太湖入湖河口和开敞区CDOM吸收和三维荧光特征

应用吸收和三维荧光光谱对2007年夏季太湖入湖河口和大太湖开敞区有色可溶性有机物(CDOM)浓度及来源进行研究.结果表明,河口区和开敞区CDOM吸收系数a(355)存在显著空间差异,河口区明显大于开敞(ANOVA,P<0.001),a(355)最大值出现在大浦河口和竺山湾漕桥河几附近,最小值出现在东太湖和胥口湾.a(355)与溶解性有机碳、化学耗氧量浓度存在显著正相关.所有样品一般都含有4个明显的荧光峰,包括1个可见光区的类腐殖质荧光C峰,1个紫外光区的类腐殖酸荧光A峰,2个类蛋白荧光B峰和D峰.河口区外源输入的类腐殖质荧光非常强,最著大于开敞区(ANOVA,P<0.05).而河口区和开敞区类蛋白荧光没有显著性差异,反映开敞区除外源河流输入外,内源生物降解等对类蛋白荧光贡献增加.在河口区B、C峰的比值r(B/C)/b于1,均值为0.62±0.14、在开敞区r(B/C)除12#是0.92,其他值均大于1,均值为1.12±0.13,初步判断r(B/C)可以作为区分CDOM来源的重要参数.CDOM吸收a(355)与类腐殖质荧光C峰、A峰均存在极显著的正相关,而与类蛋白荧光相关性则明显下降,与D峰存在显著正相关,与B峰没有显著相关.     

奥运气象服务社会经济效益评估的AHP/BCG组合分析

综合应用层次分析法(AHP方法)和波士顿矩阵(BCG矩阵)相结合的思路,将气象服务用户群对服务效益评估这个复杂系统的思维过程数学化、系统化,建立了定量的气象服务期望度/满意度组合矩阵分析模型.以2007年"好运北京"青岛国际帆船赛调查问卷为例进行实证分析,从用户反馈信息来考核对用户需求的了解和满足、气象服务时间和时效、气象服务宣传服务手段、服务人员综合能力、预报准确度和用户未来意向等6个主要项目,应用该模型来较为客观地评估奥运气象信息服务当前的四象限结构现状,掌握和判断其所处位置,发现问题进行改进,并预测该项目的未来发展变化.     

铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).     

关键金属元素分析测试技术方法应用进展

以稀有、稀散、稀土、铂族元素为主体的战略性关键金属矿产资源,在新材料、新能源和信息技术等新兴产业中发挥着越来越关键的作用。随着我国关键矿产资源地质调查的不断深入,关键金属元素以其赋存基体复杂、不同矿物含量差异大、化学性质不稳定等特点对分析测试技术提出了新的挑战。本文根据化学组成不同,对关键金属元素主要赋存基体进行了分类,主要分为硅酸盐、碳酸盐、硫酸盐、钨酸盐、磷酸盐、氧化物、硫化物、卤化物等。对于不同的基体岩石矿物,通常采用酸溶法(硝酸-氢氟酸组合、王水)或碱熔法等传统溶样方法进行化学消解。评述了当前关键金属元素测试常用的电子探针、电感耦合等离子体质谱、电感耦合等离子体发射光谱、X射线荧光光谱等仪器的特点及应用,总结了关键金属元素分析过程中出现的样品难溶解、回收率不完全、测试过程氧化物和同质异位素干扰、样品和标准基体不一致等常见问题,并提出了相应的解决方案。微区原位分析凭借其高效率、低成本、高空间分辨率的优势,以及野外现场分析凭借其简单快速、贴近野外工作的特点是关键金属元素测试技术发展的主要趋势。     

Origin and source regions of PM10 in the Eastern Mediterranean atmosphere

A set of daily PM₁₀ (n = 281) samples collected from April 2001 to April 2002 at a rural site (Erdemli), located on the coast of the Eastern Mediterranean, were analyzed applying Mass Closure (MC), absolute principal factor analysis (APFA) and Positive Matrix Factorization (PMF) to determine source contributions. The results from the three techniques were compared to identify the similarities and differences in the sources and source contributions. Source apportionment analysis indicated that PM₁₀ were mainly originated from natural sources (sea salt + crustal ≈ 60%) whilst secondary aerosols and residual oil burning accounted for approximately 20% and 10% of the total PM₁₀ mass, respectively. Calculations for sulfate showed that on average 8% and 12% of its total concentration were originated from sea salt and biogenic emissions, respectively. However, the contribution by biogenic emissions may reach up to a maximum of ~ 40% in the summer. Potential Source Contribution Function (PSCF) analysis for identification of source regions showed that the Saharan desert was the main source area for crustal components. For secondary aerosol components the analysis revealed one source region, (i.e. the south-Eastern Black Sea), whereas for residual oil, Western Europe and the western Balkans areas were found to be the main source regions.     

