Theoretical Prediction of Gibbs Free Energies of Formation for Crystalline α-MOOH and α-M2O3 Based on a Linear Free-Energy Relationship

In the present study, the modified Sverjensky–Molling equation, derived from a linear-free energy relationship, is used to predict the Gibbs free energies of formation of crystalline phases of α-MOOH (with a goethite structure) and α-M2O3 (with a hematite structure) from the known thermodynamic properties of the corresponding aqueous trivalent cations (M3+). The modified equation is expressed as ΔG0f,MVX=aMVXΔG0n,M3++bMVX+βMVXγM3+, where the coefficients aMVX, bMVX, and βMVX characterize a particular structural family of MvX (M is a trivalent cation [M3+] and X represents the remainder of the composition of solid); γ3+ is the ionic radius of trivalent cations (M3+); ΔG0f,MVX is the standard Gibbs free energy of formation of MvX; and ΔG0n,M3+ is the non-solvation energy of trivalent cations (M3+). By fitting the equation to the known experimental thermodynamic data, the coefficients for the goethite family (α-MOOH) are aMVX=0.8838, bMVX=?424.4431 (kcal/mol), and βMVX=115 (kcal/mol.?), while the coefficients for the hematite family (α-M2O3) are aMVX=1.7468, bMVX=?814.9573 (kcal/mol), and βMVX=278 (kcal/mol.?). The constrained relationship can be used to predict the standard Gibbs free energies of formation of crystalline phases and fictive phases (i.e. phases that are thermodynamically unstable and do not occur at standard conditions) within the isostructural families of goethite (α-MOOH) and hematite (α-M2O3) if the standard Gibbs free energies of formation of the trivalent cations are known.     

长春台体应变仪器观测到的地球基频球型振荡

本文分析了2004年12月26日苏门答腊M9．0级大地震后5天的长春台体应变观测资料,利用功率谱密度估计方法,在没有对资料进行去固体潮处理的情况下,较准确地获得了大地震激发的基频球型振荡,并与地球初步参考模型（PREM）的理论自由振荡频率进行了对比,发现实测振荡频率与PREM预测的振荡频率基本符合。     

Snow loads on wire mesh and cable net rockfall slope protection systems

Snow load on mesh systems is complicated by many factors. This paper presents field instrumentation data on snow load variation with temperature, snowfall and snow depth on a mesh system. It was found that snow load pattern on mesh systems changed with temperature even without variation in snow depth. It reached its maximum value when the temperature rose just above freezing to melt the interface. The field data was used to formulate appropriate snow load models for the various conditions of temperature in the field. The snow load models were used to study the performance of a number of mesh systems in North America and estimate the interface friction that was prevalent for the different surface conditions.     

Assessment of effectiveness of nature reserves on the Tibetan Plateau based on net primary production and the large sample comparison method

Twenty-one typical coupled large samples were chosen from areas within and surrounding nature reserves on the Tibetan Plateau using the large sample comparison method (LSCM). To evaluate the effectiveness of the nature reserves in protecting the ecological environment, the alpine grassland net primary production (NPP) of these coupled samples were compared and the differences between them before and after their establishment as protected areas were analyzed. The results showed that: (1) With respect to the alpine grassland NPP, the ecological and environmental conditions of most nature reserves were more fragile than those of the surrounding areas and also lower than the average values for the Tibetan Plateau. (2) Of the 11 typical nature reserves selected, the positive trend in the NPP for Manzetang was the most significant, whereas there was no obvious trend in Taxkorgan. With the exception of Selincuo, the annual NPP growth rate in the nature reserves covered by alpine meadow and wetland was higher than that in nature reserves consisting of alpine steppe and alpine desert. (3) There were notable findings in 21 typical coupled samples: (a) After the establishment of the nature reserves, the annual rate of increase in the NPP in 76% of samples inside nature reserves and 82% of samples inside national nature reserves was higher than that of the corresponding samples outside nature reserves. (b) The effectiveness of ecological protection of the Mid-Kunlun, Changshagongma, Zoige and Selincuo (Selin Co) nature reserves was significant; the effectiveness of protection was relatively significant in most parts of the Sanjiangyuan and Qiangtang nature reserves, whereas in south-east Manzetang and north Taxkorgan the protection effectiveness was not obvious. (c) The ecological protection effectiveness was significant in nature reserves consisting of alpine meadow, but was weak in nature reserves covered by alpine steppe. This study also shows that the advantage of large sample comparison method in evaluating regional ecology change. Careful design of the samples used, to ensure comparability between the samples, is crucial to the success of this LSCM.     

