狮子山铜矿岩壁X取样研究与应用

本文主要介绍了应用 X射线荧光方法在狮子山铜矿进行岩壁 X取样的技术和工作过程 ,提出了一些克服岩壁 X取样影响因素的方法。并对使用效果进行了评价     

北京西山地面塌陷的形成因素浅析

地下采矿是地面塌陷失决条件，自然重力及其他外界触发因素是其发展动因，地面塌陷受覆岩时代及岩性，采空区尺寸大小，煤层倾角，煤层厚度及开采深度，重复采动，水文条件变化，地形地势和松散盖层的影响。     

航空短波红外分光谱遥感技术直接寻找油气藏的有效性及应用实例

采用航空短波红外分光谱遥感技术，在新疆准噶尔盆地和塔里木盆地某些油气区，进行直接寻找油气资源的试验研究后发现，油气区含油岩系，油气藏上方盖层土壤的光谱在２３００和２３５０ｎｍ波段具有双吸收特征。     

无锡、常州郊区发生地裂缝

无锡、常州郊区发生地裂缝近年来，无锡石塘湾西蔡一秦村～带、常州横林分别出现了地裂缝，其中以钱桥毛村园最为严重，该处地裂缝于１９９１年夏初步形成，随后不断扩大，目前已具一定规模，长约７００ｍ，总体宽约６０ｍ，呈近东西向分布，并造成附近数十间楼房产生大量...     

Hydrous pyrolysis of a Type III source: fractionation effects during primary migration in natural and artificially matured samples

A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores.     

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.     

Modelling of soil temperature profiles using data from the pilot experiment at Anand

We present some preliminary results from a multi-layer soil temperature finite-difference model using the data set obtained during the pilot experiment on land surface processes at Anand. We hope that the present results will prove useful during the final field experiments scheduled for the coming monsoon season.     

黄铁矿表面及其与Au（HS）2^—溶液作用的STM研究

本文用ＳＴＭ研究了黄铁矿和方铅矿表面的原子结构、纳米级微形貌、电子态分布及其吸附态的特点。ＳＴＭ电流图象揭示了表面缺陷与表面电子态之间的对应关系，硫化和的表面的化学反应活性可能是表现缺陷引起的局域导电性增强有关。ＳＴＭ观察进一步表明黄铁矿和方铅矿对金的硫氢配合物的吸附作用优先发生于扭折位和台阶边缘等高能部位，反映出吸附态的分布也是与表面电子态分布相对应的。这样就从微观领域考证了硫化物表面对化学活性     

钛（Ⅳ）的反相萃取柱色层新体系研究及应用

本文研究了以ｃＨＣｌ＝８ｍｏｌ·Ｌ－１盐酸为移动相，以聚四氟乙烯负载的钽试剂－ＣＨＣｌ３为固定相反相萃取层析钛（Ⅳ）的新体系，柱上层析的钛用ｃＨＣｌ＝３ｍｏｌ·Ｌ－１盐酸洗脱后经二安替比林甲烷光度法测定，不仅钛回收率可达１００％，并可使钛（Ⅳ）与多种离子分离。能用于矿物岩石类复杂样品及其他物质中钛的分离富集与测定，方法简便快速。     

土的边界面本构模型研究进展

简述了土的边界面本构模型国内外研究状况，阐述了其基本思想。对边界面模型作了简要评述，提出了边界面模型研究的发展趋向。