对各种端元提取算法进行客观地评价。作者针对黄河口湿地CHRIS高光谱图像,使用了重建图像与原图像的均方根误差、有效端元数量两个指数对PPI、N-FINDR、VCA、OSP、IEA和SISAL六种典型的端元提取算法进行了评价。结果表明,SISAL算法重建误差最小,仅有其他算法误差的10%~28%;OSP算法识别了具有物理意义的6种有效端元,多于其他算法识别的地物类型,而SISAL算法识别的端元缺乏物理意义。     

Impact of mega-scale sand extraction on tidal dynamics in semi-enclosed basins: An idealized model study with application to the Southern North Sea

Long-term considerations of repeated and increasing sand extraction on the Netherlands Continental Shelf (North Sea) may lead to the creation of a mega-scale extraction trench in front of the Dutch coast (length hundreds of km, width over 10 km, depth several m). We investigate the impact of such a huge topographic intervention on tidal dynamics, which is a key aspect in hydrodynamics, and indirectly also affecting morphodynamics and ecology.     

番红砗磲外套膜色素提取条件优化及成分分析

以番红砗磲(Tridacna crocea)为实验对象,通过单因素对比实验对其外套膜色素的提取条件进行了优化,并利用薄层层析色谱法对色素组成进行了初步分析。结果表明:丙酮和乙醇为适宜的番红砗磲外套膜色素提取剂;使用丙酮为提取剂时,浸提时间为4 h,提取温度为25℃,料液比为1︰40。使用乙醇为提取剂时,浸提时间为4 h,提取温度为30℃,料液比为1︰200;利用薄层色谱法分离外套膜颜色为蓝色和红棕色的番红砗磲外套膜色素后发现,蓝色番红砗磲外套膜色素由9种色素组分构成,红棕色个体番红砗磲外套膜色素由10种色素组分构成。