山东济宁许厂煤矿下组煤瓦斯与二氧化碳开发利用前景及存在的问题

许厂煤矿下组煤中蕴藏着较为丰富的瓦斯、二氧化碳资源。下组煤位于瓦斯风化带内,含瓦斯、二氧化碳和氮气等气体,瓦斯含量与埋藏深度呈正相关关系,主要存在低含量瓦斯、二氧化碳抽采率、二氧化碳资源化转换等技术方面的问题。从国家相关优惠政策、资源优势、煤与煤层气一体化开发技术、近水平长钻孔定向钻进技术、煤层压裂造缝技术、煤层注气增产技术和瓦斯、二氧化碳气体提纯技术等关键技术的发展程度,结合煤矿的下组煤层的开采方案,认为许厂煤矿有着较好的煤炭与瓦斯、二氧化碳一体化开发利用前景。     

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.     

6600 years of earthquake record in the Julian Alps (Lake Bohinj,Slovenia)

Sequences of lake sediments often form long and continuous records that may be sensitive recorders of seismic shaking. A multi‐proxy analysis of Lake Bohinj sediments associated with a well‐constrained chronology was conducted to reconstruct Holocene seismic activity in the Julian Alps (Slovenia). A seismic reflection survey and sedimentological analyses identified 29 homogenite‐type deposits related to mass‐wasting deposits. The most recent homogenites can be linked to historical regional earthquakes (i.e. 1348 ad , 1511 ad and 1690 ad ) with strong epicentral intensity [greater than ‘damaging’ (VIII ) on the Medvedev–Sponheuer–Karnik scale]. The correlation between the historical earthquake data set and the homogenites identified in a core isolated from local stream inputs, allows interpretation of all similar deposits as earthquake related. This work extends the earthquake chronicle of the last 6600 years in this area with a total of 29 events recorded. The early Holocene sedimentary record is disturbed by a seismic event (6617 ± 94 cal yr bp ) that reworked previously deposited sediment and led to a thick sediment deposit identified in the seismic survey. The period between 3500 cal yr bp and 2000 cal yr bp is characterized by a major destabilization in the watershed by human activities that led to increases in erosion and sedimentation rates. This change increased the lake's sensitivity to recording an earthquake (earthquake‐sensitivity threshold index) with the occurrence of 72 turbidite‐type deposits over this period. The high turbidite frequency identified could be the consequence of this change in lake earthquake sensitivity and thus these turbidites could be triggered by earthquake shaking, as other origins are discarded. This study illustrates why it is not acceptable to propose a return period for seismic activity recorded in lake sediment if the sedimentation rate varies significantly.     

珠穆朗玛峰自然保护区湖泊动态及对区域气候变化的响应

利用Landsat卫星影像,采用面向对象分类方法提取珠穆朗玛峰自然保护区湖泊信息,分析了湖泊动态及对区域气候变化的响应关系。结果表明：（1）2015年保护区湖泊总面积为489.07 km²,构造湖、河成湖、冰川湖分别占总面积的77.3%、2.6%、20.1%。（2）1975-2015年,保护区内各类湖泊面积变化速率不同,冰川湖最大（1.05 km²·a^-1）,构造湖次之（-0.85 km²·a^-1）,河成湖最稳定（0.013 km²·a^-1）;保护区南坡冰川湖面积变化速率（0.53 km²·a^-1）略大于北坡（0.52 km²·a^-1）。（3）北坡构造湖、河成湖对区域气候的响应呈阶段性变化规律,1975-2000年珠峰地区气候呈暖湿化趋势,2000年构造湖、河成湖面积达到峰值,两类总计增加22.8 km²;2000-2015年转变为显著的暖干气候,构造湖、河成湖面积均呈减少趋势,总共减少57.16 km²。随着区域气候的变暖,冰川湖总面积不断扩大,近40年间冰川湖面积累计增加43.06 km²。（4）灰色关联度分析显示,年极端低温对构造湖面积变化影响最显著,年均气温对冰川湖起主导作用,年均相对湿度对河成湖影响最大。较其他气候因子而言,降水量对各类湖泊面积变化的影响均最小。     

俯冲带碳酸盐化对深部碳循环的启示:以中国西南天山碳酸盐化云母片岩为例

俯冲带可将地球表层碳输送至深部地幔,同时也记录着俯冲板片来源碳质流体的迁移沉淀机制,对地球深部碳循环具有重大影响。近年来,俯冲带脱碳机制的研究表明流体溶解脱碳作用是冷的大洋俯冲板片释放COH流体的重要方式,而上覆板块(尤其地幔楔)则被认为是缓冲这些COH流体的重要场所,甚至是俯冲带CO_2的唯一"归宿"。事实上,俯冲带岩石本身的固碳能力却受到了忽视,而对俯冲带岩石捕获和固存CO_2(carbon capture and storage,CCS)能力的评估对全球碳通量的估算尤为重要。本文以中国西南天山高压-超高压变质带中碳酸盐化云母片岩为例,探讨俯冲带岩石的碳酸盐化对深部碳循环的影响。西南天山长阿吾子一带的碳酸盐化云母片岩记录了俯冲板片起源的碳质流体对俯冲带云母片岩的交代作用,地球化学特征表明蛇纹岩释放的富水流体溶解俯冲洋壳中的碳酸盐可能是产生COH流体的重要机制。基于碳质流体对多硅白云母(Si(a.p.f.u.)=3.58～3.73)的交代及相对高压的碳酸盐矿物(主要为白云石和菱镁矿)与金红石的共生,结合区域上碳酸盐化云母片岩与高压碳酸盐化蛇纹岩(HP-ophidolomite)的伴生,我们认为云母片岩的碳酸盐化作用可能发生在俯冲板片峰期稍后的高压折返阶段。俯冲带云母片岩的固碳作用表明除了上覆板块,俯冲带岩石本身对于碳质流体也具有很好的吸收能力。初步估算表明俯冲带云母片岩的碳酸盐化每年可固存至少2.46～6.68Mt/yr,约占俯冲板片每年进碳量的4%～17%。     

