氧化多壁碳纳米管对水中钠离子的吸附研究

本文研究了强酸(体积比为3︰1的硫酸与硝酸)氧化的多壁碳纳米管对水中钠离子的吸附特性,考察了温度、初始浓度、吸附时间对钠离子吸附的影响。实验结果表明:多壁碳纳米管对钠离子的吸附能力随温度升高而下降;其吸附过程符合Langmuir吸附等温模型,但是在钠离子浓度较高时多壁碳纳米管的吸附特性更符合Freundlich等温模型;在温度为274K条件下,多壁碳纳米管对钠离子的吸附能约为-5.53KJ/mol即-57.3meV;化学反应焓变约为-9.31KJ/mol,表明混酸氧化的多壁碳纳米管对钠离子的吸附过程基本为物理吸附。     

Last glacial emplacement of methane-derived authigenic carbonates in the Sea of Japan constrained by diatom assemblage,carbon-14, and carbonate content

We studied diatom assemblages and CaCO₃ contents of methane-derived authigenic carbonates from the eastern margin of the Sea of Japan and assessed the formation time of these samples. Radioactive ¹⁴C date was determined in selected samples to obtain the maximum age of the time. The results of our study suggest mass formation of carbonate nodules in a glacial period within ∼40 ky, consistent with a published U/Th dating result of carbonate nodules in the study area. Diatom assemblages and contents in the carbonate nodules (abundance of ∼10⁶/g, dominance of neritic-littoral species, warm/cold water species ratio lower than ∼25) differ from the near-seafloor sediments in the study area, which have characteristics of Holocene sediments in the Sea of Japan, and suggest cementation of glacial sediments. Laminated sediments in some nodule samples are glacial sediments because laminations are records of a low sea level period in the semi-enclosed ocean. Similarity of diatom assemblages and contents in all carbonate samples is another evidence of glacial sediments in nodules. Glacial sediments with oceanic cold water species as low as Holocene sediments restricts the sediment age to before 20 cal. ky BP. Carbonate contents higher than 78 wt% suggest the cementation of poorly compacted sediments near the seafloor, and the date of carbonate cementation is, therefore, close to that of the cemented sediments. Most carbonate nodule samples in this study were formed in a glacial period and detection of ¹⁴C restricts this period to within ∼40 ky.     

桑沟湾及附近海域表层沉积物碳氮同位素分析及有机质来源

Naturally existing stable carbon and nitrogen isotopes are important in the study of sedimentary organic matter sources. To identify the sources of sedimentary organic matter in Sanggou Bay and its adjacent areas, which is characterized by high-density shellfish and seaweed aquaculture, the grain size, organic carbon(OC), total nitrogen(TN), carbon and nitrogen isotopic composition(δ13C and δ15N) of organic matter in the surface sediment were determined. The results showed that, in August, sedimentary OC and TN ranged from 0.17% to 0.76% and 0.04% to 0.14%, respectively. In November, OC and TN ranged from 0.23% to 0.87% and 0.05% to 0.14%, respectively. There was a significant positive correlation between OC and TN(R=0.98, P0.0001), indicating that OC and TN were homologous. In August, the δ13C and δ15N of organic matter varied from-23.06‰ to-21.59‰ and 5.10‰ to 6.31‰, respectively. In November, δ13C and δ15N ranged from-22.87‰ to-21.34‰ and 5.13‰ to 7.31‰, respectively. This study found that the major sources of sedimentary organic matter were marine shellfish biodeposition, seaweed farming, and soil organic matter. Using a three-end-member mixed model, we estimated that the dominant source of sedimentary organic matter was shellfish biodeposition, with an average contribution rate of 65.53% in August and 43.00% in November. Thus, shellfish farming had a significant influence on the coastal carbon cycle.     

