History of crustal growth and recycling at the Pacific convergent margin of South America at latitudes 29°–36° S revealed by a U–Pb and Lu–Hf isotope study of detrital zircon from late Paleozoic accretionary systems

Detrital zircon provides a powerful archive of continental growth and recycling processes. We have tested this by a combined laser ablation ICP-MS U–Pb and Lu–Hf analysis of homogeneous growth domains in detrital zircon from late Paleozoic coastal accretionary systems in central Chile and the collisional Guarguaráz Complex in W Argentina. Because detritus from a large part of W Gondwana is present here, the data delineate the crustal evolution of southern South America at its Paleopacific margin, consistent with known data in the source regions.Zircon in the Guarguaráz Complex mainly displays an U–Pb age cluster at 0.93–1.46 Ga, similar to zircon in sediments of the adjacent allochthonous Cuyania Terrane. By contrast, zircon from the coastal accretionary systems shows a mixed provenance: Age clusters at 363–722 Ma are typical for zircon grown during the Braziliano, Pampean, Famatinian and post-Famatinian orogenic episodes east of Cuyania. An age spectrum at 1.00–1.39 Ga is interpreted as a mixture of zircon from Cuyania and several sources further east. Minor age clusters between 1.46 and 3.20 Ga suggest recycling of material from cratons within W Gondwana.The youngest age cluster (294–346 Ma) in the coastal accretionary prisms reflects a so far unknown local magmatic event, also represented by rhyolite and leucogranite pebbles. It sets time marks for the accretion history: Maximum depositional ages of most accreted metasediments are Middle to Upper Carboniferous. A change of the accretion mode occurred before 308 Ma, when also a concomitant retrowedge basin formed.Initial Hf-isotope compositions reveal at least three juvenile crust-forming periods in southern South America characterised by three major periods of juvenile magma production at 2.7–3.4 Ga, 1.9–2.3 Ga and 0.8–1.5 Ga. The ¹⁷⁶Hf/¹⁷⁷Hf of Mesoproterozoic zircon from the coastal accretionary systems is consistent with extensive crustal recycling and addition of some juvenile, mantle-derived magma, while that of zircon from the Guarguaráz Complex has a largely juvenile crustal signature. Zircon with Pampean, Famatinian and Braziliano ages (< 660 Ma) originated from recycled crust of variable age, which is, however, mainly Mesoproterozoic. By contrast, the Carboniferous magmatic event shows less variable and more radiogenic ¹⁷⁶Hf/¹⁷⁷Hf, pointing to a mean early Neoproterozoic crustal residence. This zircon is unlikely to have crystallized from melts of metasediments of the accretionary systems, but probably derived from a more juvenile crust in their backstop system.     

Impact of land use covers upon karst processes in a typical Fengcong depression system of Nongla, Guangxi, China

The direction and intensity of karst processes can be deeply affected by soil physical and chemical variations which were resulted from land use. Taking Nongla Fengcong depression area, Mashan County, Guangxi as an example, authors discussed the impact of land use on karst processes based on the data of field limestone tablet. The results showed that the corrosional rates at varied soil depth are quite different. Corrosional rate in woodland and orchard is mostly bigger than 20 mg/a, which is much higher than that in tilled land and shrub. Generally, corrosional rate decreased from orchard, woodland, tilled land, fallow land and shrub successively, in which soil organic matter (OM) and soil pH are two major controlling factors: corrosion process is controlled remarkably by soil OM in woodland and orchard. The higher the organic matter content is and the less the pH value is, the higher the corrosional rate is. Owing to lower organic matter content, the corrosional rate is mainly affected by soil CO₂ in tilled land and shrub.     

Suitability analysis for sand and gravel extraction site location in the context of a sustainable development in the surroundings of Zaragoza (Spain)

Zaragoza city is located in the central Ebro Basin, in the Iberian Peninsula. The fluvial terraces formed by the Ebro River present a valuable resource of sand and gravel deposits. However, taking advantage of these available resources implies conflicts with other land use interests like urban and industrial development as well as agricultural use, which has also traditionally occupied the alluvial terraces. These deposits represent a substantial groundwater resource that should be preserved for future generations. The development of spatial decision support systems (SDSS) has greatly assisted efforts for solving land-use conflicts. These systems combine the benefits of geographic information systems (GIS) and decision support methodologies and are therefore suitable to manage sustainable development of urban areas. In this contribution, an extraction suitability map taking into consideration a variety of environmental criteria is created with the help of a SDSS. The method used is the analytical hierarchy process which is integrated in ArcGIS. Areas most suitable to sand and gravel extraction are located in the high terraces, and in those terraces covered by pediments where the thickness of resource is relatively high. These areas are far from valuable natural areas, outside areas most vulnerable to groundwater contamination, and beneath soils with poor irrigation characteristics.     

A modified DRASTIC model for Siting Confined Animal Feeding Operations in Williams County,Ohio, USA

Three of DRASTIC’s parameters (Depth to Water, Soil Media, and Topography) were modified and another parameter was added (land use/land cover) to the model to determine the potential impact on groundwater from Confined Animal Feeding Operations (CAFO) manure lagoon settings and manure application as fertilizer. Williams County is a mostly agricultural county located in northwest Ohio, USA. It currently has three CAFOs, all dairy, with the possibility of the construction of a multi-million chicken egg CAFO in the near future. A Geographic Information System (GIS) was utilized to modify the Ohio Department of Natural Resources (ODNR) DRASTIC map for the county to fully assess the county-wide pollution potential of CAFOs. The CAFO DRASTIC map indicates that almost half of Williams County has elevated groundwater pollution potential. The rest of the county, primarily the southeast corner, has lower CAFO groundwater pollution potential. Future CAFO development within the county should focus on the southeastern portion of the county where the groundwater table is deeper, and the aquifer is composed of shale substrate with low hydraulic conductivity. The CAFO DRASTIC results are intended to be used as a screening tool and are not to replace site-specific hydrogeologic investigations.     