加权混合估计中权值的确定方法

综合了大地测量中各种异方差多源观测模型和联合平差方法,说明了混合估计方法可以用于测量数据融合,平衡附加信息和样本信息对参数估计的影响。通过求取权值使参数估计的协方差阵的迹最小的方法,给出了一个权的最优选择方法。本文扩展了已有的加权混合估计方法,使得新方法中的权不受验前单位权方差的限制,能有效应用于大地测量数据处理。     

天然气水合物和游离气饱和度估算的影响因素

讨论了不同水合物胶结类型的流体饱和多孔隙固体中地震波的衰减情况,分析了估算天然气水合物和游离气饱和度影响因素.结果表明, 地层孔隙度、纵波速度模型和弹性模量的计算方法是影响反演水合物和游离气饱和度的关键因素.含水合物地层的吸收与水合物胶结类型密切相关,当水合物远离固体颗粒,像流体一样充填在孔隙时,品质因子出现负异常,而当水合物胶结固体颗粒影响骨架的弹性性质,其品质因子出现正异常.根据布莱克海台地区164航次995井的测井资料,分别应用低频和高频速度模型估算了水合物和游离气饱和度.由低频速度模型得到的水合物饱和度(占孔隙空间的)10%～20%,游离气饱和度(占孔隙空间的)0.5%～1%;而由高频速度模型得到的水合物饱和度(占孔隙空间的)5%～10%,游离气饱和度(占孔隙空间的)1%～2%.     

狭长区域GNSS控制网数据处理方法研究

针对狭长区域GNSS控制网边长差异较大的问题,本文通过划分子网来降低数据处理的难度,从基线处理和网平差两个方面,分析了系统误差来源,研究了基准处理中卫星轨道误差、对流层误差以及网平差中位置、尺度、方位和时间演变基准误差的改正方法,形成了一套高精度数据处理方案。基于该方法,对三峡库区GPS滑坡监测网的实测数据进行了分析与处理,获得了高精度的处理结果,本研究对狭长区域GNSS控制网的建立具有借鉴意义和指导作用。     

同伦函数与填充函数相结合的非线性最小二乘平差模型

提出了同伦函数与填充函数相结合进行非线性最小二乘平差的方法。先采用同伦函数求解非线性恰定方程组,得到一个局部最优解,然后以该局部最优解为基础构造填充函数,通过对填充函数求解,得到比当前局部最优解更小的局部极小点,再以该局部极小点为基础重新构造同伦函数和填充函数进行求解,通过有限步的循环迭代,最终找到非线性最小二乘平差的全局最优解。实例验证,该方法能有效地寻找出非线性最小二乘平差的全局最优解。     

国产高分数据在草原露天煤矿植被监测中的应用

利用高分一号卫星数据建立小尺度CASA－NPP估算模型,反演及监测草原露天煤矿区草地NPP空间分布格局,以及煤矿区内部复垦植被的NPP与表层土壤之间的关系。利用归一化植被指数、归一化水体指数等获取CASA模型有效光辐射参数、水分胁迫系数等,从而简化并改进小尺度CASA模型,遥感反演数据与实测样点数据拟合度达到0．94。结果表明,该模型能够高精度地完成小区域NPP估测。从利用CASA模型反演得到的NPP空间格局可以看出,这一地区的植被退化以采矿、放牧等人类活动为主导,原地貌区域围栏的典型草甸草原NPP在300～400 gC／m2· yr 之间,高于放牧区域 NPP,矿区内 NPP 空间变化显著,矿区内部 NPP 低于100 gC／m2· yr,明显低于周边原地貌地区。对于矿区复垦排土场区域,复垦年限和表土的养分是决定植被生长和NPP的主要因素。研究得出国产高分卫星数据可以高精度地完成小尺度NPP的估测,从而为其在草原地区以及矿山环境中监测提供了研究基础。     

A baroclinic typhoon model with a moving multi-nested grid and variational adjustment initialization Ⅱ. Forecast experiments

INTRODUCTIONBeingoneofthemestdisastrousweathersystemsinfluencingthesoutheaStcoastofChinainsurnmerandautumn,typhoonsalsocausestrongstormsUrgeSandseawavesI'eSultinginsevereoceandisasters,whichthreaten~theasternChina'sagriculture,navigation,offshoreoila...