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511.
The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er0.01YbxY1 - 0.01 - xVO4 crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.  相似文献   
512.
This paper calculates the structural parameters, electronic and optical properties of orthorhombic distorted perovskite-type TbMnO3 by first principles using density functional theory within the generalised gradient approximation. The calculated equilibrium lattice constants are in a reasonable agreement with theoretical and experimental data. The energy band structure, density of states and partial density of states of elements are obtained. Band structures show that TbMnO3 is an indirect band gap between the O 2p states and Mn 3d states, and the band gap is of 0.48 eV agreeing with experimental result. Furthermore, the optical properties, including the dielectric function, absorption coefficient, optical reflectivity, refractive index and energy loss spectrum are calculated and analysed, showing that the TbMnO3 is a promising dielectric material.  相似文献   
513.
This paper systematically studies the rolling effects of the (n, n) single-wall carbon nanotubes (SWCNT) with different curvatures on Rh adsorption behaviours by using density functional theory. The outside charge densities of SWCNTs are found to be higher than those inside, and the differences decrease with the increase of the tube radius. This electronic property led to the discovery that the outside adsorption energies are higher than the inside ones, and that the differences are reduced with the increase of the tube radius. Partial density of states and charge density difference indicate that these strong interactions induce electron transfer between Rh atoms and SWCNTs.  相似文献   
514.
Sea-level return periods are estimated at 18 sites around the English Channel using: (i) the annual maxima method; (ii) the r-largest method; (iii) the joint probability method; and (iv) the revised joint probability method. Tests are undertaken to determine how sensitive these four methods are to three factors which may significantly influence the results; (a) the treatment of the long-term trends in extreme sea level; (b) the relative magnitudes of the tidal and non-tidal components of sea level; and (c) the frequency, length and completeness of the available data. Results show that unless sea-level records with lengths of at least 50 years are used, the way in which the long-term trends is handled in the different methods can lead to significant differences in the estimated return levels. The direct methods (i.e. methods i and ii) underestimate the long (> 20 years) period return levels when the astronomical tidal variations of sea level (relative to a mean of zero) are about twice that of the non-tidal variations. The performance of each of the four methods is assessed using prediction errors (the difference between the return periods of the observed maximum level at each site and the corresponding data range). Finally, return periods, estimated using the four methods, are compared with estimates from the spatial revised joint probability method along the UK south coast and are found to be significantly larger at most sites along this coast, due to the comparatively short records originally used to calibrate the model in this area. The revised joint probability method is found to have the lowest prediction errors at most sites analysed and this method is recommended for application wherever possible. However, no method can compensate for poor data.  相似文献   
515.
在多源遥感影像融合中,基于传统PCA变换的多源遥感影像融合的光谱分辨率受到较大影响。提出了一种新的基于PCA变换的多源遥感影像像素级融合方法,通过在传统PCA变换融合算法基础上引入小波变换融合,保留了多波段遥感图像光谱特性的有用信息,进一步提高融合后遥感影像的效果。给出实验的融合结果,并与传统PCA变换方法进行对比,证明了该方法的有效性。  相似文献   
516.
在研究了非负矩阵分解(NMF)用于遥感图像融合技术的基础上,改进了一种基于光谱复原的NMF遥感图像融合算法,首先利用矩阵非负性分解求取图像的基向量矩阵,然后综合考虑图像融合后的光谱特性和波形变化情况,对基向量矩阵进行直方图规则化处理,最后得到融合后的图像。实验结果表明,该方法具有较好保持原始图像的光谱信息和空间信息的优点。  相似文献   
517.
