Mineralogical changes during thermal demagnetization of natural continental sandstones

We study the mineralogical changes suffered by specimens of natural miocene red and green continental sandstones (from Pozuelos Formation and Tiomayo Formation) cropping out in the Argentine Puna that increase their bulk magnetic susceptibility and change color when thermally treated. We hypothesize that on heating siderite, which is present in small quantities as cement in the studied sandstones, would oxidize and decompose into maghemite and/or magnetite. Subsequent heating to higher temperatures sometimes would bring about the conversion of maghemite and/or magnetite to hematite. Mössbauer spectroscopy proved to be a very valuable tool for the determination of the presence of siderite in small amounts in the studied samples. The present results show that further work is needed in order to fully understand the mineralogical changes suffered by continental sandstones during heating. The characterization of such changes occurred during laboratory routines is relevant, since they can help to better understand natural processes.     

Polymorphic phase transition in Superhydrous Phase B

We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction, Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures (down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering occurs not only at the Mg sites but also at the hydrogen sites.     

Rb2Ca[B4O5(OH)4]2·8H2O溶解及相转化过程的研究

利用IR光谱和Raman光谱等实验手段,对25℃时Rb2Ca[B4O5(OH)4]2·8H2O的溶解及相转化过程进行了初步探索,结果表明,Rb2Ca[B4O5(OH)4]2·8H2O溶于水后,硼在溶液中主要以B(OH)3和[B(OH)4]-的形式存在,残留固相由开始的无定形水合三硼酸钙,最终部分转变为Ca2[B3O3(OH)5]2·8H2O晶体。     

封闭体系有机质与有机碳氢氮恢复动力学研究

在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。     

城市“腾笼换鸟”产业转型升级的困境与出路——基于北京市的调查研究

剖析北京"腾笼换鸟"产业转型升级的现状,在针对"新鸟"进笼"老鸟"去哪问题",老笼"空间结构合理优化问题",老鸟"涅槃"新鸟"培育问题",老鸟"和"新笼"承接问题的分析基础上,提出应完善京津冀产业链协作",腾笼换鸟"拓展区域联动发展空间;东西城合并成首都特区",腾笼换鸟"保护北京历史文化名城;切实发挥政府的职能作用",腾笼换鸟"提升企业内在动力机制;规划建设"微中心"小城镇",腾笼换鸟"促进北京人口有效疏解的建议。     

加权总体最小二乘的效率优化算法

加权总体最小二乘法是理论上估计EIV模型参数相对严密的方法,其迭代过程中涉及的矩阵运算较为耗时,在处理大量级数据时尤其明显。PEIV模型有助于提高加权总体最小二乘法的计算效率。本文基于PEIV模型和经典最小二乘准则给出了一种加权总体最小二乘法算法,算法的推导过程简洁,易于理解,迭代过程中无需重构矩阵,减少了矩阵运算量。最后通过仿真试验验证了算法的可靠性。试验结果表明,本文算法可以取得与现有算法相同的参数估计精度且计算效率更高。     

多重加密格网内插法坐标转换

我国CGCS2000坐标系启用后,各地均面临着大批量、多类型、多坐标系成果数据坐标转换的需求,而国家大地坐标系、地心坐标系及独立坐标系之间的转换参数属于绝密级别,保密要求高,因此给实际应用带来了困难。顾及与参数法坐标转换成果的一致性及数据的安全要求,本文提出了多重加密格网内插坐标转换方法,研制了适用于多种数据格式的二/三维格网坐标转换软件,并将该算法应用于CORS服务,通过实例验证了该方法的可靠性与实用性。     

一种移动视频与地理场景的融合方法

快速准确地了解灾害现场状况是救灾过程中的重中之重。通常发生灾害都会使用无人机进行现场勘察,但是无人机视频难以与实际的地理场景关联起来,为此本文提出了一种移动视频与地理场景的融合方法。该方法首先采用具有仿射不变性的ASIFT算法检测特征点,将匹配后的特征点采用RANSAC算法进行迭代剔除噪点,计算视频与地理场景最优的透视变换矩阵模型参数;然后将计算得到的透视变换参数应用到视频数据,恢复视频角点坐标;最后通过内插得出所有视频帧的角点坐标,实现视频与DOM的精确融合。试验结果表明,对视频数据匹配的间隔帧越短,其整体融合精度越高,通过本文方法进行视频与地理场景融合的误差标准差低于10 m。     

洱海沉积物粒度记录与气候干湿变迁

通过对洱海现代沉积物的精细采样,将放射性核素精确计年与沉积物粒度研究相结合,重建了 6 0 0多年来洱海区域气候的干湿变迁,为恢复百年尺度的气候干湿变化提供了一条新途径。研究结果表明,15世纪是洱海地区最为湿润的一个世纪;洱海区域存在 10 0a、2 0 0a两种时间尺度的气候干湿准周期波动;自 19世纪末以来洱海区域气候整体上向干旱化方向发展,目前正处于干旱期末期,预计气候将由干旱转向湿润。     

新疆博格达山分段及深浅构造转换关系

研究表明 ,天山及邻区自中生代以来一直处于热衰减状态 ,博格达山新生代再造山具有“冷隆升”性 ,盆山边界断裂多限于上地壳内 ,而非直通中地壳低速体甚至上地幔的“深大断裂”。造山带内的韧性剪切带是在古生代形成的 ,而不是再造山期的断裂 ,它对造山带隆升及盆山耦合无贡献 ,博格达山的隆升为复式背斜构造所支持。博格达山与准东的关系为背斜北翼与盆地平缓基底构成的挠曲构造 ,而不是被深大断裂分隔的断块。博格达山具有独特鲜明的分段性 ,造山带的两个弧形构造与新生代再生前陆盆地构成独特的“斜方对称”分布样式。以板条观点为指导 ,从盆山单元的平面配置关系和深浅构造转换关系入手 ,探讨了博格达山板内造山阶段的几何学和运动学分段性的成因 ,构建了盆山耦合模式