Long‐term final void salinity prediction for a post‐mining landscape in the Hunter Valley,New South Wales,Australia

Opencast mining alters surface and subsurface hydrology of a landscape both during and post‐mining. At mine closure, following opencast mining in mines with low overburden to coal ratios, a void is left in the final landform. This final void is the location of the active mine pit at closure. Voids are generally not infilled within the mines' lifetime, because of the prohibitive cost of earthwork operations, and they become post‐mining water bodies or pit lakes. Water quality is a significant issue for pit lakes. Groundwater within coal seams and associated rocks can be saline, depending on the nature of the strata and groundwater circulation patterns. This groundwater may be preferentially drawn to and collected in the final void. Surface runoff to the void will not only collect salts from rainfall and atmospheric fallout, but also from the ground surface and the weathering of fresh rock. As the void water level rises, its evaporative surface area increases, concentrating salts that are held in solution. This paper presents a study of the long term, water quality trends in a post‐mining final void in the Hunter Valley, New South Wales, Australia. This process is complex and occurs long term, and modelling offers the only method of evaluating water quality. Using available geochemical, climate and hydrogeological data as inputs into a mass‐balance model, water quality in the final void was found to increase rapidly in salinity through time (2452 to 8909 mg l⁻¹ over 500 years) as evaporation concentrates the salt in the void and regional groundwater containing high loads of salt continues to flow into the void. Copyright © 2004 John Wiley & Sons, Ltd.     

Temporal patterns and controls on runoff magnitude and solution chemistry of urban catchments in the semiarid southwestern United States

Urban expansion and the scarcity of water supplies in arid and semiarid regions have increased the importance of urban runoff to localized water resources. However, urban catchment responses to precipitation are poorly understood in semiarid regions where intense rainfall often results in large runoff events during the short summer monsoon season. To evaluate how urban runoff quantity and quality respond to rainfall magnitude and timing, we collected stream stage data and runoff samples throughout the 2007 and 2008 summer monsoons from four ephemeral drainages in Tucson, Arizona. Antecedent rainfall explained 20% to 30% of discharge (mm) and runoff ratio in the least impervious (22%) catchment but was not statistically related to hydrologic responses at more impervious sites. Regression models indicated that rainfall depth, imperviousness and their combined effect control discharge and runoff ratios (p < 0.01, r² = 0.91 and 0.75, respectively). In contrast, runoff quality did not vary with imperviousness or catchment size. Rainfall depth and duration, time since antecedent rainfall and event and cumulative discharge controlled runoff hydrochemistry and resulted in five specific solute response patterns: (i) strong event and seasonal solute mobilization (solute flush), (ii) event chemostasis and strong seasonal flush, (iii) event chemostasis and weak seasonal flush, (iv) event and seasonal chemostasis and (v) late seasonal flush. Our results indicate that hydrologic responses of semiarid catchments are controlled by rainfall partitioning at the event scale, whereas wetting magnitude, frequency and timing alter solute stores readily available for transport and control temporal runoff quality. Copyright © 2012 John Wiley & Sons, Ltd.     

Application of FY-2C Cloud Drift Winds in a Mesoscale Numerical Model

Statistical tests and error analysis of cloud drift winds(CDWs) from the FY-2C satellite were made by using radiosonde observations.According to the error characteristics of the CDW,a bias correction using the thermal wind theory was applied in the data quality control.The CDW data were then assimilated into the GRAPES-meso model via the GRAPES-3DVar.A torrential rain event that occurred in northwestern China during 1-2 July 2005 was simulated.The results indicate that the CDW data were mainly distribute...     

Towards developing sediment quality assessment guidelines for aquatic systems: An Australian perspective

Sediment at the sediment‐water interface of natural and man‐made waterways forms an integral part of the ecosystem because it is affected by a continuous flux of physical, chemical and biological components between the sediment, interstitial water and the overlying water column. Aquatic sediments contain records of past and present urban and rural runoff, chemical discharges and spills. In recent years sediment quality has received increasing attention following identification of the role of sediment as both a sink for pollutants and as a contaminant source with potential impacts on the quality of receiving waters. Research has indicated that the processes leading to remobilization of contaminated sediments in upstream reaches of a waterway may, through time, exert a significant influence on water quality in the downstream reaches. This, together with the cumulative effects due to contaminant input from point and non‐point source discharges, have dramatic effects on water quality and thus on ecosystem structure and functioning.

The problems associated with elevated concentrations of many hazardous organic and inorganic compounds have resulted in the establishment of aquatic sediment quality criteria and management guidelines in many overseas countries, with the objectives being the reduction and elimination of adverse environmental effects and human health risks associated with contaminated sediments. Whereas more than 70% of the Australian population is clustered around the coastal waterways, little is known about the role of sediments as a repository of environmental pollutants and/or as a source of adverse impacts on water quality and the health of our rivers. The paucity of knowledge on the quality of aquatic sediment highlights the need for the development of coherent guidelines for sediment quality assessment and management of contaminated sites, which are consistent with Australian environmental conditions and land use features.

