重要找矿指示元素的野外快速分析法——金的野外快速分析

近年来,作者发展了七种以上重要找矿指示元素的野外快速分析法,此乃其一。文中提出一种新的金样冷浸技术,引进了新的光导光度检测方法,样品经溴化钠—硫酸—过氧化氢冷浸,用经丙酮—MIBK处理的泡沫塑料富集金,经混合解脱剂解脱并直接取解脱液用改进的微珠析出法或用光导光度法测定。取10g样品,可测定0.0005-50g/t范围内的金。方法简便、快速,可在普查分队驻地进行,每一工作日可测定80多个样品,由于废弃了王水分解样品和泡沫塑料的灰化,具有广阔的应用前景。     

南海海盆区莫霍面分布规律及其对深部钻探的意义

钻遇莫霍面是人类一直以来的梦想。深海海底是地球上离莫霍面最近的地方，目前有研究推测南海是世界上莫霍面深度最浅的海域之一，但缺乏足够的直接证据。深反射地震探测可以直接揭示岩石圈的构造形态，是莫霍面探测的重要手段。本文基于长达15000 km的深反射多道地震剖面的解释、处理、制图和分析，结合前人的研究，形成了南海海盆区莫霍面反射特征和空间分布的初步认识。① 南海东部次海盆南部早期经历了较快速扩张，岩浆供应充足，受扩张停止后岩浆活动影响较小，基底平坦，地质构造相对简单，同时洋壳地震速度结构不存在异常，且有较强的广角莫霍面反射波和可识别的地幔顶部折射波，具备莫霍面钻探的基本条件。② 南海海盆不同区域的莫霍面反射强度存在较大差异。其中东部次海盆莫霍面反射最为强烈且清晰，西北次海盆次之，西南次海盆仅有零星出现的清晰莫霍面反射且可信度不高。③ 识别南海海盆区莫霍面地震反射长度超过3500 km，首次形成了海盆区深度域莫霍面地震反射空间分布图。与重力反演的莫霍面深度相比，利用深反射多道地震计算的莫霍面深度细节更为丰富，并且可以在垂向上清晰刻画莫霍面的结构。整体上，南海海盆区莫霍面地震反射强烈和可信度高的区域中，深度较浅的区域之一是东部次海盆南部，最浅处仅约9. 5 km，其中水深4. 01 km，洋壳厚度仅5. 54 km。综合判断，东部次海盆南部是南海重要的莫霍面钻探备选区，这对南海莫霍面钻探选址具有重要意义。     

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.     

Lermontovskoe Tungsten Skarn Deposit: the Oldest Mineralization in the Sikhote-Alin Orogen, Far East Russia

Abstract. Lermontovskoe tungsten skarn deposit in central Sikhote-Alin is concluded to have formed at 132 Ma in the Early Cretaceous, based on K-Ar age data for muscovite concentrates from high-grade scheelite ore and greisenized granite. Late Paleozoic limestone in Jurassic - early Early Cretaceous accretionary complexes was replaced during hydrothermal activity related to the Lermontovskoe granodiorite stock of reduced type. The ores, characterized by Mo-poor scheelite and Fe^3+- poor mineral assemblages, indicate that this deposit is a reduced-type tungsten skarn (Sato, 1980, 1982), in accordance with the reduced nature of the granodiorite stock.
The Lermontovskoe deposit, the oldest mineralization so far known in the Sikhote-Alin orogen, formed in the initial stage of Early Cretaceous felsic magmatism. The magmatism began shortly after the accretionary tectonics ceased, suggesting an abrupt change of subduction system. Style of the Early Cretaceous magmatism and mineralization is significantly different between central Sikhote-Alin and Northeast Japan; reduced-type and oxidized-type, respectively. The different styles may reflect different tectonic environments; compressional and extensional, respectively. These two areas, which were closer together before the opening of the Japan Sea in the Miocene, may have been juxtaposed under a transpressional tectonic regime after the magmatism.     

新疆绿色电气石颜色成因研究

新疆绿色电气石颜色成因比较特殊,为了更好地了解其颜色的形成,主要采用化学分析、吸收光谱、穆斯堡尔谱等测试手段对绿色电气石颜色成因进行研究。化学分析结果显示每个样品中均含有少量不同过渡元素离子,如Fe2 、Ti4 、Cr3 等,影响着绿色的形成;利用吸收光谱测试方法确定了致色离子的吸收带位置及主要离子的种类、价态,并根据化学成分计算出相应的化学式,利用穆斯堡尔谱确定了铁离子在晶体中的占位。综合运用上述测试方法,确定了绿色电气石的颜色成因。     

中国大陆科学钻探主孔声发射法现今地应力状态的确定

对中国大陆科学钻探主孔的岩心进行了声发射测量,确定了301～1531m深度的最大主应力。并与钻孔崩落法(深度1269～1655m)测量结果进行了对比,结果表明,声发射测量所得测值基本上落在钻孔崩落法测值的趋势线上,两种方法所得结果一致,说明测量结果可信。测量结果表明科学钻探主孔地应力大小随深度增加,在浅部301m最大主应力为13.4MPa,在深部1655m为55.2MPa。随深度的增加率为0.0279MPa/m。最大主应力方向为N54°±3.3°E,且方向不随深度变化。     

大气热力学的若干新发展

对自20世纪80年代以来的大气热力学发展进行了综合评述, 阐述了如城市热岛效应、全球增暖等非传统大气热力学问题; 基于大气非平衡态热力学的非线性理论, 提出应发展突显热力学作用的数值模式, 并阐述其必要性和可能性。