求解GM(1,1)模型新总体最小二乘算法

在GM(1,1)模型中系数矩阵和观测向量都是由原始序列组成的。系数矩阵中同样是有误差的,与观测向量中的误差一样,亦来源于原始序列,即它们误差同源。不同位置的相同元素应该有相同的改正数,采用传统总体最小二乘求解则不能达到此目的。针对这一缺陷,推导了一种新的总体最小二乘算法;并且通过算例验证了新方法的可行性和有效性。     

基于混合罚函数法的多尺度电离层层析确权方法

在利用GNSS进行像素基电离层层析时,多尺度层析方法利用权重因子将反演区域不同像素层析模型结合在一起,最终得到电离层电子密度反演结果,可以有效地解决电离层层析过程中不适应问题和最终的电离层电子密度失真现象。在多尺度电离层层析中,不同像素尺度层析模型之间权重是影响最终的电离层电子密度精度的重要因素。为了获得高精度电离层层析模型,考虑到权重因子存在着等式和不等式限制条件,采用解决最优化问题的罚函数法确定不同像素尺度电离层层析模型之间的权重。通过采用实测GNSS观测数据进行电离层多尺度电离层层析,对比了多尺度层析模型的各个子模型建模精度并进行分析,同时将罚函数法获得的模型精度与其他确权方法进行了对比,该方法可以有效地应用于多尺电离层度层析,且最终的层析模型精度优于其他确权方法,更优于单尺度电离层层析模型精度。     

抗差估计的多波束测深数据内插方法

针对传统多波束测深数据网格化内插方法抗差性不足的问题,该文将抗差估计理论应用于网格化内插方法中。基于不确定度指标建立了距离不确定度联合加权内插模型,在该模型的权函数中引入了等价权,同时给出了等价权设计方案及迭代初值确定原则,以增强模型的抗差性;介绍了一种节点邻域参考点合理选取方法,给出了改进内插法实现的基本步骤,最后通过实测数据对反距离加权法、联合加权法及改进方法内插水深质量进行比较。结果表明,改进方法内插结果要优于另外两种方法,可应用于多波束测深数据网格化处理中。     

加权Logistic回归模型在火山岩型铜矿预测中的应用:以宁芜盆地中段为例

文中探讨了加权Logistic回归模型在宁芜盆地中段火山岩型铜矿预测中的应用。首先,结合研究区的成矿地质背景,提取地质体、构造、围岩蚀变三大类证据因子;其次,分析各证据因子与铜矿点之间的空间关系,认为姑山旋回、娘娘山旋回火山机构控制了本区火山岩型铜矿的空间分布,根据计算结果,选取与火山岩型铜矿密切相关的龙王山组、姑山组地层,姑山旋回粗面斑岩、娘娘山旋回二长斑岩、NW向构造1.5 km缓冲区、NE向构造1.3 km缓冲区、EW向构造4.5 km缓冲区、硅化、褐铁矿化、黄铜矿化等作为模型自变量;最后采用加权Logistic回归模型进行成矿概率计算,并结合成矿地质背景,圈定四个成矿远景区,分别为P1、P2、P3、P4,其中P1、P2、P3呈北东向展布,主要受娘娘山和姑山火山机构控制,P4为东西向分布,主要受龙王山火山机构控制,在这些预测区中,均存在已发现的铜矿体,说明预测可信度较高。     

西菲律宾海2万年以来浮游有孔虫壳体重量变化

为探讨2万年以来浮游有孔虫的壳体重量变化及其影响因素,对取自西菲律宾海MD06-3052岩芯的浮游有孔虫表层种Globigerinoides ruber进行壳体重量分析,基于氧同位素年龄模式,获得了2万年以来有孔虫传统壳体重量(WMS)和标准化壳体重量(WSN)变化特征。对比两种壳体重量指标,发现在本海区标准化壳体重量指标更为准确。结果表明,2万年以来,浮游有孔虫WSN具有不断变轻的趋势,整体表现为冰期时壳体重量较重,而全新世时壳体重量相对较轻的特征。末次冰盛期(Last Glacial Maximum,LGM)以来浮游有孔虫WSN变化曲线同大气CO2浓度变化曲线具有较好的相似性,推测在该海区控制壳体重量的主要因素为与全球大气CO2相关的表层海水的CO32–浓度。     