中国贝类养殖对海洋碳循环的贡献评估

造成全球暖化的主要原因是温室气体的过量排放,其中CO2的贡献率达60 %,贝类养殖具有碳沉积作用。依据农业部渔业局编制的《中国渔业统计年签》,以2001年到2010年的年平均产量计算贝类捕获和养殖的碳沉积能力,并评估其碳沉积潜力;计算牡蛎、蛤、扇贝与贻贝四种贝壳单位面积的碳沉积能力并与森林、珊瑚礁的碳沉积能力进行比较分析。本文对我国浅海贝类养殖所具有的碳沉积能力进行评估,以了解贝类养殖对海洋碳循环的贡献,可为争取国家碳份额的合法权益提供基础数据。分析表明我国近十年贝类总产量稳定在1100万吨以上,并有增加的趋势,其中海水养殖贝类约占87.34 %。贝类养殖和捕获总产量的碳沉积和海水养殖产量的碳沉积量分别为58.57、51.15万吨/年,碳沉积能力分别相当于122.28、106.78万公顷的造林,可分别减少大气CO2增加量的0.0125 %、0.0109 %。牡蛎、蛤、扇贝与贻贝的单位面积碳沉积速率分别为1.573、0.388、0.301、1.039吨碳/(公顷?年);牡蛎和贻贝高于森林的碳沉积能力0.479吨碳/(公顷?年);但低于珊瑚礁的碳沉积能力1.8吨碳/(公顷?年)。我国贝类淡、海水养殖产量可分别创造约268.4万元/年、12,711.2万元/年的碳权商机。     

复配型席夫碱缓蚀剂对碳钢在海水中缓蚀性能研究

设计了由邻氧乙酸苯甲醛-4-吡啶甲酰腙席夫碱80 mg/L,邻香草醛脱氢枞胺席夫碱6 mg/L,ZnSO4 50 mg/L,Tween-80 100 mg/L四元复配缓蚀剂,通过失重法、极化曲线法和电化学交流阻抗技术,研究了该复配缓蚀剂在模拟现实使用环境中的缓蚀性能。结果表明,该复配缓蚀剂的缓蚀率受海水盐度的影响不大,但该复配缓蚀剂的缓蚀性能受海水温度和海水流速的影响较大,当温度低于50℃和流速较低、缓蚀剂浓度为临界浓度时,缓蚀剂对碳钢有很好的抑制作用,而有锈试样和间浸实验发现高浓度的复配缓蚀剂可以抑制碳钢的腐蚀。     

商业平板式超滤膜包完整性检验：对海洋胶体生物地球化学研究的启示

The performance and integrity of a cassette cross-flow ultrafilter(Pellicon 2, Millipore) are examined with a suite of macromolecules of different molecular masses. The retention coefficient during the cross-flow ultrafiltration experiments increases with increasing molecular mass and reaches 90% with 10 kDa dextran in both milli-Q water and ultrafiltered seawater media. Based on a 90% retention coefficient, the molecular mass cut-off for the ultrafiltration membrane is defined at 10 kDa, which is ten times(1 kDa) that rated by the manufacturer. To further validate the accuracy of the laboratory calibration, the samples from the lower Zhujiang River and the Jiulong River Estuary are ultrafiltered with the cassette ultrafiltration membrane and the colloidal organic carbon abundances in these samples are quantified with the ultrafiltration permeation model based on time series permeation subsamples. The colloidal organic carbon abundances are 5.8%–21.1% in the Jiulong River Estuary and 5.6%–11.0% in the lower Zhujiang River. These are consistent with the reported values for both estuaries as well as with the colloidal organic carbon abundances in marine environments over the coastal and open oceans with 10 kDa cut-off membranes. Therefore, these field data support the laboratory calibration result and indicate the validity of the experimental and quantification procedure adopted. The discrepancy between the nominal molecular mass cut-off and the actual pore size of the ultrafiltration membrane should be of great concern for research in colloidal and nanoparticle biogeochemistry. Careful examination of the membrane integrity should be taken during ultrafiltration experiments in order to avoid misleading molecular mass cut-off information.     

