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Jean-Maurice Cases Jerzy Mielczarski Ella Mielczarska Laurent J. Michot Frédéric Villiéras Fabien Thomas 《Comptes Rendus Geoscience》2002,334(9):675-688
The adsorption of surfactants from aqueous solution is a phenomenon of major importance in applications ranging from ore flotation and paint technology to enhanced oil recovery. As this paper will illustrate, the process is very complex and of high scientific interest; its results can be extended to the retention of organic compounds (humic and fulvic acids, pollutants...) on solids in the biosphere. For a good understanding of the mechanisms involved in surfactants adsorption at the hydrophilic solid–aqueous solution interface, thermodynamic models have to take into account: (i) the physical chemistry of the surfactant in aqueous solution for choosing the appropriate reference phase, (ii) the surface heterogeneity of the adsorbing solid, (iii) the intensity of normal adsorbate–adsorbent bonds responsible for adsorption, (iv) the intensity of lateral bonds that favour the formation of surface aggregates through cooperative process and finally, (v) suitable theoretical models to describe adsorption phenomena. Once this has been achieved, two systems can be discussed: systems characterised by strong normal adsorbate–adsorbent bonds, currently used in ore flotation, which lead, in the case of heterogeneous surfaces, to the formation of lamellar aggregates at monolayer concentration and bilayer formation for higher concentrations. Systems characterised by weak normal adsorbate–adsorbent bonds, currently used in enhanced oil recovery and hydrocarbon (bio)remediation, which correspond to: (i) formation of globular micelles at the solid surface near the CMC when the temperature is higher than the Krafft point, (ii) formation of bilayered lamellar aggregates in the opposite case, (iii) three-dimensional condensation on substrate (T<TKrafft) if the ionic surfactant interacts with cations in the bulk. To cite this article: J.-M. Cases et al., C. R. Geoscience 334 (2002) 675–688. 相似文献
994.
Claude Lang 《Aquatic Sciences - Research Across Boundaries》1997,59(1):26-33
Oligochaete communities were used to assess the biological recovery of sediments after the abatement of eutrophication in
Lake Geneva (Switzerland). In 1995, mean relative abundance of oligotrophic worm species (OS) was around 30% in areas of low
organic sedimentation (LOS) whereas, in areas of high organic sedimentation (HOS), it was below 15%. The abundance of OS observed
in LOS areas was close to values predicted from total phosphorus (TP) concentrations in the water. Recovery from eutrophication
proceeded at the same pace in the water (TP) and in the sediment (OS) of LOS areas, whereas it was delayed in the sediment
of HOS areas. Lake Geneva was mesotrophic according to the oligochaete communities of LOS areas, but it was meso-eutrophic
according to those of HOS areas. 相似文献
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阐述了高质量印刷的4种方法:高精细度印刷、调频网印刷、高密度印刷、6~7色印刷以及它们的印刷效果和有待解决的问题。 相似文献
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Immediate impacts and recovery trajectories of macrofaunal communities following hydraulic clam dredging on Banquereau, eastern Canada 总被引:2,自引:0,他引:2
998.
本文介绍了一种测定积物中210Pb的方法.沉积物中的210Pb用HNO3和HF消化,然后210Po在85~90℃下从0.5molHCl介质中自沉积在银片上;其全程放化回收率为85.0±4.9×10-2 相似文献
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