Determination of High Field Strength Elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g−1 Levels in Geological Reference Materials by Magnetic Sector ICP-MS after HF/HClO4 High Pressure Digestion

Six low abundance rock reference materials (basalt BIR-1, dunite DTS-1, dolerite DNC-1, peridotite PCC-1, serpentine UB-N and basalt TAFAHI) have been analysed for high field strength elements (Zr, Nb, Hf, Ta, Th and U), Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels (in rock) by magnetic sector inductively coupled plasma-mass spectrometry after HF/HClO₄ high pressure decomposition. The adopted method uses only indium as an internal standard. Detection limits were found to be in the range of 0.08 to 16.2 pg ml⁻¹ in solution (equivalent to 0.08 to 16.2 ng g⁻¹ in rock). Our data for high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi for the six selected low abundance geological reference materials show general agreement with previously published data. Our Ta values in DTS-1 and PCC-1 (1.3 and 0.5 ng g⁻¹) are lower than in previously published studies, providing smooth primitive mantle distribution patterns. Lower values were also found for Tl in BIR-1, DTS-1 and PCC-1 (2, 0.4 and 0.8 ng g⁻¹). Compared with quadrupole ICP-MS studies, the proposed magnetic sector ICP-MS method can generally provide better detection limits, so that the measurement of high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels can be achieved without pre-concentration, ion exchange separation or other specialised techniques.     

历史传承与现代化的对接——北京城市建设新风貌

北京城市建设日新月异,以惊人的速度、超常的规模,黍列国际大都会行列。但800年古都、风韵犹存;本文论述对东西长安街和南北中轴线空间布局的棋盘格局;地铁选线与设计的乡土特色,古树名木的历史见证与城市记忆,为读者解读北京城市建设现代化过程中,体现历史文化传承潜规则的精彩与和谐。     

基于循环神经网络的重力异常数据推估研究

利用鄂尔多斯西南缘的重力观测数据对长短期记忆循环神经网络(long short-term memory,LSTM)进行训练,结果表明,该神经网络可基于有限的数据获取较好的推估结果.基于自由空气重力异常数据,对比分析长短期记忆循环神经网络和传统克里金方法的推估结果发现,神经网络的推估能力优于传统克里金方法,但运算效率低于...     

自动电位滴定仪应用于测定海洋沉积物中有机碳的可行性研究

自动电位滴定仪具有操作简便、测定速度快的优势,减少了人为操作的影响,本文使用自动电位滴定仪测定海洋沉积物中有机碳的含量,并与国家标准(GB 17378.5—2007)中根据滴定过程中溶液颜色变化用肉眼判定滴定终点的方法进行了对比分析,确定通过仪器自动判断滴定终点实现准确测定的可行性。结果表明:自动电位滴定的方法检出限为0.029%,人工肉眼判定终点的方法检出限为0.086%,在滴定终点判定方面两种方法无显著性差异,但自动电位滴定仪的准确度和精密度更优,在一定程度上可代替肉眼判定滴定终点。实际应用过程中也发现,当滴定的溶液体系由于氧化还原反应、络合作用等影响因素使电位变化较为复杂时,自动电位滴定仪有可能会得到多个等当点而无法判断哪个等当点是真正的目标等当点,此时需要利用肉眼进行辅助确定。     

基于多变量LSTM神经网络的地下水水位预测

为解决以往模型未考虑地下水位相关影响因素的问题,探讨长短期记忆（LSTM）神经网络在地下水位预测中的应用,利用长短期记忆神经网络,采用多变量输入的方式,构建了基于多变量LSTM神经网络的地下水水位预测模型。以泰安市岱岳区J1号监测井为例,采用2001-2014年地下水水位动态监测资料与相关影响因素数据,利用多变量LSTM神经网络对2015-2016年地下水位进行预测,并与单变量LSTM神经网络和反向传播（BP）神经网络进行对比。研究结果表明：以相关影响变量为输入的BP神经网络无法考虑时序变化规律,预测均方根误差最大,为2.399 3;以地下水位为变量输入的单变量LSTM神经网络仅能根据时序变化作出相应预测,无法考虑相关变量影响,预测均方根误差为2.102 2;基于多变量输入的LSTM神经网络的预测精度显著高于单变量LSTM神经网络和BP神经网络,预测均方根误差最小,仅为1.919 1。总体上,多变量LSTM神经网络地下水位预测模型仅在某些峰值处误差较大,但总体预测效果较为理想。     

基于百度地图的精细化格点预报显示

精细化格点要素预报是目前中国气象局的主推业务和未来天气预报的发展方向,如何有效地将预报产品提供给用户使用,是精细化格点预报的最终环节。本文介绍了基于百度地图API的陕西精细化格点预报显示系统,系统主要实现了:(1)降水预报,以CMORPH(NOAA Climate Prediction Center Morphing Method)卫星与全国3万个自动观测站的逐时降水量融合资料为基础,通过动态偏差订正的方法来提高格点降水的预报能力;温度预报,采用滑动线性回归的方法来改善温度预报效果。(2)任意位置的地理信息获取及对应格点240h预报时效的气象要素实时展示。(3)格点气象要素向站点转换,通过格点值提取全省98个观测站逐3h站点预报值,实时分析过去24h降水、温度预报与观测值的误差,供用户预判未来预报值的可能误差趋势;并提供未来168h逐日要素预报。(4)与以往的数据库后台支撑不同,本系统直接将3.5GB格点预报数据一次性读入内存,进行侦听,解决了数据库检索、调用效率低下的问题。     