中国区域滨海湿地固碳能力研究现状与提升

对我国滨海湿地的固碳能力进行了评估,同时,对其固碳能力的遥感监测和评估方法进行了总结和分析,最后提出了滨海湿地固碳能力的提升技术。全球看来,我国滨海湿地的固碳能力总体上不高。国内看来,在北方泥炭地和植被覆盖率高,生长茂盛的区域,尤其是有红树林生长的区域固碳能力相对较高。滨海湿地主要分布在潮间带,人为监测困难,卫星遥感的出现为滨海湿地的监测带来很大方便,遥感监测已成为评估湿地固碳能力的一种高时效方法。滨海湿地固碳蕴藏着巨大潜力,提升滨海湿地的固碳能力可以大大降低全球CO2含量,对于改善全球温室效应有不可替代的作用。     

Risk mitigation and the social cost of carbon

The social cost of carbon – i.e., the marginal present-value cost imposed by greenhouse gas emissions – is determined by a complex interaction between factual assumptions, modeling methods, and value judgments. Among the most crucial factors is society's willingness to tolerate potentially catastrophic environmental risks. To explore this issue, the present analysis employs a stochastic climate–economy model that accounts for uncertainties in baseline economic growth, baseline emissions, greenhouse gas mitigation costs, carbon cycling, climate sensitivity, and climate change damages. In this model, preferences are specified to reflect the high degree of risk aversion revealed by private investment decisions, signaled by the large observed gap between the average rates of return paid by safe and risky financial instruments. In contrast, most climate–economy models assume much lower risk aversion. Given high risk aversion, the analysis finds that investment in climate stabilization yields especially large net benefits by forestalling low-probability threats to long-run human well-being. Accordingly, the social cost of carbon attains the markedly high value of $25,700 per metric ton of carbon dioxide in a baseline scenario in which emissions are unregulated. This value falls to just $4 per ton as the stringency of control measures is successively increased. These results cast doubt on the idea that the social cost of carbon takes on a uniquely defined, objective value that is independent of policy decisions. This does not, however, rule out the use of carbon prices to achieve the benefits of climate stabilization using least-cost mitigation measures.     

The economic impact of extreme sea-level rise: Ice sheet vulnerability and the social cost of carbon dioxide

The possibility of extreme sea-level rise is one of the commonly cited reasons for concern about climate change. Major increases in sea level would likely be driven by the melting or collapse of major ice sheets. This possibility has implications for the social cost of carbon dioxide, which is a key policy value as well as a useful summary measure of damage caused by greenhouse gas emissions.This paper extends earlier work on the importance of low-probability, high-impact events for the social cost of carbon dioxide to incorporate the possibility of extreme sea-level rise.To estimate its impact, an integrated assessment model is used, which allows a probabilistic assessment of climate change damages based on the linkages between the economic and climate systems. In the model, the generic discontinuity damage is replaced with the possibility of large-scale damage from factors that are taken to be correlated with temperature rise and, crucially for this paper, explicit consideration of extreme sea-level rise.Estimates of the amount of increase in the social cost of carbon dioxide that can be expected from incorporating extreme sea-level rise show that the increase is significant, though not especially large in percentage terms.The paper contributes to the literature of how to represent uncertain climate impacts in integrated assessment models and the associated estimation of the social cost of carbon dioxide.     

杞麓湖形态时空变化分析及地图可视化

杞麓湖是滇中高原湖泊的典型代表之一,近年来湖泊形态变化频繁且明显。基于2010—2021年的Landsat卫星影像,提取杞麓湖湖泊面积、湖岸线长度以及湖泊质心等数据,并计算出其他湖泊形态特征指标的数值。结合各年湖岸线的具体形态,对所获取数据的变化趋势及其原因进行分析,得出湖泊形态在时间与空间两个维度上的变化特征。根据专题地图制图的理论与规范,运用“形”“数”结合的方法对研究内容进行可视化表达,绘制杞麓湖湖泊形态的专题地图。