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61.
流动注射-光度法测定地质样品中痕量碘 总被引:2,自引:2,他引:2
利用I~-对4,4′-四甲基二氨基二苯甲烷(4,4′-TMB-DPM)与氯胺T反应的催化作用,建立了流动注射-分光光度测定地质样品中痕量碘的方法。采用不等流速合并带法,分析速度快、节省试剂、灵敏度高。与高温水解法释放I~-相结合,使样品处理简单、干扰离子少。对于含I~-10μg/L的水样,其RSD(n=19)为1.1%,检出限为0.3ng/ml。用于水系沉积物、土壤分析时,含碘1.6×10~(-6)的样品RSD(n=10)为6.1%,检出限为0.08×10~(-6)。测量速度50N/h。 相似文献
62.
海洋沉积体系的定量模拟可分为仿真和勘察式模拟,后者的目标是建立沉积特征的连续谱、凝练新的科学问题。本文提出一个勘察式模拟的方法论框架,即根据控制方程确定自变量的定义域,进而由模拟计算给出应变量的值域,并结合物质收支平衡原理和“圆台状环礁”几何模型,以此方法预估环礁及其海底阶地物质输运和堆积格局。环礁是珊瑚礁的独特类型,其礁盘区提供了礁体生长和礁外坡、海底阶地堆积的几乎全部物源。结果表明,环礁自身生长受控于生物碎屑生产,而海底阶地的范围和沉积速率不仅决定于离礁悬沙通量,而且受到环礁外水深和海盆环流的制约。悬沙输运和重力流过程形成常态沉降和水下滑坡的交替沉积。此模型所预测的环礁沉积体系高程-面积曲线与南海环礁的实际曲线相对照,可获得环礁演化的机制信息。模拟结果还提示了需进一步研究的科学问题,如环礁生长规模及其控制机制、环礁沉积体系中周期性沉积的时间尺度、环礁外坡由于珊瑚生长自组织机制形成的重力流事件与地震等极端事件的对比和机制识别、环礁群的海底阶地沉积记录多样性、海面变化对环礁演化的影响和沉积记录、环礁人居环境安全等。 相似文献
63.
ZHANG Yi HE Lijuan WANG Jiyang XU Xing SHA Zhibing GONG Yuehu WANG Hongbing LIANG Jinqiang 《海洋学报(英文版)》2011,30(1):59-67
Using the collected 433 heat flow values, we estimated the bases of methane hydrate stability zone (BHSZ), in northern South China Sea (NSCS). Through comparing BHSZs with the depths of bottom simulating reflectors (BSRs), in Shenhu Area (SA), we found that there are big differences between them. In the north of SA, where the water depth is shallow, many slumps developed and the sedimentation rate is high, it appears great negative difference (as large as -192%). However, to the southeast of SA, where the water depth is deeper, sedimentation rate is relatively low and uplift basement topography exists, it changes to positive difference (as large as +45%). The differences change so great, which haven’t been observed in other places of the world. After considering the errors from the process of heat flow measurement, the BSR depth, the relationship of thermal conductivity with the sediments depth, and the fluid flow activities, we conclude that the difference should be not caused by these errors. Such big disagreement may be due to the misunderstanding of BSR. The deviant “BSRs” could represent the paleo-BSRs or just gas-bearing sediment layers, such as unconformities or the specific strata where have different permeability, which are not hydraterelated BSRs. 相似文献
64.
分析讨论了季风风应力、大陆坡地形及底摩擦在产生季风逆风流的必要条件和间接逆风流诊断判据中的作用;应用季风逆风流必要条件和间接逆风流诊断判据,解释冬季风和夏季风逆风流是如何产生的。结果表明:季风风应力是产生季风逆风流的主导因素;冬季风风应力、大陆坡地形及底摩擦三者联合作用导致表层海水在大陆坡上产生辐合生成高水位带和高动力高度带,在大陆被北侧产生NE向的冬季逆风流,南侧产生SW向顺风流;夏季风风应力、大陆坡地形及底摩擦三者联合作用导致表层海水在大陆坡上产生辐散生成低水位带和低动力高度带,在大陆被北侧产生SW向的夏季逆风流,南侧产生NE向的顺风流;冬季风盛行期间,风致经巴士海峡流入南海的黑潮水,将加速冬季逆风流的形成,加大冬季逆风流的强度;夏季风盛行期间,风应力的作用使巴上海峡以东的黑潮水不能进入南海,即使别的原因令巴上海峡以东的黑潮水流入南海,但高温、高盐的黑潮水对夏季逆风流具有阻扼作用。 相似文献
65.