A new assessment model for evacuation vulnerability in urban areas

In the high-speed urbanization process of China, the urban population has been increasing significantly, leading to a high-density aggregation of population. However, the sharp increase in population density has not produced commensurate improvements in the road networks. On the contrary, the population increase induced a serious evacuation vulnerability, which cities experience during various hazards and catastrophic events. Therefore, research on evacuation vulnerability is important to urban planning. To assess the evacuation vulnerability, the optimal and worst scenarios should be considered because all possible evacuation plans occur between these extremes. However, most previous evacuation vulnerability studies are based on the worst-case scenario, only providing an upper bound of a potential evacuation assessment. To provide a more comprehensive theoretical basis for decision-makers to understand the consequences caused by all possible evacuations, this paper proposes an optimal evacuation vulnerability assessment model that provides the lower bound on potential evacuation difficulties. The model is solved by a stepwise spreading algorithm based on Graph Theory. Subsequently, to evaluate the effectiveness of the model, the study adopts the model to assess the evacuation capability of different road network topologies. A comparison with previous research was performed. The model was demonstrated in an application to the South Luogu Alley of Beijing, China. The significance of this paper is that the combination of our model with previous research may provide a more complete theoretical basis for an evacuation vulnerability assessment.     

Diagnosis of earth-fill dams by synthesised approach of sounding and surface wave method

The spatial distribution of the strength inside the earth-fill is identified by the sounding tests. In this research, the Swedish weight sounding (SWS) is employed, and the spatial high-density test is performed to identify the spatial correlation structure. Furthermore, the synthesised approach of the SWS and surface wave method, which is one of the geophysical method, is proposed to compensate the shortage of each approach. Consequently, the correlation structure of an earth-fill could be identified accurately, and the high resolution of the spatial distribution could be visualised based on the survey results.     

三峡库岸滑坡变形特征及影响因素分析

三峡库区涉水滑坡主要影响因素是水位和降雨量,也是库区滑坡体失稳的主要影响因素和诱发因素。库区每年重复着水位升降不利于滑坡的稳定,而降雨特别是大强度的降雨也诱发产生滑坡。当水位波动遇到降雨,出现工况叠加,滑坡将加剧。因此,有必要对影响滑坡变形的主导因素进行了解分析。2016年6月三峡库区全面展开了自动化监测,使得数据统计方便可靠。本文采用滑坡变形速率、降雨量、库水位变化、最大水位变化速率、淹没程度,运用灰色关联度分析法对涉水滑坡进行了计算分析。水位下降阶段,文中土质滑坡变形受库水位影响最大。水位上升阶段,该土质滑坡上部变形受降雨影响最大,下部受水位影响最大。文中岩质滑坡总是受库水位影响最大。     

A New Reference Material for Tritium Organic Molecules in Sediment: Results of an International Intercomparison Exercise

Solid matrix ³H reference materials are challenging to prepare given the volatile nature of ³H and are often unrepresentative of the range of ³H forms that may be encountered during routine analysis. As a result, few ³H reference materials are currently available, undermining verification of analytical techniques for environmental ³H measurement. To address this, an International Working Group on Organically‐Bound Tritium Analysis determined to produce a tritium natural matrix reference material (NMRM). The reference material comprises marine sediment blended with sewage sludge contaminated with ³H‐organic species arising from authorised discharges from a radiopharmaceutical manufacturing site. Previous studies have demonstrated that the ³H species have persisted in the environment over three decades providing valuable supporting data to underpin the characterisation of the NMRM. The preparation and characterisation of the NMRM are described along with the subsequent application of the reference material in an international intercomparison exercise involving nineteen laboratories from nine countries. A reference value of 168 ± 22 Bq kg^?1 was derived from the data arising from the proficiency test.     

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。