中朝边境天池破火山口湖底地形多波束测深探测

为调查天池破火山口湖的基本参数和湖底地形特征,研究破火山口的内部构造、破火山口的组合样式和垮塌堆积分布,本文采用多波束测深方法,对天池湖底地形进行了探测。探测结果显示:天池最大水深值为373.2m,天池水域边界实测周长为13.44km,天池湖水面面积9.4km~2,天池总蓄水量约为19.88×10~8m~3。天池周边分布4个温泉,温度为7~47℃。根据湖底地形推断,现今的天池破火山口形成于千年大喷发。其后,在天池西侧形成一个喷火口,东侧形成一个熔岩丘。天池湖底存在5个较大的破火山口内壁垮塌堆积区,但在湖底未见熔岩流。天池边缘出露的温泉点对应环状断裂,同时反映深部存在岩浆体。     

Spatiotemporal change patterns of urban lakes in China’s major cities between 1990 and 2015

China has experienced unprecedented urbanization in the past decades, resulting in dramatic changes in the physical, limnological, and hydrological characteristics of lakes in urban landscapes. However, the spatiotemporal dynamics in distribution and abundance of urban lakes in China remain poorly understood. Here, we characterized the spatiotemporal change patterns of urban lakes in China’s major cities between 1990 and 2015 using remote-sensing data and landscape metrics. The results showed that the urban lake landscape patterns have experienced drastic changes over the past 25 years. The total surface area of the urban lakes has decreased by 17,620.02?ha, a decrease of 24.22%, with a significant increase in the landscape fragmentation and a reduction in shape complexity. We defined three lake-shrinkage types and found that vanishment was the most common lake-shrinkage pattern, followed by edge-shrinkage and tunneling in terms of lake area. Moreover, we also found that urban sprawl was the dominant driver of the lake shrinkage, accounting for 67.89% of the total area loss, and the transition from lakes to cropland was also an important factor (19.86%). This study has potential for providing critical baseline information for government decision-making in lake resources management and urban landscape design.     

尼泊尔低喜马拉雅推覆带油源对比及油气成藏

尼泊尔低喜马拉雅推覆带油气苗来源不清极大地影响了该区油气勘探.在地质-地球物理综合调查的基础上,利用油气地球化学、碳同位素及生烃史模拟对尼泊尔代莱克地区油源和成藏过程进行了研究.结果表明:①尼泊尔代莱克地区油苗产于Padukasthan断裂,可分两期,第一期呈含油断层泥产出,氯仿沥青"A"为149～231 μg/g,RR.为0.81％,氯仿沥青"A"的δ13C相对较重(-26.24‰～-27.10‰),族组分具有正碳同位素序列,发黄绿色荧光,为典型的低熟煤成油,第二期呈液态油产出并遭受微生物降解,金刚烷IMD指数为0.33～0.45,R.为1.24％～1.53％,3,4-DMD含量46％～47％,全油δ13C为-29.50‰～-29.45‰,族组分碳同位素趋于一致,发蓝色荧光,为海相成因高熟油;②第一期油来源于Surkhet群的Melpani组和Gondwana群煤系烃源岩,为Ⅲ型有机质低熟阶段的产物,第二期来源于Surkhet群的Swat组浅海陆棚相黑色页岩,为Ⅱ1型有机质生油高峰的产物,两期油与Lakharpata群过成熟黑色泥岩和Siwalik群未熟泥岩没有亲缘关系;③尼泊尔低喜马拉雅推覆带具有"多源多期、推覆增熟、砂体控储、披覆控聚"的油气成藏模式,油气成藏过程可划分为沉积浅埋、构造圈闭形成、深埋油藏形成、气藏形成和晚期改造定型5个演化阶段;④尼泊尔低喜马拉雅推覆有利于Gondwana群、Surkhet群深埋增温、持续快速生烃和晚期成藏,对比邻区巴基斯坦的含油气盆地,尼泊尔低喜马拉雅推覆带及相邻类似地区具备良好的油气成藏条件.     

The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.     

双碳背景下我国煤炭资源勘查开发布局研究

随着双碳背景下国家能源结构调整和生态文明建设的要求,本文从保障国家主体能源安全和优化煤炭资源勘查开发布局的角度考虑,阐述了中国煤炭资源分布特点及勘查开发现状;从坚持集约与协调发展、改革与创新发展、绿色与清洁发展的基本原则出发,分析了新时期煤炭资源勘查目标：加强大型煤炭基地资源勘查、推进新增煤层气资源储量、加快煤系矿产资源勘查;从资源禀赋、开发强度、市场区位、环境容量、输送通道等方面出发,阐述了14个大型煤炭基地开发布局方向及建设规模,同时要加快煤层气的开发利用。研究成果对未来一段时期煤炭资源勘查开发及煤炭工业高质量发展具有重要的指导意义。