河口水动力因素复杂,涨潮急流造成施工困难,引发断桩事故,应该引起工程界的足够重视,本文进行了流速实测资料分析和基桩动力特性的计算,得出的结论,可供有关河口及近海工程建设时参考。 相似文献
66.
Alexander Korobkin 《Ocean Engineering》1998,25(8):687-714
The impact of an elastic plate onto the compressible fluid without free surface deformation is considered. The ability of the liquid volume to be deformed is geometrically limited which leads to severe impact conditions. The present analysis is focused on the stresses in the plate and the hydrodynamic loads under the impact. The motivation for this research comes from ship hydrodynamics, where the hulls of a catamaran restrict the liquid outflow and the water impacts onto the wetdeck. The influence of the air on the impact process is investigated. The analysis did not reveal any great advantage of utilizing the air-cushion effect or ejection of air into the water near the impact region to prevent high stresses in the elastic plate. It was found that in the problem considered, the stress peaks far from the plate centre and the one-mode approximation does not provide correct information about the stress level. 相似文献
67.
Numerical study about vortex-induced vibration(VIV) related to a flexible riser model in consideration of internal flow progressing inside has been performed.The main objective of this work is to investigate the coupled fluid-structure interaction(FSI) taking place between tensioned riser model,external shear current and upward-progressing internal flow(from ocean bottom to surface).A CAE technology behind the current research which combines structural software with the CFD technology has been proposed.According to the result from dynamic analysis,it has been found that the existence of upward-progressing internal flow does play an important role in determining the vibration mode(/dominant frequency),vibration intensity and the magnitude of instantaneous vibration amplitude,when the velocity ratio of internal flow against external current is relatively high.As a rule,the larger the velocity of internal flow is,the more it contributes to the dynamic vibration response of the flexible riser model.In addition,multi-modal vibration phenomenon has been widely observed,for asymmetric curvature along the riser span emerges in the case of external shear current being imposed. 相似文献
68.
在一定来流条件下,张力腿平台(tension leg platform,简称TLP)的立柱后缘出现周期性的交替旋涡脱落,致使立柱受到垂直于来流方向的升力和平行于来流方向的阻力作用,导致TLP产生大幅度往复运动,显著增加平台结构和系泊系统的负载。目前,关于单柱、多柱结构绕流问题的研究较多,但对于TLP绕流特性的研究较少,机理尚存不明确的地方。为研究TLP的绕流力变化情况和流场特征,开展了数值模拟分析。利用计算流体动力学数值模拟软件,基于雷诺平均(RANS)法和分离涡模拟(DES)法对TLP绕流场进行仿真分析,揭示了TLP的绕流特性。结果表明,在3种来流角度和多个折合速度Vr下,TLP绕流的流体力系数存在明显差异,升力系数时域曲线呈现脉动性。TLP的上、下游立柱间存在明显的相互作用,影响了旋涡的形成与发展。TLP的旋涡脱落大多集中在平台固有频率附近,且在Vr=7,来流角度为0°时,升力系数频谱峰值最大,旋涡脱落集中。 相似文献
69.
70.
Vibration in heat exchangers is one of the main problems that the industry has faced over last few decades. Vibration phenomenon in heat exchangers is of major concern for designers and process engineers since it can lead to the tube damage, tube leakage, baffle damage, tube collision damage, fatigue, creep etc. In the present study, vibration response is analyzed on single tube located in the centre of the tube bundle having parallel triangular arrangement (60°) with P/D ratio of 1.44. The experiment is performed for two different flow conditions. This kind of experiment has not been reported in the literature. Under the first condition, the tube vibration response is analyzed when there is no internal flow in the tube and under the second condition, the response is analyzed when the internal tube flow is maintained at a constant value of 0.1 m/s. The free stream shell side velocity ranges from 0.8 m/s to 1.3 m/s, the reduced gap velocity varies from 1.80 to 2.66 and the Reynolds number varies from 44500 to 66000. It is observed that the internal tube flow results in larger vibration amplitudes for the tube than that without internal tube flow. It is also established that over the current range of shell side flow velocity, the turbulence is the dominant excitation mechanism for producing vibration in the tube since the amplitude varies directly with the increase in the shell side velocity. Damping has no significant effect on the vibration behavior of the tube for the current velocity range. 相似文献