随着村镇经济建设发展,生活垃圾和工业固体废弃物造成的污染问题日益突出,已经成为制约新农村建设发展和生态文明建设的关键问题,而目前针对乡镇非正规固体废弃物的调查与统计主要依赖全国各乡镇相关部门逐级调查上报,工作量较大。本文基于高分辨率遥感影像,将深度学习模型和条件随机场模型相结合引入到乡镇固体废弃物的提取研究中,探索一种基于深度卷积神经网络的乡镇固体废弃物提取模型。由于固体废弃物在影像上表现为面积小,分布破碎等特点,为了提高工作效率,将模型特分为识别和提取2个部分:① 通过全连接卷积网络(CNN)对固体废弃物进行快速识别判断,筛选感兴趣区域影像块;② 在传统的全卷积神经网络(FCN)的基础上加入条件随机场模型(CRF)提取固体废弃物边界,提高整体分割精度。根据安徽、山西等地区相关部门上报固体废弃物堆放点以及住房与城乡建设部城乡规划管理中心进行野外检查的结果,实验最终识别精度达到86.87%以上;形状提取精度为89.84%,Kappa系数为0.7851,识别与提取精度均优于传统分类方法。同时,该方法已经逐步应用于住房和城乡建设部有关成都、兰州、河北等部分乡镇非正规固体废弃物的核查工作,取得了较为满意的结果。  相似文献   
518.
无人机倾斜摄影测量颠覆了以往正射影像只能从垂直角度拍摄的局限,在三维建模中有广泛的前景。针对有些无人机倾斜影像数据无相机标定参数、无航带信息(无序)、无POS信息的现状,本文以计算机视觉中基于内容的影像检索方法与改进的渐进式SFM方法为基础,提出一种“三无”影像自动检索、空中三角测量及影像三维重建的方法。该方法首先通过提取的特征检索出相似影像并建立网络结构,然后将影像进行两两匹配增强对应关系并进行连接点的追踪,最后利用光束法平差方法对其进行平差,获取影像集的三维点云,提高大规模影像检索、影像匹配速度的同时,提高重建的精确性和鲁棒度。本文选取三组典型试验区大数据量倾斜影像数据进行试验,立体实测控制点中误差可以达到平面0.16m/高程0.18m,试验验证了方法的稳定性、可靠性和实用性。  相似文献   
519.
图像匹配作为三维重建至关重要的环节,其精度直接影响了平差优化、正射校正等模块的精度。对于城镇、农场等特征密集型区域,特征距离小,相似性强,易于匹配图像;而针对草地、沙漠等特征不明显区域,特征距离大,如果使用特征点匹配的方法,严格阈值下难以获得足够数量的匹配对,放宽阈值又将引入较多误匹配对,这也是导致稀疏点云不够均匀的原因之一。在此场景下,本文提出了基于动态极坐标参数化的无人机正视影像匹配算法,首先对图像做极坐标参数变化,采用动态策略解决极轴方向采样不均匀的问题,使用最小二乘法对得到的极坐标影像对做位移方向上的匹配,匹配后得到的旋转量和平移量,将该结果和SIFT算法的结果做比较。本文设计了2组实验,即参数已知的解算实验和参数未知的解算实验,且每组实验进行3次。在同等配置的计算机上,对两张7360像素×5400像素,32位的影像,本文方法的位姿解算时间相比SIFT的时间减少约57%,二者求得的位姿差通常小于1%。结论表明二者的结果在精度上表现相当,在时间上明显优于SIFT算法,具有实际的应用价值。  相似文献   
520.
Conventional farming-pastoral ecotones methods of delineating were not quantitative and could not fully show their spatial distribution. The present paper attempts to develop quantitative methods for mapping farming-pastoral ecotones in China. Nine indicators, related to temperature, precipitation and altitude aspects, were selected to quantify ecological susceptibility of vegetation (crops and forage). Methods of analytic hierarchy process (AHP) and expert score ranking combined with fuzzy set theory were applied to assign the weight for each indicator and to define the membership functions. The geographic information system (GIS) was used to manage the spatial database and conduct the spatial analysis. According to the spatial calculation of evaluation model integrated with GIS, the ecological susceptibility of vegetation (crops and forage) was mapped. Three different zones, pastoral area, farming-pastoral ecotones and farming area, were classified by spatial cluster analysis and the maximum likelihood classification for the numeric map of vegetation ecological susceptibility by GIS. This map was validated by the economic statistical result based on the ratio of the output value from animal husbandry in total output value of agriculture by the National Bureau of Statistics in China, indicating that the mapping of the farming-pastoral ecotones may be accepted.  相似文献   
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