Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.     

青海省新型功能材料研究和产业的分析(续完)

介绍了部分新型功能材料的前沿领域发展情况;通过对青海省在能源、矿产资源方面的优势及青海省可持续发展能力的分析,对我省目前及未来可以发展的新型功能材料产业提出了意见和建议。     

中国城市职能分类研究综述

城市职能分类的研究一直以来就是城市地理学研究的重要领域。在简要回顾中国城市职能分类研究的主要成果和观点的基础上，从研究的阶段性角度将城市职能分类分为研究初步展开、研究发展、研究逐步完善3个时期；并提出为适应新形势的发展，城市职能分类研究将在拓展研究对象、创新研究方法、完善数据指标体系、充分利用研究成果等方面得到完善和提高。     

Urban stormwater thermal gene expression models for protection of sensitive receiving streams

Thermal impact of typical high‐density residential, industrial, and commercial land uses is a major concern for the health of aquatic life in urban watersheds, especially in smaller, cold, and cool‐water streams. This is the first study of its kind that provides simple easy‐to‐use equations, developed using gene expression programming (GEP) that can guide the assessment and the design of urban stormwater management systems to protect thermally sensitive receiving streams. We developed 3 GEP models using data collected during 3 years (2009–2011) from 4 urban catchments; the first GEP model predicts event mean temperature at the inlet of the pond; the second model predicts the stormwater temperature at the outlet of the pond; and the third model predicts the temperature of the stormwater after flowing through a cooling trench and before discharging to the receiving stream. The new models have high correlation coefficients of 0.90–0.94 and low prediction uncertainty of less than 4% of the median value of the predicted runoff temperatures. Sensitivity analysis shows that climatic factors have the highest influence on the thermal enrichment followed by the catchment characteristics and the key design variables of the stormwater pond and the cooling trench. The general method presented here is easily transferable to other regions of the world (but not necessarily the exact equations developed here); also through sensitivity and parametric analysis, we gained insight on the key factors and their relative importance in modelling thermal enrichment of urban stromwater runoff.     

基于等价权抗差估计和线性规划的天线曲面拟合算法

现有天线曲面拟合算法均基于最小二乘法,难以消除多个粗差对拟合结果的影响。本文基于等价权抗差估计思想,利用线性规划计算残差初值,再进行选权迭代计算。通过算例,证明本文方法能较好地探查多个粗差,且计算结果精度更高。     

局部区域模型重力异常快速算法

地球重力场位系数模型可以用于计算局部重力扰动场元。然而随着地球重力场模型阶次的提高、局域重力场计算范围的增大,其计算速度往往不能满足工程需求。针对这一问题,在对位系数模型泰勒级数展开的基础上提出了采用向量运算、混合编程的方法,同时对连带勒让德函数Belikov递推方法中与经纬度无关的量进行了预先计算,有效提高了计算速度。提出的方法对于利用超高阶次重力场模型快速解算大范围、高分辨率重力场元数据以及累加求和计算具有一定的参考与借鉴意义。     

耦合长期预报的跨流域引水受水水库调度模型

为提高跨流域引水工程受水水库引水有效性,研究了耦合长期径流预报信息的跨流域引水受水水库调度模型。首先选取汛期径流预报信息,采用径流预报概率修正先验概率来描述径流的不确定性,建立了贝叶斯随机动态规划模型(BSDP-LTF)。然后将模型应用于碧流河水库,并与仅考虑径流相关的随机动态规划模型(SDP-I)、仅考虑长期预报信息的随机动态规划模型(SDP-LTF)进行比较。比较结果得出在供水保证率基本一致且不增加调度风险的情况下,BSDP-LTF模型相比SDP-I、SDP-LTF模型,可分别减少引水8.2%、4.1%。表明贝叶斯随机动态规划模型BSDP-LTF有效改进了径流描述,提高了跨流域引水的有效性。     

基于潜在语义信息的城市功能区识别————广州市浮动车GPS时空数据挖掘

随着中国城市化进程的不断推进和深入,城市内部空间结构正发生不断的变化.城市内部形成的不同功能区标识研究,对城市结构理论以及政策制定,资源配置等方面具有非常重要的意义.这些不同的功能区包括住宅区,工业区,教育区以及办公区等.本文以大数据为依托,重点研究城市功能区的特点和分布状态,选取广州市6个区为样本,以最新道路网络为分割依据把研究样本分为439个区域.对历时一周的海量浮动车(GPS)数据以及兴趣点数据采用时空语义挖掘方法,建立潜在的狄利克雷模型(LDA)以及狄利克雷多项式回归模型(DMR);通过OPTICS聚类方法对不同模型的结果进行聚类,进而利用POI类别密度,居民出行特征等方法进行分区结果识别.同时,参考百度地图的地理信息,将研究得到的广州市功能分区结果与广州市城镇用地现状图,居民日常出行特征进行对比验证分析.研究表明,该方法基本能识别出具明显特征的城市功能区,如成熟居住区,科教文化区,商业娱乐区,开发区等.识别出的广州市不同类型的功能区呈现了以居住区和商业区为主导,其他类型功能区围绕其展开的特点.研究证明,利用大规模,高质量的个体时空数据开展人们移动行为和日常活动组织及社会空间的研究,能从一个新的视角揭示城市功能区的形成及其机制.