Lacustrine basin hydrocarbon exploration – current thoughts

Although much of the world's petroleum resource-base is associated with marine systems, regionally lacustrine petroleum systems are important. Individual accumulations may exceed several billion barrels. In each of these cases the oil is derived from a lacustrine source rock and may be produced from either nonmarine or marine reservoir rocks. The purpose of this paper is to describe the factors that control lacustrine source rock development and the nature of lacustrine reservoirs. Lacustrine oils display different physical and chemical characteristics than their marine counterparts. These differences can be related to the nature of their precursor material. Although the nature of the products are different, the geochemical threshold criteria for defining source rocks in both settings are the same because of common expulsion requirements. Commercially significant lacustrine systems require the presence of large, long-lived lakes. Such lake settings are tectonic in origin and restricted to climatic settings where precipitation exceeds evaporation. Within these large lake systems three primary factors determine source rock potential and quality. These factors are primary productivity level, organic preservation potential, and matrix sedimentation rate, which controls the dilution of preserved organic matter. Source rock potential is maximized where both productivity and preservation potential are maximized and sedimentation rate is minimized. To some degree these factors can compensate for each other. Hydrocarbon reservoir potential within lacustrine basins is partially impacted by overall tectonic setting. Within extensional settings, transport distances tend to be limited, with much of the sediment being transported away from the basin. The sediments delivered to the lake are poorly sorted and sedimentologically immature, commonly resulting in poor reservoirs due to both primary properties and their susceptibility to diagenesis. Within rifts better reservoirs tend to develop along platform or flexural margins. Stacking of reservoirs is important in lacustrine systems but baffles and barriers are often present between individual sand units. These barriers form as a result of lake level fluctuations. In compressional settings transport distances tend to be longer, resulting in more mature, better sorted sediments leading to higher quality reservoirs. These reservoirs typically develop in fluvial-deltaic and wave-dominated shoreline settings. Lacustrine carbonate reservoirs are locally important. These carbonates tend to develop during lake level lowstands and are dependent on diagenesis (dissolution and karstification) for porosity and permeability development. Lacustrine reservoirs are often stratigraphically and areally limited and display low individual well production rates. Within pure lacustrine systems exploration opportunities appear to be often restricted by either reservoir presence or quality (i.e., production rates). The best exploration opportunities in lacustrine basins appear to be associated with hybrid systems where a lacustrine source and marine reservoir exist.     

煤样渗透率有效应力与基质收缩双重耦合效应及其与煤阶关系

为研究煤层气在排采过程中不同煤阶煤储层渗透率动态变化规律,利用煤岩三轴应力应变（基质收缩膨胀）测试系统,对褐煤、气煤和无烟煤样开展了有效应力与基质收缩双重效应物理模拟实验。固定轴压和围压不变,改变气体平衡压力,模拟开发过程中储层压力变化特征,测试其动态渗透率。利用实验结果,分析了不同煤阶煤岩在排采过程中动态渗透率反弹特征,并对比分析煤岩动态渗透率改善效果的差异性。研究表明：气体平衡压力从5 MPa降至1 MPa过程中,在有效应力和基质收缩双重效应作用下,褐煤样的归一化渗透率依次为1. 00、0. 60、0. 57、0. 57、0. 52,气煤样依次为1.00、0. 64、0. 50、0. 54和0. 55,无烟煤样依次为1.00、0. 74、0. 58、0. 50和0. 56。随气体平衡压力下降,中阶及高阶煤样动态渗透率先下降后上升,整体呈不对称“V”型变化规律,但拐点略有不同;低阶煤样动态渗透率呈先下降后基本稳定的趋势,整体呈斜“L”型变化规律。在有效应力和基质收缩双重效应影响下,中阶及高阶煤样动态渗透率改善效果优于低阶煤样。     

多层弹性平面问题解的精确刚度矩阵法

从平面弹性力学的基本方程出发,利用Fourier积分变换等数学手段,推导出了单层平面问题的刚度矩阵,然后按有限元法组成总体刚度矩阵。通过求解由总体刚度矩阵所构成的代数方程和Fourier积分逆变换,得到在任意静荷载作用下多层弹性平面问题的精确解。由于刚度矩阵不含有正指数项,计算时不会出现溢出现象,从而克服了传递矩阵法的缺点。推导过程中摒弃了应力函数的选择,使得问题的求解更加合理化,同时也为进一步研究此类问题如温度场、动力学等奠定了理论基础。计算实例证明了推导结果的准确性。     

Canopy cover effects on local soil water dynamics in a tropical agroforestry system: Evaporation drives soil water isotopic enrichment

Despite the widely held assumption that trees negatively affect the local water budget in densely planted tree plantations, we still lack a clear understanding of the underlying processes by which canopy cover influences local soil water dynamics in more open, humid tropical ecosystems. In this study, we propose a new conceptual model that uses a combination of stable isotope and soil moisture measurements throughout the soil profile to assess potential mechanisms by which evaporation (of surface soil water and of canopy‐intercepted rainfall) affects the relationship between surface soil water isotopic enrichment (lc‐excess) and soil water content. Our conceptual model was derived from soil water data collected under deciduous and evergreen plants in a shade grown coffee agroforestry system in Costa Rica. Reduced soil moisture under shade trees during the “drier” season, coinciding when these trees were defoliated, was largely the result of increase soil water evaporation as indicated by the positive relationship between soil water content and lc‐excess of surface soil water. In contrast, the evergreen coffee shrubs had a higher leaf area index during the “drier” season, leading to enhanced rainfall interception and a negative relationship between lc‐excess and soil water content. During the wet season, there was no clear relationship between soil water content and between lc‐excess of surface soil water. Greater surface soil water under coffee during the dry season may, in part, explain greater preferential flow under coffee compared with under trees in conditions of low rainfall intensities. However, with increasing rainfall intensities during the wet season, there was no obvious difference in preferential flow between the two canopy covers. Results from this study indicate that our new conceptual model can be used to help disentangling the relative influence of canopy cover on local soil water isotopic composition and dynamics, yet also stresses the need for additional measurements to better resolve the underlying processes by which canopy structure influences local water dynamics.     

On a class of variational equations transformable to the Gauss hypergeometric equation

A new class of linear ordinary differential equations with periodic coefficients is found which can be transformed to the Gauss hypergeometric equation, and therefore the monodromy matrices are computable explicitly. These equations appear as the variational equations around a straight-line solution in Hamiltonian systems of the form H = T(p) + V(q), where T(p) and V(q) are homogeneous functions of p and q, respectively.