The petroleum generation potential and effective oil window of humic coals related to coal composition and age

A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%R_o or T_max of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HI_max. Similarly, QI increases to a maximum value, QI_max. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or T_max. This means that in humic coals the vitrinite reflectance or T_max values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%R_o or T_max range 440–455 °C and the oil window extends to 1.5–2.0%R_o or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%R_o or from 440 to 490 °C. Specific ranges for HI_max and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HI_max values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%R_o or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%R_o or T_max of 440–445 °C.     

Fe and Mn in calcites cementing red beds: A record of oxidation–reduction conditions: Examples from the Catalan Coastal Ranges (NE Spain)

Fe and Mn occur in calcite cements depending on the oxidizing–reducing conditions of cementing waters, which may change according to depositional and diagenetic environments. In red beds, Mn and Fe are available from the ferruginous matrix. Thus, it is possible to know the oxidizing–reducing conditions of fluids that precipitated calcite as a function of Mn and Fe content in calcite cement. A detailed petrological (with special attention to cathodoluminescence) and geochemical analysis of these cements is a useful tool to constrain the diagenetic evolution of red beds and the history of the basin where they deposited.     

A laboratory experiment to monitor the contact state of a fault by transmission waves

We performed a series of laboratory experiments in which elastic waves were transmitted across a simulated fault. Two types of experiments were carried out: (1) Normal Stress Holding Test (NSHT): normal stress was kept constant for about 3 h without shear stress and transmission waves were observed. (2) Shear Stress Increasing Test (SSIT): shear stress was gradually increased until a stick-slip event occurred. Transmission waves were continuously observed throughout the process of stress accumulation. We focused on the change in transmission waves during the application of shear stress and especially during precursory slips.It was found in NSHT that the amplitude of transmission waves linearly increased with the logarithm of stationary contact time. The increase amounted to a few percent after about 3 h. Creep at asperity contacts is responsible for this phenomenon. From a theoretical consideration, it was concluded that the real contact area increased with the logarithm of stationary contact time.We observed in SSIT a significant increase in wave amplitude with shear stress application. This phenomenon cannot be attributed to the time effect observed in NSHT. Instead, it can be explained by the mechanism of “junction growth” proposed by Tabor. Junction growth yields an increase in real contact area. It is required for junction growth to occur that the material in contact is already plastic under a purely normal loading condition. A computer simulation confirmed that this requirement was satisfied in our experiments. We also found that the rate at which the amplitude increased was slightly reduced prior to a stick-slip event. The onset time of the reduction well coincides with the onset of precursory slip. The cause of the reduction is attributed to the reset of stationary contact time due to displacement. This interpretation is supported by the result of NSHT. Taking the time of stationary contact in SSIT into account, we may expect the change in wave amplitude to be, at most, only a few percent. The observed slight reduction in increasing rate is, in this sense, reasonable. The static stiffness of the fault also decreases with precursory slip. It was also found that low frequency waves are a better indicator of precursory slip than high frequency waves. This might suggest that low frequency waves with longer wavelength are a better indicator of average behavior of faults. The problem, however, merits a further investigation. The shifts in phase were also found to be a good indicator of the change in contact state of the fault. The changes in both amplitude and phase of transmission waves are unifyingly understood through the theory of transmission coefficient presented by Pyrak-Nolte et al. Rough surfaces have a tendency to give larger stick-slips than smooth surfaces. The amount of precursory slip is larger for rough surfaces than for smooth surfaces. Although it was confirmed by a computer simulation that rough surfaces have larger contact diameters than smooth surfaces, the rigorous relationship between the surface roughness (contact diameter) and the amount of precursory slips was not established.     

Slope instability of San Miniato hill (Florence, Italy): possible deformation patterns

The hill of San Miniato (Florence, Italy) has been repeatedly identified in the past as the site of a slow moving, intermittent landslide. Possible hypotheses regarding the mechanisms responsible for past movements and for cracks and fissures present today are formulated based on the comparison of historical information and processed monitoring data. Although it is not possible to completely exclude a large inactive landslide that involves the entire northern slope, it seems more probable that the slide, if it does exist, is no longer active and that present-day damage is due to separate shallow movements concentrated in man-made deposits. This hypothesis can only be verified with a temporal extension of the monitoring activities, necessary in any case for planning possible safeguarding measures for the cultural heritage in the area.     

Hydrogeology of thermal waters in Viterbo area, central Italy

A conceptual hydrogeological model of the Viterbo thermal area (central Italy) has been developed. Though numerous studies have been conducted on its geological, geochemical and geothermal features, there is no generalized picture defining the origin and yield of the hydrothermal system. These latter aspects have therefore become the objectives of this research, which is based on new hydrogeological and geochemical investigations. The geological setting results in the coexistence of overlapped interacting aquifers. The shallow volcanic aquifer, characterized by fresh waters, is fed from the area around the Cimini Mountains and is limited at its base by the semiconfining marly-calcareous-arenaceous complex and low-permeability clays. To the west of Viterbo, vertical upflows of thermal waters of the sulphate-chloride-alkaline-earth type with higher gas contents, are due to the locally uplifted carbonate reservoir, the reduced thickness of the semiconfining layer and the high local geothermal gradient. The hot waters (30–60°C) are the result of deep circulation within the carbonate rocks (0.5–1.8 km) and have the same recharge area as the volcanic aquifer. The upward flow in the Viterbo thermal area is at least 0.1 m³/s. This flow feeds springs and deep wells, also recharging the volcanic aquifer from below.     

