Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl2[AlSi3O10](OH,F)2 series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H3BO3 contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B2O3, 3.64–5.20 wt.% Cs2O, 0.54 wt.% Li2O, 0.57 wt.% Ta2O5, 0.10 wt.% Nb2O5, 0.12 wt.% BeO. The H2O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H2O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.
Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H2O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets. 相似文献
The Strona-Ceneri Zone comprises a succession of polymetamorphic, pre-Alpidic basement rocks including ortho- and paragneisses,
metasedimentary schists, amphibolites, and eclogites. The rock pile represents a Late Proterozoic or Palaeozoic subduction
accretion complex that was intruded by Ordovician granitoids. Eclogites, which occur as lenses within the ortho-paragneiss
succession and as xenoliths within the granitoids record a subduction related high-pressure event (D1) with peak metamorphic
conditions of 710 ± 30 °C at 21.0 ± 2.5 kbar. After isothermal uplift, the eclogites experienced a Barrowtype (D2) tectonometamorphic
overprint under amphibolite facies conditions (570-630 °C, 7-9 kbar). U-Pb dating on zircon of the eclogites gives a metamorphic
age of 457 ± 5 Ma, and syn-eclogite facies rutile gives a 206Pb/238U age of 443 ± 19 Ma classifying the subduction as a Caledonian event. These data show that the main tectonometamorphic evolution
of the Strona-Ceneri Zone most probably took place in a convergent margin scenario, in which accretion, eclogitization of
MOR-basalt, polyphase (D1 and D2) deformation, anatexis and magmatism all occurred during the Ordovician. Caledonian high-pressure
metamorphism, subsequent magmatism and Barrow-type metamorphism are believed to be related to subduction and collision within
the northern margin of Gondwana.
Editorial handling: Edwin Gnos 相似文献
A high slope is located on the side of the spillway at a hydropower station in Southwest China, which has some weak inter-layers inclining outwards. Parts of the slope show heavy weathering and unloading. There appeared deformation and tensile crack either on the surface or on the afteredge of the slope during excavation, and under a platform (elev. 488 m), two levels of slopes collapsed on the downriver side. Based on the investigation in situ and the analysis of the geological structure, the conceptual model of deformation and failure mechanism was erected for this slope. Furthermore, the deformation characteristics were studied with FLAC^3D numerical simulation. Comprehensive analysis shows that the whole deformation of the slope is unloading rebound in certain depth scope and the whole body does not slide along any weak interlayer. In addition, two parts with prominent local deformation in the shallow layer of the slope show the models of "creep sfiding-tensile cracking" and "slidlng-tensile cracking", respectively. Based on the above analysis, the corresponding project of support and reinforcement is proposed to make the slope more stable. 相似文献