A comparative evaluation of sediment quality information from eight coastal rivers along the east coast of Australia, presented in this paper, indicates the possibility for establishing a framework for regional sediment quality assessment. This may be achievable by using textural and compositional attributes of bottom sediments in depositional areas to develop databases on the loading and concentration trends of nutrients and contaminants. Regional variability in sediment quality determinants are shown to reflect the influence of catchment hydrology, lithology and land use on nutrient and contaminant concentration trends. Locally, the loading and partitioning behaviour of sediment‐bound contaminants is largely controlled by the nature and the extent of interactions occurring at the sediment‐water interface within individual depositional units.

The concept of ‘Sediment Effect Zone’ is introduced to provide a compartmental approach to the characterization of aquatic sediments and depositional environments in different hydrologic zones. This approach offers a rational basis for follow‐up chemical and biological assessments to establish sediment quality standards and management guidelines. Because of the complex influences of environmental, methodological and statistical factors on defining the sediment variability, the need for implementing proper quality control measures from early stages of design of a sediment quality assessment program is highlighted.     

Global ENSO-streamflow teleconnection,streamflow forecasting and interannual variability

Abstract

El Niño Southern Oscillation (ENSO) has been linked to climate anomalies throughout the world. This paper presents an overview of global ENSO-streamflow teleconnection and identifies regions where the relationship may be exploited to forecast streamflow several months ahead. The teleconnection is investigated by fitting a first harmonic to 24-month El Niño streamflow composites from 581 catchments worldwide and the potential for forecasting is investigated by calculating the lag correlation between streamflow and two indicators of ENSO. The analyses indicate clear ENSO-streamflow teleconnections in many catchments, some of which are consistent across large geographical regions. Strong and regionally consistent ENSO-streamflow teleconnections are identified in Australia and New Zealand, South and Central America, and weaker signals are identified in some parts of Africa and North America. The results suggest that the ENSO-streamflow relationship and the serial correlation in streamflow can be used to successfully forecast streamflow. The streamflow forecasts can be used to help manage water resources, particularly in systems with high interannual variability in Australia, southern and drier parts of Africa and some areas of North America.     

Response of seismically isolated structures to rocking‐type excitations

In this paper, the origin of rocking‐type excitations and their effects on the response of base isolated structures are studied. In particular, the role of kinematic interaction in the determination of the rocking excitation is highlighted. The cases of surface foundations subjected to horizontally propagating waves, as well as of embedded foundations under vertically incident shear waves are examined. The validity of the kinematic interaction based on the rigid base mat assumption is discussed. It is shown that, in the case of classical horizontal isolation, rocking input may amplify significantly the response of the lower non‐isolated modes. The examination of full three‐dimensional isolation and active and semi‐active control methods demonstrates the efficacy of these methods to improve the performance of seismically isolated structures subjected to rocking excitations. Copyright © 2009 John Wiley & Sons, Ltd.     

三峡水库汛期控制水位及运用条件

随着长江上游梯级水库的陆续建成投运，三峡水库的水文情势和功能需求与设计条件相比发生了显著变化，仍维持固定的汛限水位运行已不能适应新形势需求。本文通过辨析三峡水库设计阶段汛限水位的设置条件，挖掘流域洪水特性和洪水遭遇规律，论证三峡水库汛期运行水位动态控制的可行性。结果表明：① 三峡水库设计推求的汛限水位145 m的适用条件是应对流域性大洪水，而流域性洪水发生概率小且特征明显，可以通过水文水情分析提前预判。② 根据流域洪水类型、洪水分期和遭遇规律，预判发生区域性大洪水时，三峡水库6月初至梅雨期结束汛限水位按145 m设置，从梅雨期结束后逐渐提高水位，8月20日后过渡到155 m。③ 在考虑上游水库群联合调度和气象水文预报的配合下，正常年份三峡水库汛期运行水位可在155 m上下浮动，并考虑提前蓄水。④ 三峡水库汛期运行水位动态控制，不会增加防洪风险和库区淤积风险，对中下游江湖关系和水文情势有利，可显著提高发电、航运、生态保护和供水等综合利用效益。     

Correlation between geochemical environments and controlling factors in the metallation of porphyrins

Experimental study on metallation of tetrapyrroles in biphasic systems showed that complexation with metal cations of the first transition series is a feasible under chemical environments similar to the naturally occurring ones. The metal transport from the aqueous media to the organic, which is a novel approach using naturally occurring fatty acids hydroxy aromatic compounds and thiols, is demonstrated. Selectivity between Ni²⁺ and VO²⁺ complexation is achieved under sulfurous rich conditions. The kinetic implications are discussed in view of their geoenvironmental applicability.     

ON SOME KEY SEDIMENTATION PROBLEMS OF THREE GORGES PROJECT (TGP)

I. INTRODUCTIONThe Three Gorges Project (TGP) being planned is to be located on the Yangtze River at Sandouplug, 44 km upstream of Yichang (Fig. l). A scheme studied in the feasibility stage has the crest ofthe dam placed at 185 m with a maximums height o…