Laboratory Simulation of the Formation Process of Surface Geochemical Anomalies Applied to Hydrocarbon Exploration

The formation mechanisms and processes of geochemical anomalies used as proxies in surface geochemistry exploration (SGE) have not been well understood. Previous studies cannot realize 3D measurement of microseeping hydrocarbons from reservoirs to the surface, which made it difficult to understand the features and pathways of deep hydrocarbon microseepages. Understanding the processes of hydrocarbon microseepages will contribute to the acceptance and effectiveness of surface geochemistry. Based on a simplified geological model of hydrocarbon microseepages, including hydrocarbon reservoir, direct caprock, overlying strata and Quaternary sediments, this work established a 3D experimental system to simulate the mechanisms and processes of deep hydrocarbon microseepes extending to the surface. The dispersive halos of microseeping hydrocarbons in the subsurface were adequately described by using this 3D experimental system. Results indicate that different migration patterns of hydrocarbons above the point gas source within the simulated caprock and overlying strata can be reflected by the ratio of i-butane to n-butane (i-C4/n-C4), which follow diffusion and infiltration (buoyancy) mechanisms. This is not the case for vertical measurement lines far from the point gas source. A vertical gas flow in the form of a plume was found during hydrocarbon microseepage. For sampling methods, the high-density grid sampling is favorable for delineating prospecting targets. Hydrocarbon infiltration or buoyancy flow occurs in the zones of infiltration clusters, coupling with a diffusion mechanism at the top of the water table and forming surface geochemical anomalies. These results are significant in understanding hydrocarbon microseepage and interpreting SGE data.     

赤道东北太平洋表层沉积物间隙水中营养盐的剖面分布及其海底扩散通量

对赤道东北太平洋海域表层沉积物间隙水中硅酸盐、磷酸盐和硝酸盐等营养盐的剖面分布三个航次的研究表明,研究区在采样深度内沉积物中有机质的分解以硝化作用为主.在水-沉积物界面附近硅酸盐、磷酸盐和硝酸盐都存在着极陡的浓度梯度, Fick扩散定理的计算结果表明,研究区内硅酸盐、磷酸盐和硝酸盐的海底扩散通量分别为- 886.45～ 42.62 μ mol/(m2· d)、- 3.04～ 5.83 μ mol/(m2· d)和- 189.43～ 21.05 μ mol/(m2· d),且硅酸盐和硝酸盐主要是从沉积物向底层水体扩散,是底层水体营养盐的来源之一;研究区内硅酸盐、磷酸盐和硝酸盐的海底扩散通量存在着一定的时间和空间变化, 这可能与因全球气候变化而导致的沉积环境的改变有关.     

高岭土/聚丙烯酸高吸水材料合成及表面改性

采用高温快速的水溶液聚合方法合成了高岭土／聚丙烯酸高吸水性复合材料,探讨了复合材料合成过程中各种因素,如引发剂用量、交联剂用量、中和度、高岭土超细粉用量等对复合材料吸水倍数的影响,还对该高吸水性复合材料进行表面亲水改性研究,结果表明表面亲水改性有利于提高复合材料的吸水速率。     

探地雷达在吉林西部地区探测土壤碱化层

吉林西部盐碱地区的探地雷达调查表明,盐碱地与耕地土的雷达回波具有明显差别,根据振幅的衰减特征可以精确区分耕地与盐碱地,根据频谱中高频峰值与土壤有机质含量的相关性可定性评价土壤的盐碱化程度.在雷达瞬时振幅图上,可将盐碱地纵向剖面分为盐分积累带和过渡带.采用探地雷达方法可快速了解盐碱化程度在深度方向上的变化,适宜开展大面积地面调查.     

多孔介质中天然气水合物稳定性的实验研究进展

勘探表明天然气水合物多产出于细碎屑沉积物中,其分布和赋存形式受温度、压力、水化学条件等多种物理化学因素的影响。前人的实验研究表明不同孔径尺度中的甲烷水合物稳定性有别于块状、层状水合物,同时孔隙表面的润湿性也是影响因素之一。在综合分析前人研究成果的基础上,系统阐述了孔隙的孔径、孔隙内表面润湿性对所含天然气水合物稳定性的影响规律,总结了可能的内在机理;并指出了当前应当尽快建立包括空间效应、温度、压力和组分等因素的综合天然气水合物相图,查明含天然气水合物沉积物的孔隙结构和表界面特征,建立天然气水合物的稳定性模型,将有助于精确预测天然气水合物的分布和规模,对于水合物开发和甲烷存储技术的研发也有着重要的意义。     

瑞雷波勘探在地下洞穴探测中的应用

利用瑞雷波勘探方法进行地下洞穴探测，在实际处理过程中，对场地所测得的面波频散曲线进行分类、归纳，并利用动力触探曲线对各种特征曲线所反映的地下洞穴情况进行标定，从而确定整个测区洞穴的空间分布规律。     

基于传统吸附烃概念的烃类检测新技术

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.     

Geochemical and radioactivity mapping in Poland

In 1990 the Polish Geological Institute initiated geochemical mapping of the country aimed at determining the actual conditions of chemistry in the Earth's surficial environments (soils, water sediments, and surficial waters as well) and sea-floor deposits in the Polish economic sector of the Baltic Sea. The geochemical mapping on different scales covered the entire area of the country and selected more important urban agglomerations and industrial districts. Approximately 15,100 samples of soils, 16,200 samples of fresh water sediments, 14,600 samples of surface waters and 467 samples of marine deposits were collected and analysed. A list of geochemical atlases published by the Polish Geological Institute is presented. Investigation of the distribution of radionuclides (natural and artificial) has been done since 1992. Concentrations of U, Th, K, post-Chernobyl Cs and γ dose rate were measured. Approximately 20,000 points covering the whole country were measured. More detailed mappings were executed in the areas polluted by Cs.     

椭圆-抛物线双屈服面模型参数灵敏度分析

利用两种土石料三轴CD试验数据确定两组椭圆-抛物双屈服面模型参数,研究了模型参数? 、KG、n、h、m、M1、M2和pr分别单独变化（而其他参数保持不变）对模型所反映的土的应力-应变关系的影响。结果表明,土体的体积应变对参数h、m比较敏感;? 、KG、n对剪胀性土的体变影响较大,而对剪缩性土体变影响不明显;? 、KG、n、h和m对模型反映的强度没有影响;pr变化对体变和强度影响均较小。M1和M2对强度和体变均有显著影响,且M1和M2中的小值决定模型的强度。定义了灵敏度,即一种用于表示模型参数对其所反映的应力-应变的影响程度的参数。分析表明,不同的参数,其灵敏度差异很大;不同的土类,参数灵敏度差异也较大。实际应用时,对灵敏度大的参数取值应特别慎重。     

岩层厚度对碳酸盐岩构造裂缝面密度和分形分布的影响

岩层厚度对于碳酸盐岩构造裂缝的发育起到重要作用.新疆柯坪大湾沟、青松和蓬莱坝构造性质比较稳定,剖面的构造裂缝测量结果统计分析表明,碳酸盐岩构造裂缝面密度与层厚呈负相关关系,层厚越大,构造裂缝面密度越小,但裂缝规模较大;随着层厚减薄,构造裂缝面密度线性增大,但裂缝规模较小.碳酸盐岩构造裂缝具有良好的分形特征,统计结果显示...