Real Time Analysis and Forecasting of Strata Caving Behaviour during Longwall Operations

Summary. Discontinuous manual observations and irregular caving characteristics of roof rocks often lead to improper decisions resulting in accidents and production loss. Hence, systematic monitoring of the hanging roof behind the chock shields is necessary for safe and productive mining operations. A real-time application was successfully implemented in an Indian mine for forecasting of hanging roof behaviour to enhance safety and productivity. This paper reports the functioning of real-time TWAP (time weighted average pressure) analysis in the forecasting of hanging roof behaviour in real time.     

Temperature dependence of large-scale water-retention curves: a case study

A local-scale model for temperature-dependence of water-retention curves may be applicable to large scales. Consideration of this temperature dependence is important for modeling unsaturated flow and transport in the subsurface in numerous cases. Although significant progress has been made in understanding and modeling this temperature effect, almost all the previous studies have been limited to small scales (on the order of several centimeters). Numerical experiments were used to investigate the possibility of extending a local-scale model for the temperature-dependence of water retention curves to large scales (on the order of meters). Temperature effects on large-scale hydraulic properties are of interest in many practical applications. Numerical experiment results indicate that the local-scale model can indeed be applicable to large-scale problems for special porous media with high air entry values. A typical porous medium of this kind is the porous tuff matrix in the unsaturated zone of Yucca Mountain, Nevada, the proposed geologic disposal site for national high-level nuclear wastes. Whether this finding can approximately hold for general cases needs to be investigated in future studies.     

Control of dust emissions by geomorphic conditions, wind environments and land use in northern China: An examination based on dust storm frequency from 1960 to 2003

The degree to which dust emissions are controlled by geomorphic conditions, wind environments and land use was investigated using the dust storm frequency (DSF) and data from more than 300 meteorological stations throughout northern China. Our analysis showed that most dust emissions originated in gobi deserts that developed in piedmont alluvial fans of the Kunlun, Qilian and Helan mountains. Dust emissions are low from other gobi desert regions, such as the northern Gurbantunggut and eastern Taklimakan, where high vegetation coverage restrained dust emissions or where dust-size particles are not abundant after a long period of strong wind erosion. Sandy deserts with relatively high vegetation coverage or an extensive cover by mobile sands are not a major dust source. Although the highest dust emissions did not appear in regions with the highest wind energy, DSF trends in each region from 1960 to 2003 were closely related to local wind activity. DSF was low in regions with high levels of human activity, where the mean DSF from 1960 to 2003 did not exceed 4 days/year; even from the 1960s to the early 1970s, the period with the greatest DSF, frequency did not exceed 8 days/year, which indicates that extensive land use did not contribute to DSF. The low DSF in these areas might result from the fact that although land use could produce abundant fine soil fractions, vegetation coverage and soil moisture remained higher than in the gobi deserts of arid China, thereby decreasing dust-storm occurrence.     

四川省康定县滑坡灾害发育特征与形成条件

康定县地处四川盆地西缘山地及青藏高原过渡地带。县域内地势险峻,地形切割强烈,地层与地质构造复杂,新构造运动强烈,地震活动频繁。加之降水充沛,致使山地灾害十分发育,其中滑坡灾害占山地灾害的38.32%。通过搜集资料及现场调查,概述了该县县域内滑坡灾害的分布;从行政区划、自然地理及灾害规模等3方面统计分析了滑坡灾害的发育现状;从地形地貌、地层岩性、地质构造、降雨、地震活动、人类工程活动等方面总结了滑坡灾害的形成条件,并提出防治对策与措施,力求有效地预防与减少滑坡灾害的发生。     

Spatial assessment and redesign of a groundwater quality monitoring network using entropy theory, Gaza Strip, Palestine

Using entropy theory, a methodology was developed for the evaluation and redesign of groundwater quality monitoring wells in the Gaza Strip in Palestine. Essential to the methodology is the development of a Transinformation Model (TM) which yields the amount of information transfer and the dependency between the wells as a function of distance. The TM parameters, such as the minimum transinformation and the range, were employed for evaluating the network which revealed that most of the distances between wells were less than the range. It also indicated that a high percentage of redundant information existed in the network. Therefore, the network was reduced by superimposing a square pattern over the monitored area and selecting one well per square block in a stratified pattern. The methodology was tested using the chloride data collected from 1972–2000 from 417 groundwater quality monitoring wells in the Gaza Strip. The number of the groundwater quality monitoring wells in the Gaza Strip was reduced by 53%, while there was 26% redundant information based on the minimum existing distance between wells. This methodology is meant to help monitor the groundwater quality (salinity) in the Gaza Strip.