O-羧甲基壳聚糖的制备及其结构表征

本文以壳聚糖为原料,采用苯甲醛选择性的保护壳聚糖C2位氨基的方法,制备了O-羧甲基壳聚糖(O-CMC)。采用红外光谱及核磁共振波谱法对产物结构进行了表征,确定了羧甲基化反应只发生在壳聚糖的O位。该方法制备得到的O-CMC的羧甲基度为42.2%,反应选择性好,步骤简单,产率高达85%。     

粤北地热资源遥感调查探测模式与应用

目前,地热资源勘查仍以传统的物探方法为主,这样在探测区地热宏观环境条件不明时,就会出现投资风险大或盲目开采的情况;而遥感对地热资源的探测是弥补这一不足的先进技术.本文利用陆地卫星遥感数据处理方法进行了有效的遥感地质解译,依据陆地卫星红外遥感数据所反映的地物辐射温度差异特点,对遥感影像进行波段差值运算、HIS(HLS)彩...     

Deriving Temporal and Vertical Distributions of Methane in Xianghe Using Ground-based Fourier Transform Infrared and Gas-analyzer Measurements

Methane(CH4) is one of the most important greenhouse gases in the atmosphere, making it worthwhile to study its temporal and vertical distributions in source areas, e.g., North China. For this purpose, a ground-based high-resolution Fourier transform infrared spectrometer(FTIR), the Bruker IFS 125 HR, along with an in-situ instrument, the Picarro G2301, were deployed in Xianghe County(39.8°N,117.0°E), Hebei Province, China. Data have been recorded since June2018. For the FTIR measurements, we used two observation modes to retrieve the mole fraction of CH4: the Total Carbon Column Observing Network(TCCON) method(retrieval algorithm: GGG2014), and the Network for the Detection of Atmospheric Composition Change(NDACC) method(retrieval algorithm: SFIT4). Combining FTIR with in-situ measurements, we found the temporal and vertical distributions of atmospheric CH4 within three vertical layers(near the ground, in the troposphere, and in the stratosphere), and throughout the whole atmosphere. Regarding the diurnal variation of CH4 near the ground, the concentration at night was higher than during the daytime. Regarding the seasonal variation,CH4 was low in spring and high in summer, for all three vertical layers. In addition, there was a peak of CH4 in winter near the ground, both in the troposphere and the whole atmosphere. We found that variation of CH4 in the tropospheric column was close to that of the in-situ measurements near the ground. Furthermore, the variations of CH4 in the stratospheric column could be influenced by vertical motions, since it was higher in summer and lower in winter.     

A survey of molecular hydrogen in the central galaxies of cooling flows

We present a large sample of H - and K -band spectra of 32 optically line-luminous central cluster galaxies. We find significant rovibrational H₂ emission in 23 of these galaxies as well as H recombination and/or [Fe  ii ] emission in another five. This represents a fourfold increase in the number of molecular line detections known. A number of the detections are of extended emission (5–20 kpc). In several objects we find significant [Si  vi ] emission that appears to correlate with the strength of high ionization lines in the optical (e.g. [O  iii ]). This comprehensive sample builds on previous work and confirms that warm (1000–2500 K) molecular hydrogen is present wherever there is ionized material in the cores of cooling flows and in most cases it also coincides with CO molecular line emission.     

Building Blocks of the most Luminous Galaxies

Nearby luminous galaxies serve as templates to gain insight into the building blocks of the most luminous galaxies in the distant universe. In this conference I have shown that the most luminous galaxies in the Local Universe are mergers of evolved gas-rich galaxies that radiate the bulk of their energy in the mid and far-infrared. The most important implication for future studies on the formation of galaxies at early cosmological timescales is that they will appear as luminous sub-millimeter sources. This revised version was published online in September 2006 with corrections to the Cover Date.