拟合法15°波动方程有限差分串联偏移

本文把最佳拟合算法（三点和五点差分格式）及串联偏移方法应用在15°波动方程偏移中。由于拟合法的差分因子随着采样间隔、步长、速度等参数的变化而变化,因此与原有的波动方程差分偏移法相比,串联偏移方法能有效的使大倾角归位,克服频散,速度及步长可以灵活变化,运算效率高等优点。     

Li3N·LiI·LiCl锂快离子导体研究

采用固态反应的方法制备Li_3N·LiI·LiCl快离子导体样品。使用X—射线衍射分析和差热分析的方法进行物相鉴定。电化学性能测试结果表明,样品具有较高的离子电导率,在100℃,其电导率可达10~(-4)_s/cm量级。样品的电导率与温度的关系很好地遵循Arrhenius方程。测得样品的电导活化能E_a为0.45eV。     

电离层赤道异常两日振荡的数值模拟

近20年来,国外学者对电离层赤道异常问题的数值模拟研究未考虑到大气行星波对潮汐发电机电场的调制效应,因而不能解释赤道异常峰值的逐日变化.本文结果表明二日波对F_2区电子浓度的输运有很大影响.这一方法可以推广到赤道异常各种长周期行星波振荡的数值研究. 本文从非定常等离子体连续方程出发,建立包含行星波振荡对E×B漂移的调制效应的方程,并给出数值模拟的方法以及可与实际观测进行比较的结果.文中取二日波漂移振幅为U_p=0 m/s、5m/s、10m/s,而初位相分别为φ=0°、90°共四种情形进行了模拟,结果表明,二日波的调制可使赤道异常的时空分布以及异常峰值产生明显的逐日变化.在所选取的模型中,取U_p=5m/s,φ=0°所得到的f_0F_2t的二日分布特征与观测较吻合.而u_p约5m/s的变化能引起异常峰值f_0F_2约1-2MHz的起伏,而二天之内f_0F_2的二个峰值表现出约2-4MHz的起伏.     

地球弓激波前的低频磁流体波

一、引言 在地球弓激波前存在着低频磁流体波。这种低频磁流体波是太阳风在地球弓激波上的反射粒子和太阳风粒子之间相互作用产生的。根据人造卫星的观测资料可以得到,在地球弓激波前,Pc3-4脉动频率范围内的低频磁流体波的主频率和行星际磁场强度     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。     

3D chemical model for geological macromolecules

This study defines a chemical representation of the kerogen macromolecule based on data from physicochemical analyses. The model should permit: creation of various schematic drawings representing an average macromolecule; future integration of new analytical results (for instance on structures of biomarkers or biopolymers); and determination of the distribution of chemical bonds.The models developed in this study can be represented in a 3D space, using classical chemical symbols, in the form of cyclic groups linked to each other by aliphatic chains. One cyclic group is a connected set of aromatic, naphthenoaromatic or naphthenic rings. These cyclic groups are constructed using basic elements such as atoms and bonds defined by their length and direction.Modeling of kerogen is done in three successive steps. A library is first created to define atoms, bonds and cyclic groups. Secondly, starting from a set of equations describing the analytical results, cyclic and aliphatic groups are chosen in the appropriate stoechiometric amount to match the analytical data. Finally the construction is done: cyclic groups are placed randomly in a 3D space, connections are made by aliphatic chains, and functional groups are added.The molecular modeling software Xmol^TM can be operated on APOLLO stations. It allows the creation of libraries, the calculation of chemical bonds corresponding to the analyses and the construction of macromolecules. An example is given for a type III kerogen at the beginning of diagenesis.     

Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.     

康定片麻岩岩石化学特征的初步研究

川西地区康定片麻岩(原称澄江—晋宁期岩浆岩第Ⅳ期的酸性岩)的主体是富钠质的英云闪长质-奥长花岗质片麻岩(灰色片麻岩);尚有少量花岗质片麻岩,系灰色片麻岩遭受钾质交代而成。其岩石化学特征与太古代花岗地体一致.灰色片麻岩属低铝型,以相对富铁和不具Eu异常为特征。它与川滇交界区晚太古代垭口片麻岩等一起构成川西滇中地区的片麻岩基底.     

New Investigation on the Space Group of Chevkinite

Chevkinite specimen from a rare-earth mineral deposit in Sichuan,southwest ofChina have been studied in detail by means of transmission electron microscope(TEM).The selected area electron diffraction(SAED)and convergent beam electron diffraction(CBED)patterns,obtained from different crystal zone axis direction,proved coineidently that the space group of chevkinite is C2/m.Fringe lattice image obser-vation showed the mineral crystal is structurally uniform in microscale,and it is anideal specimen for electron diffraction analysis.The mineral studied here is similar to theone from Bayan Obo,Inner Mongolia,China,in chemical composition and REE distri-bution.The chemical formula of the crystal is(Ce,La,…,Ca)_4 Fe~2-(Fe,Ti,Nb)_2O_8 (Si_2O_7)_2 .From our study,we come to the conclusion that the space group of the natu-ral chevkinite is C2/m,instead of P2_1/a as synthetic one.Up to now,chevkinitecompositionally similar to the synthetic one,in which the complete replacements of Ce,La by Nd and Fe by Mg or Co o