Evaluation of geochemical impact of tsunami on Pichavaram mangrove ecosystem,southeast coast of India

The 26 December 2004-tsunami has deposited sediments in the Pichavaram mangrove ecosystem, east coast of India. Ten surface and three core sediment samples were collected within 30 days of the event and analyzed for nutrients. Water samples were also analyzed to see the impact of tsunami on the geochemical behavior of nutrients. An increase in the concentration of various nutrients namely nitrate and phosphate was observed. The geochemistry of the mangrove forest was observed to be influenced by a number of factors like rapid increase of aquaculture farms, agricultural practices and the anthropogenic discharge from the nearby-inhabited areas. Further the sediment column was disturbed due to energetic tsunami waves, which has caused a sheer increase in the dissolved oxygen in water. As a result, the change in the redox potential has resulted in change in the nutrients absorbed/associated with the sediments. In addition, role of retreating water after tsunami on the nutrient geochemistry was also evaluated.     

The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Framing in geographical analysis of environmental conflicts: Theory, methodology and three case studies

When applied to environmental concerns, framing offers a rigorous conceptual and analytic approach with potentially practical significance for dealing with complex issues relevant to geography. The purpose of this article is to introduce framing concepts, typology and modes of analysis to address issues which geographers commonly treat: disputes over land ownership and uses, competition for water resources, cultural clashes over control of territory and resources and the impact of spatial patterns and structures when siting noxious sites. Framing analysis is applied to three cases of environmental conflict in Israel and, more generally, for understanding conflicts revolving around the management of human habitats in relation to the physical environment.     

Integrating diverse methods to understand climate-land interactions in East Africa

The questions of how land use change affects climate, and how climate change affects land use, require examination of societal and environmental systems across space at multiple scales, from the global climate to regional vegetative dynamics to local decision making by farmers and herders. It also requires an analysis of causal linkages and feedback loops between systems. These questions and the conceptual approach of the research design of the Climate-Land Interaction Project (CLIP) are rooted in the classical human-environment research tradition in Geography.This paper discusses a methodological framework to quantify the two-way interactions between land use and regional climate systems, using ongoing work by a team of multi-disciplinary scientists examining climate-land dynamics at multiple scales in East Africa. East Africa is a region that is undergoing rapid land use change, where changes in climate would have serious consequences for people’s livelihoods, and requiring new coping and land use strategies. The research involves exploration of linkages between two important foci of global change research, namely, land use/land cover (LULC) and climate change. These linkages are examined through modeling agricultural systems, land use driving forces and patterns, the physical properties of land cover, and the regional climate. Both qualitative and quantitative methods are being used to illustrate a diverse pluralism in scientific discovery.     

Models of natural and human dynamics in forest landscapes: Cross-site and cross-cultural synthesis

We synthesize the study of coupled natural and human systems across sites and cultures through a process of simplification and abstraction based on multiple dimensions of human-nature connectedness: satisfaction of basic needs, psycho-cultural connectedness and regulation of use of natural resources. We thus provide both a place-based and general understanding of value-driven anthropogenic environmental change and response. Two questions guide this research: what are the crucial stakeholder values that drive land use decisions and thus land cover change? And how can knowledge of these values be used to make decisions and policies that sustain both the human and natural systems in a place? To explore these questions we build simulation models of four study sites, two in the State of Texas, United States, and two in Venezuela. All include protected areas, though they differ in the specifics of vegetation and land use. In the Texas sites, relatively affluent individuals are legally converting forests to residential, commercial, and industrial uses, while in Venezuela landless settlers are extra-legally converting forests for purposes of subsistence agriculture. Contemporary modeling techniques now facilitate simulations of stakeholder and ecosystem dynamics revealing emergent patterns. Such coupled human and natural systems are currently recognized as a form of biocomplexity. Our modeling framework is flexible enough to allow adaptation to each of the study sites, capturing the essential features of the respective natural and anthropogenic land use changes and stakeholder reactions. The interactions between human stakeholders are simulated using multi-agent models that act on forest landscape models, and receive feedback of the effects of these actions on ecological habitats and hydrological response. The multi-agent models employ a formal logic-based method for the Venezuelan sites and a decision analysis approach using multi-attribute utility functions for the Texas sites, differing more in style and emphasis than in substance. Our natural-systems models are generic and can be tailored according to site-specific conditions. Similar models of tree growth and patch transitions are used for all the study sites and the differing responses to environmental variables are specified for each local species and terrain conditions.     

Coupled and complex: Human-environment interaction in the Greater Yellowstone Ecosystem, USA

Complexity theory has received considerable attention over the past decade from a wide variety of disciplines. Some who write on this topic suggest that complexity theory will lead to a unifying understanding of complex phenomena; others dismiss it as a passing and disruptive fad. We suggest that for the analysis of coupled natural/human systems, the truth emerges from the middle ground. As an approach focused as much on the connections among system elements as the elements themselves, we argue that complexity theory provides a useful conceptual framework for the study of coupled natural/human systems. It is, if nothing else, a framework that leads us to ask interesting questions about, for example, sustainability, resilience, threshold events, and predictability.In this paper we attempt to demystify the ongoing discussions on complexity theory by linking its evocative and overloaded terminology to real-world processes. We illustrate how a shift in focus from system elements to connections among elements can lead to meaningful insight into human-environment interactions that might otherwise be overlooked. We ground our discussion in ongoing interdisciplinary research surrounding Yellowstone National Park’s northern elk winter range; a tightly coupled natural/human system that has been the center of debate, conflict, and compromise for more than 135 years.