Influence of land use on the persistence effect of riverine phosphorus

The persistence effect contribution of legacy nutrients is often cited as a reason for little or no improvement in water quality following extensive implementation of watershed nutrient mitigation actions, yet there is limited knowledge concerning factors influencing this response, often called the “persistence effect.” Here, we adopted detrended fluctuation analysis and Spearman analysis methods to assess the influence of land use on the watershed phosphorus (P) persistence effect, using monthly water quality records during 2010–2016 in 13 catchments within a drinking water reservoir watershed in eastern China. Detrended fluctuation analysis was used to calculate the Hurst exponent α to assess watershed legacy P characteristics (α  ≈ 0.5, α  > 0.5, and α  < 0.5 indicate white noise, persistence, and anti‐persistence, respectively). Results showed weak to strong P persistence (0.60–0.81) in the time series of riverine P in the 13 catchments. The Hurst exponent α had negative relationships with agricultural land (R = ?.47, p = .11) and developed land (R = ?.67, p = .01) and a positive relationship with forest land cover (R = .48, p = .10). The persistence effect of riverine P was mainly determined by retention ability (biogeochemical legacy) and migration efficiency (hydrological legacy). A catchment with strong retention capacity (e.g., biomass uptake/storage and soil PO₄ sorption) and low migration efficiency results in a stronger persistence effect for riverine P. In practice, source control is more effective in catchments with weak persistence, whereas sink control (e.g., riparian buffers and wetlands) is preferred in catchments with strong persistence effects.     

The effect of El Niño Southern Oscillation cycles on the decadal scale suspended sediment behavior of a coastal dry‐summer subtropical catchment

Rivers display temporal dependence in suspended sediment–water discharge relationships. Although most work has focused on multi‐decadal trends, river sediment behavior often displays sub‐decadal scale fluctuations that have received little attention. The objectives of this study were to identify inter‐annual to decadal scale fluctuations in the suspended sediment–discharge relationship of a dry‐summer subtropical river, infer the mechanisms behind these fluctuations, and examine the role of El Niño Southern Oscillation climate cycles. The Salinas River (California) is a moderate sized (11 000 km²), coastal dry‐summer subtropical catchment with a mean discharge (Q_mean) of 11.6 m³ s^?1. This watershed is located at the northern most extent of the Pacific coastal North America region that experiences increased storm frequency during El Niño years. Event to inter‐annual scale suspended sediment behavior in this system was known to be influenced by antecedent hydrologic conditions, whereby previous hydrologic activity regulates the suspended sediment concentration–water discharge relationship. Fine and sand suspended sediment in the lower Salinas River exhibited persistent, decadal scale periods of positive and negative discharge corrected concentrations. The decadal scale variability in suspended sediment behavior was influenced by inter‐annual to decadal scale fluctuations in hydrologic characteristics, including: elapsed time since small (~0.1 × Q_mean), and moderate (~10 × Q_mean) threshold discharge values, the number of preceding days that low/no flow occurred, and annual water yield. El Niño climatic activity was found to have little effect on decadal‐scale fluctuations in the fine suspended sediment–discharge relationship due to low or no effect on the frequency of moderate to low discharge magnitudes, annual precipitation, and water yield. However, sand concentrations generally increased in El Niño years due to the increased frequency of moderate to high magnitude discharge events, which generally increase sand supply. Copyright © 2014 John Wiley & Sons, Ltd.     

温敏堵漏水泥浆体系研究与应用

温敏形状记忆聚合物是形状记忆材料的一种,其结构中存在记忆起始形状的固定相和随温度变化能可逆地固化和软化的可逆相。本文将这种材料性能应用于石油工程的固井领域,利用温敏聚合物温敏形变的特点,在井下温度升高时激发粒子形变形成大形变体,为封堵漏失层提供架桥结构,解决固井水泥浆防漏堵漏效果差、水泥车不能泵送较大尺寸颗粒的难题。研制的温敏堵漏材料初始粒径1 mm,达到温敏点后体积形变膨胀,应用温度60~140 ℃,加量0~2% BWOC;据此构建的温敏堵漏水泥浆体系,能有效封堵2 mm的缝隙板,承压7 MPa。温敏堵漏水泥浆先后在东北分公司北209井、北8井、北213-1井等的尾管或油层固井中进行了现场应用,尤其在北213-1井的固井堵漏过程中有效解决了固井漏失难题。     

基于集体记忆的红色旅游地地方性建构

红色历史的集体记忆嵌入动态的地方建构和空间生产过程,成为地方性重构的有力素材。文章以云南省宾川县新庄红军村为例,通过参与式观察和访谈文本分析等质性方法,从地方性景观与话语的再建构,以及地方性情境创设的空间实践,探讨新庄村的地方性建构机制。研究发现：具体的地方要素在地方-记忆的互动关系中起中介承启作用。地方要素既促进红色旅游情境下记忆的唤起、存储与再创造,又对集体记忆重新建构的地方特质、意义与场所精神进行地方性元素表达。旅游情境创设与地方性展演使集体记忆不断得到投影、表达与重构,推动差异化的地方叙述与体验。